emendrix

Classification, Labelling and Packaging Regulation

CLP · 32008R1272 · every event for this act · on EUR-Lex

detected 2026-08-13 no amending act named

02008R1272-20170601 → 02008R1272-20180301

in force not stated

8 provisions touched — 8 substantive, 0 date-only, 0 disputed · 1 change without an explanation

No amending act is named for this event: the EU's own amendment metadata annotated nothing in this window and there were no amending-act instructions to read, so only the text comparison observed it. That is a fact about the corpus's records for the window, not a doubt about the text shown below.

MODIFIED +61 −24 Art. 23 Derogations from labelling requirements for special cases

applies from: unchanged

Point (f) of Article 23 now describes the exclusion using the phrase "not classified as skin corrosion or as serious eye damage (Category 1)" instead of the earlier wording "not corrosive to skin and/or eyes."

Cited: Art. 23, v1 · Art. 23, v2

text before / after

02008R1272-2017060102008R1272-20180301

Article 23 Derogations from labelling requirements for special cases The specific provisions on labelling laid down in section 1.3 of Annex I shall apply in respect of the following: (a) transportable gas cylinders; (b) gas containers intended for propane, butane or liquefied petroleum gas; (c) aerosols and containers fitted with a sealed spray attachment and containing substances or mixtures classified as presenting an aspiration hazard; (d) metals in massive form, alloys, mixtures containing polymers, mixtures containing elastomers; (e) explosives, as referred to in section 2.1 of Annex I, placed on the market with a view to obtaining an explosive or pyrotechnic effect; (f) substances or mixtures classified as corrosive to metals but not corrosive to classified as skin and/or eyes. corrosion or as serious eye damage (Category 1).

MODIFIED +53,245 −46,854 Annex I CLASSIFICATION AND LABELLING REQUIREMENTS FOR HAZARDOUS SUBSTANCES AND MIXTURES

applies from: unchanged

Section 1.1.3.4's heading and text now refer to interpolation within one hazard category rather than one toxicity category.

Section 1.3.6 now describes the exemption from the GHS05 pictogram by reference to substances or mixtures not classified as skin corrosion or as serious eye damage Category 1, in the finished state and packaged for consumer use, rather than by reference to substances not corrosive to skin and/or eyes in the finished state as packaged for consumer use.

Table 2.1.2 and its surrounding text in section 2.1.3 were reworked, including changed precautionary statement entries, a repositioned and renumbered note (now Note 1) on unpackaged or repackaged explosives, and the addition of a new Note 2 concerning substances and mixtures exempted from explosive classification after a negative Test Series 6 result, while the decision flowchart in Figure 2.1.3 accompanying section 2.1.4.1 was also restructured, and the remaining differences across the listed sub-provisions are not shown because the compared text is truncated before their content appears.

Cited: Annex I, v1 · Annex I, v2

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02008R1272-2017060102008R1272-20180301

compared line by line: this provision is too large to compare word by word, so a marked line is a line that changed somewhere

ANNEX I CLASSIFICATION AND LABELLING REQUIREMENTS FOR HAZARDOUS SUBSTANCES AND MIXTURES This annex sets out the criteria for classification in hazard classes and in their differentiations and sets out additional provisions on how the criteria may be met. … 56 unchanged lines … The hazard category of a tested production batch of a mixture can be assumed to be substantially equivalent to that of another untested production batch of the same commercial product, when produced by or under the control of the same supplier, unless there is reason to believe there is significant variation such that the hazard classification of the untested batch has changed. If the latter occurs, a new evaluation is necessary. 1.1.3.3. Concentration of highly hazardous mixtures In the case of the classification of mixtures covered by sections 3.1, 3.2, 3.3, 3.8, 3.9, 3.10 and 4.1, if a tested mixture is classified in the highest hazard category or sub-category, and the concentration of the components of the tested mixture that are in that category or sub-category is increased, the resulting untested mixture shall be classified in that category or sub-category without additional testing. 1.1.3.4. Interpolation within one toxicity category 1.1.3.4. Interpolation within one hazard category In the case of the classification of mixtures covered by sections 3.1, 3.2, 3.3, 3.8, 3.9, 3.10 and 4.1, for three mixtures (A, B and C) with identical components, where mixtures A and B have been tested and are in the same hazard category, and where untested mixture C has the same hazardous components as mixture A and B but has concentrations of those hazardous components intermediate to the concentrations in mixtures A and B, then mixture C is assumed to be in the same hazard category as A and B. 1.1.3.5. Substantially similar mixtures Given the following: … 46 unchanged lines … 1.3.4.2. Instead, the supplier shall provide the information to downstream users or distributors by means of the SDS. 1.3.5. Explosives placed on the market with a view to obtaining an explosive or pyrotechnic effect Explosives, as referred to in section 2.1, placed on the market with a view to obtaining an explosive or pyrotechnic effect shall be labelled and packaged in accordance with the requirements for explosives only. 1.3.6. Substances or mixtures classified as corrosive to metals but not corrosive to skin and/or eyes Substances or mixtures classified as corrosive to metals but not corrosive to skin and/or eyes which are in the finished state as packaged for consumer use do not require on the label the hazard pictogram GHS05. 1.3.6. Substances or mixtures classified as corrosive to metals but not classified as skin corrosion or as serious eye damage (Category 1) Substances or mixtures classified as corrosive to metals but not classified as skin corrosion or as serious eye damage (Category 1) which are in the finished state and packaged for consumer use do not require on the label the hazard pictogram GHS05. 1.4. Request for use of an alternative chemical name 1.4.1. Requests for use of an alternative chemical name under Article 24 may be granted only where (I) the substance has not been assigned a Community workplace exposure limit; and … 102 unchanged lines … 2.1.2.4. If explosives are unpackaged or repacked in packaging other than the original or similar packaging, they shall be retested. 2.1.3. Hazard Communication Label elements shall be used for substances, mixtures or articles meeting the criteria for classification in this hazard class in accordance with Table 2.1.2. NOTE to Table 2.1.2: Unpackaged explosives or explosives repacked in packaging other than the original or similar packaging shall include all of the following label elements: (a) the pictogram: exploding bomb; (b) the signal word: Danger; and (c) the hazard statement: explosive; mass explosion hazard unless the hazard is shown to correspond to one of the hazard categories in Table 2.1.2, in which case the corresponding symbol, the signal word and/or the hazard statement shall be assigned. Table 2.1.2 Label elements for explosives Classification Unstable Explosive Division 1.1 Division 1.2 Division 1.3 Division 1.4 Division 1.5 Division 1.6 GHS Pictograms Signal Word Danger Danger Danger Danger Warning Danger No signal word Hazard Statement H200: Unstable Explosive H201: Explosive; mass explosion hazard H202: Explosive; severe projection hazard H203: Explosive; fire, blast or projection hazard H204: Fire or projection hazard H205: May mass explode in fire No hazard statement Precautionary Statement Prevention P201 P202 Precautionary Statement Prevention P201 P250 P280 P210 P230 P234 P240 P250 P280 P210 P230 P234 P240 P250 P280 P210 P230 P234 P240 P250 P280 P210 P234 P240 P250 P280 P210 P230 P234 P240 P250 P280 No precautionary statement Precautionary Statement Response P372 P373 P380 P370+P380 P372 P373 P370+P380 P372 P373 P370+P380 P372 P373 P370+P380 P372 P373 P370+P380 P372 P373 No precautionary statement Precautionary Statement Storage P401 P401 P401 P401 P401 P401 No precautionary statement Precautionary Statement Disposal P501 P501 P501 P501 P501 P501 No precautionary statement Precautionary Statement Response P370 + P372 + P380 + P373 P370 + P372 + P380 + P373 P370 + P372 + P380 + P373 P370 + P372 + P380 + P373 P370 + P372 + P380 + P373 P370 + P380 + P375 P370 + P372 + P380 + P373 No precautionary statement Precautionary Statement Storage P401 P401 P401 P401 P401 P401 No precautionary statement Precautionary Statement Disposal P501 P501 P501 P501 P501 P501 No precautionary statement NOTE 1: Unpackaged explosives or explosives repackaged in packaging other than the original or similar packaging shall include all of the following label elements: (a) the pictogram: exploding bomb; (b) the signal word Danger; and (c) the hazard statement: Explosive; mass explosion hazard unless the hazard is shown to correspond to one of the hazard categories in Table 2.1.2, in which case the corresponding symbol, the signal word and/or the hazard statement shall be assigned. NOTE 2: Substances and mixtures, as supplied, with a positive result in Test Series 2 in Part I, Section 12, of the UN RTDG, Manual of Tests and Criteria, which are exempted from classification as explosives (based on a negative result in Test Series 6 in Part I, Section 16 of the UN RTDG, Manual of Tests and Criteria) still have explosive properties. The user shall be informed of these intrinsic explosive properties because they have to be considered for handling — especially if the substance or mixture is removed from its packaging or is repackaged — and for storage. For this reason, the explosive properties of the substance or mixture shall be communicated in Section 2 (Hazards identification) and Section 9 (Physical and chemical properties) of the Safety Data Sheet and other sections of the Safety Data Sheet, as appropriate. 2.1.4. Additional Classification Considerations 2.1.4.1. The classification of substances, mixtures and articles in the explosives hazard class and further allocation to a division is a very complex, three step procedure. Reference to Part I of the UN RTDG, Manual of Tests and Criteria is necessary. The first step is to ascertain whether the substance or mixture has explosive effects (Test Series 1). The second step is the acceptance procedure (Test Series 2 to 4) and the third step is the assignment to a hazard division (Test Series 5 to 7). The assessment whether a candidate for ammonium nitrate emulsion or suspension or gel, intermediate for blasting explosives (ANE) is insensitive enough for inclusion as an oxidising liquid (section 2.13) or an oxidising solid (section 2.14) is answered by Test Series 8 tests. … 50 unchanged lines … (*) For classification purposes, start with Test Series 2. Figure 2.1.3 Procedure for assignment to a division in the class of explosives (Class 1 for transport) ARTICLE OR SUBSTANCE PROVISIONALLY ACCEPTED IN THIS CLASS (from 2.1.2) Is the product an article excluded by definition? (see 2.1.1.1 (b)) Is the substance/mixture or article manufactured with the view of producing a practical explosive or pyrotechnic effect? DIVISION 1.1 DIVISION 1.2 DIVISION 1.3 DIVISION 1.4 Compatibility groups other than S DIVISION 1.4 Compatibility group S DIVISION 1.5 DIVISION 1.6 NOT AN EXPLOSIVE Are there hazardous effects outside the package? Would the hazard hinder fire-fighting in the immediate vicinity? Is the major hazard radiant heat and/or violent burning but with no dangerous blast or projection hazard? Is the major hazard that from dangerous projections? Is it a very insensitive explosive substance /mixture with a mass explosion hazard? Is it an extremely insensitive article? Is the result a mass explosion? TEST SERIES 5 TEST SERIES 7 TEST SERIES 6 Package the substance/ mixture Is the substance/mixture a candidate for Division 1.5? Is the article a candidate for Division 1.6? No Is the article a candidate for Division 1.6? Is the substance a candidate for Division 1.5? No Package the substance TEST SERIES 6 Yes Yes Is the result a mass explosion? Yes TEST SERIES 7 TEST SERIES 5 No Is it an extremely insensitive article? No Is the major hazard that from dangerous projections? Yes Yes Yes Is it a very insensitive explosive substance with a mass explosion hazard? No No No Is the major hazard radiant heat and/or violent burning but with no dangerous blast or projection hazard? Would the hazard hinder fire-fighting in the immediate vicinity? Yes Yes Yes Yes Yes Yes Yes Yes No No Are there hazardous effects outside the package? No Is the substance or article manufactured with the view of producing a practical explosive or pyrotechnic effect? Yes Yes Yes Is the product an article excluded by definition? (see 2.1.12 (b)) No NOT AN EXPLOSIVE DIVISION 1.6 DIVISION 1.5 DIVISION 1.4 Compatibility group S DIVISION 1.4 Compatibility groups other than S DIVISION 1.3 DIVISION 1.2 DIVISION 1.1 No No No No No No ARTICLE OR SUBSTANCE/MIXTURES PROVISIONALLY ACCEPTED IN THIS CLASS (from figure 2.1.2) Figure 2.1.4 Procedure for the classification of ammonium nitrate emulsion, suspension or gel (ANE) TEST SERIES 8 … 52 unchanged lines … Table 2.2.3 Label elements for flammable gases (including chemically unstable gases) Classification Flammable gas Chemically unstable gas Category 1 Category 2 Category A Category B Category 1 Category 2 Category A Category B GHS Pictogram No pictogram No additional pictogram No additional pictogram Signal Word Danger Warning No additional signal word No additional signal word Hazard Statement H220: Extremely flammable gas H221: Flammable gas H230: May react explosively even in the absence of air H231: May react explosively even in the absence of air at elevated pressure and/or temperature Hazard Statement H220: Extremely flammable gas H221: Flammable gas Additional hazard statement H230: May react explosively even in the absence of air Additional hazard statement H231: May react explosively even in the absence of air at elevated pressure and/or temperature Precautionary Statement Prevention P210 P210 P202 P202 Precautionary Statement Response P377 P381 P377 … 40 unchanged lines … 2.3.1. Definitions Aerosols, this means aerosol dispensers, are any non-refillable receptacles made of metal, glass or plastics and containing a gas compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state or in a gaseous state. 2.3.2. Classification criteria 2.3.2.1. Aerosols shall be considered for classification as flammable in accordance with section 2.3.2.2 if they contain any component which is classified as flammable according to the following criteria set out in this Part: Liquids with a flash point ≤ 93 °C, which includes Flammable Liquids according to section 2.6; Flammable gases (see section 2.2); Flammable solids (see section 2.7). Note 1: Flammable components do not cover pyrophoric, self-heating or water-reactive substances and mixtures because such components are never used as aerosol contents. Note 2: Aerosols do not fall additionally within the scope of sections 2.2 (flammable gases), 2.5 (gases under pressure), 2.6 (flammable liquids) and 2.7 (flammable solids). Depending on their contents, aerosols may however fall within the scope of other hazard classes, including their labelling elements. 2.3.2.1. Aerosols shall be classified in one of the three categories of this hazard class, depending on their flammable properties and their heat of combustion. They shall be considered for classification in Category 1 or 2 if they contain more than 1 % components (by mass) which are classified as flammable according to the following criteria set out in this Part: Flammable gases (see Section 2.2); Liquids with a flash point ≤ 93 °C, which includes Flammable Liquids according to Section 2.6; Flammable solids (see Section 2.7); or if their heat of combustion is at least 20 kJ/g. NOTE 1: Flammable components do not cover pyrophoric, self-heating or water-reactive substances and mixtures because such components are never used as aerosol contents. NOTE 2: Aerosols do not fall additionally within the scope of Sections 2.2 (flammable gases), 2.5 (gases under pressure), 2.6 (flammable liquids) and 2.7 (flammable solids). Depending on their contents, aerosols may however fall within the scope of other hazard classes, including their labelling elements. 2.3.2.2. An aerosol shall be classified in one of the three categories for this Class on the basis of its components, of its chemical heat of combustion and, if applicable, of the results of the foam test (for foam aerosols) and of the ignition distance test and enclosed space test (for spray aerosols) in accordance with Figures 2.3.1(a) to 2.3.1(c) of this Annex and subsections 31.4, 31.5 and 31.6 of Part III of the UN RTDG, Manual of Tests and Criteria. Aerosols which do not meet the criteria for inclusion in Category 1 or Category 2 shall be classified in Category 3. Note: Aerosols containing more than 1 % flammable components or with a heat of combustion of at least 20 kJ/g, which are not submitted to the flammability classification procedures in this section shall be classified as aerosols, Category 1. Figure 2.3.1 (a) Aerosols For aerosols AEROSOL Does it contain ≤ 1 % flammable components and does it have a heat of combustion < 20 kJ/g? Does it contain ≤ 1% flammable components (by mass) and does it have a heat of combustion < 20 kJ/g? YES Category 3 No pictogram Warning NO Does it contain ≥ 85 % flammable components and does it have a heat of combustion ≥ 30 kJ/g? Does it contain ≥ 85% flammable components (by mass) and does it have a heat of combustion ≥ 30 kJ/g? YES Category 1 Danger … 49 unchanged lines … 2.3.3. Hazard Communication Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.3.1. Table 2.3.1 Label elements for flammable and non-flammable aerosols Label elements for aerosols Classification Category 1 Category 2 Category 3 GHS Pictograms No pictogram Signal Word Danger Warning Warning … 72 unchanged lines … Classification Compressed gas Liquefied gas Refrigerated liquefied gas Dissolved gas GHS Pictograms Signal Word Warning Warning Warning Warning Hazard Statement H280: Contains gas under pressure; may explode if heated H280: Contains gas under pressure; may explode if heated H281: Contains refrigerated gas; may cause cryogenic burns or injury H280: Contains gas under pressure; may explode if heated Precautionary Statement Prevention P282 Precautionary Statement Response P336 P315 Precautionary Statement Storage P410 + P403 P410 + P403 P403 P410 + P403 Precautionary Statement Disposal Note: Precautionary Statement Prevention P282 Precautionary Statement Response P336 + P315 Precautionary Statement Storage P410 + P403 P410 + P403 P403 P410 + P403 Precautionary Statement Disposal Note: Pictogram GHS04 is not required for gases under pressure where pictogram GHS02 or pictogram GHS06 appears. 2.5.4. Additional Classification Considerations For this group of gases, the following information is required to be known: … 173 unchanged lines … Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.8.1. Table 2.8.1 Label elements for self-reactive substances and mixtures Type G has no hazard communication elements assigned but should be considered for properties belonging to other hazard classes.See the introduction to Annex IV for details on the use of square brackets. Classification Type A Type B Type C & D Type E & F Type G GHS Pictograms There are no label elements allocated to this hazard category Signal Word Danger Danger Danger Warning Hazard Statement H240: Heating may cause an explosion H241: Heating may cause a fire or explosion H242: Heating may cause a fire H242: Heating may cause a fire Precautionary Statement Prevention P210 P220 Precautionary Statement Prevention P210 P234 P235 P240 P280 P210 P220 P234 P235 P240 P280 P210 P220 P234 P235 P240 P280 P210 P220 P234 P235 P240 P280 Precautionary Statement Response P370 + P378 P370 + P380 + P375 P370 + P378 P370 + P380 + P375 P370 + P378 P370 + P378 Precautionary Statement Storage P403 + P235 Precautionary Statement Response P370 + P372 + P380 + P373 P370 + P380 + P375 [+ P378] P370 + P378 P370 + P378 Precautionary Statement Storage P403 P411 P420 P403 + P235 P420 P403 P411 P420 P403 + P235 P420 P403 P411 P420 P403 + P235 P411 P420 Precautionary Statement Disposal P501 P501 P501 P501 Type G has no hazard communication elements assigned but shall be considered for properties belonging to other hazard classes. P420 P403 P411 P420 Precautionary Statement Disposal P501 P501 P501 P501 Type G has no hazard communication elements assigned but shall be considered for properties belonging to other hazard classes. 2.8.4. Additional Classification Considerations 2.8.4.1. The properties of self-reactive substances or mixtures which are decisive for their classification shall be determined experimentally. The classification of a self reactive substance or mixture shall be performed in accordance with test series A to H as described in Part II of the UN RTDG, Manual of Tests and Criteria. The procedure for classification is described in Figure 2.8.1. 2.8.4.2. The classification procedures for self-reactive substances and mixtures need not be applied if: (a) There are no chemical groups present in the molecule associated with explosive or self reactive properties. Examples of such groups are given in Tables A6.1 and A6.2 in Appendix 6 of the UN RTDG, Manual of Tests and Criteria; or (b) For a single organic substance or a homogeneous mixture of organic substances, the estimated SADT for a 50 kg package is greater than 75 oC or the exothermic decomposition energy is less than 300J/g. The onset temperature and decomposition energy can be estimated using a suitable calorimetric technique (see Part II, sub-section 20.3.3.3 of the UN RTDG, Manual of Tests and Criteria). Figure 2.8.1 Self-reactive substances and mixtures SUBSTANCE/MIXTURE Box 1 Test A Box 2 Test B 1.1 Yes Does it propogate a detonation? 1.3 No 2.1 Yes Can it detonate as packaged? 2.2 No 1.2 Partial Box 3 Test C Can it propogate a deflagration? 3.1 Yes, rapidly Box 4 Test C Can it propogate a deflagration? 4.1 Yes, rapidly Type B Type A Type G Type F Type E Type D Type C 6.1 Yes 7.1 Violent Box 10 Test G 10.2 No 7.2 Medium 7.3 Low 7.4 None 8.1 Violent 8.2 Medium 8.3 Low 8.4 None 9.1 Violent 9.2 Medium 16.2 No 16.1 Yes Is a diluent with a boiling point of < 150 °C used? Box 16 15.2 No 15.1 Yes Is the substance a solid? Box 14 Test H 14.1 Yes 13.1 Low 12.2 Low What is the effect of heating it under defined confine- ment? Box 13 Test E 12.1 Not low 12.3 None Box 12 Test F 5.2 Yes, slowly 11.1 Yes Packaged in packages of more than 400 kg/450 l or to be considered for exemption? What is the effect of heating it under defined confinement? 9.3 Low 9.4 None Box 9 Test E Box 8 Test E What is the effect of heating it under defined confinement? What is the effect of heating it under defined confinement? Box 7 Test E 6.2 No Does it deflagrate rapidly in package? Box 6 Test D 5.1 Yes rapidly Box 5 Test C Can it propagate a defla-gration? 3.2 Yes, slowly 3.3 No Box 5 Test C Can it propogate a deflagration? 5.1 Yes, rapidly 4.2 Yes, slowly 4.3 No Box 6 Test D Can it propagate a defla-gration? Box 4 Test C 4.1 Yes, rapidly Box 2 Test B Box 3 Test C Can it propagate a defla-gration? Does it propagate a deto-nation? 10.1 Yes 11.2 No 13.2 None 14.2 No Box 15 Box 11 Box 1 Test A 5.3 No 5.2 Yes, slowly 6.2 No Does it deflagrate rapidly in package? 6.1 Yes Box 7 Test E What is the effect of heating under confinement? 7.1 Violent Box 8 Test E What is the effect of heating under confinement? 8.1 Violent 7.2 Medium 7.3 Low 7.4 No Box 9 Test E What is the effect of heating under confinement? Box 10 Test G 8.2 Medium 8.3 Low 8.4 No 9.3 Low 9.4 No Box 11 10.2 No 1.2 Partial 1.3 No 3.1 Yes, rapidly 2.2 No 2.1 Yes 1.1 Yes Is the SADT <60°C in a 50 kg package? What is its explosive power? Can it explode as packaged? 10.1 Yes Packaged in packages of more than 400 kg/450 l or to be considered for exemption? 11.1 Yes Box F Test F What is its explosive power? 12.3 None Box 13 Test E 12.1 No low 12.2 Low What is effect of heating it under defined confinement? 11.2 No 13.1 Low 13.2 None TYPE A TYPE B TYPE C TYPE D TYPE E TYPE F TYPE G 9.1 violent 9.2 Medium Can it detonate as packaged? SUBSTANCE/MIXTURE 2.9. Pyrophoric liquids 2.9.1. Definition Pyrophoric liquid means a liquid substance or mixture which, even in small quantities, is liable to ignite within five minutes after coming into contact with air. 2.9.2. Classification criteria 2.9.2.1. A pyrophoric liquid shall be classified in a single category for this class using test N.3 in Part III, sub-section 33.3.1.5 of the UN RTDG, Manual of Tests and Criteria according to Table 2.9.1: Table 2.9.1 Criteria for pyrophoric liquids Category Criteria 1 The liquid ignites within 5 min when added to an inert carrier and exposed to air, or it ignites or chars a filter paper on contact with air within 5 min. 2.9.3. Hazard Communication Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.9.2. Table 2.9.2 Label elements for pyrophoric liquids Classification Category 1 Classification Category 1 GHS Pictogram Signal Word Danger Hazard Statement H250: Catches fire spontaneously if exposed to air Precautionary Statement Prevention P210 Precautionary Statement Prevention P210 P222 P231 + P232 P233 P280 Precautionary Statement Response P302 + P334 Precautionary Statement Response P302 + P334 P370 + P378 Precautionary Statement Storage P422 Precautionary Statement Disposal 2.9.4. Additional Classification Considerations Precautionary Statement Storage Precautionary Statement Disposal 2.9.4. Additional Classification Considerations 2.9.4.1. The classification procedure for pyrophoric liquids need not be applied when experience in manufacture or handling shows that the substance or mixture does not ignite spontaneously on coming into contact with air at normal temperatures (i.e. the substance is known to be stable at room temperature for prolonged periods of time (days)). 2.10. Pyrophoric solids 2.10.1. Definition Pyrophoric solid means a solid substance or mixture which, even in small quantities, is liable to ignite within five minutes after coming into contact with air. 2.10.2. Classification criteria 2.10.2.1. A pyrophoric solid shall be classified in a single category for this class using test N.2 in Part III, sub-section 33.3.1.4 of the UN RTDG, Manual of Tests and Criteria in accordance with Table 2.10.1: Table 2.10.1 Criteria for pyrophoric solids Category Criteria 1 The solid ignites within 5 minutes of coming into contact with air. Note The test shall be performed on the substance or mixture in its physical form as presented. If, for example, for the purposes of supply or transport, the same chemical is to be presented in a physical form different from that which was tested and which is considered likely to materially alter its performance in a classification test, the substance shall also be tested in the new form. 2.10.3. Hazard Communication Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.10.2. Table 2.10.2 Label elements for pyrophoric solids Classification Category 1 Classification Category 1 GHS Pictogram Signal Word Danger Hazard Statement H250: Catches fire spontaneously if exposed to air Precautionary Statement Prevention P210 Precautionary Statement Prevention P210 P222 P231 + P232 P233 P280 Precautionary Statement Response P335 + P334 Precautionary Statement Response P302 + P335 + P334 P370 +P378 Precautionary Statement Storage P422 Precautionary Statement Disposal 2.10.4. Additional Classification Considerations Precautionary Statement Storage Precautionary Statement Disposal 2.10.4. Additional Classification Considerations 2.10.4.1. The classification procedure for pyrophoric solids need not be applied when experience in manufacture or handling shows that the substance or mixture does not ignite spontaneously on coming into contact with air at normal temperatures (i.e. the substance is known to be stable at room temperature for prolonged periods of time (days)). 2.11. Self-heating substances and mixtures 2.11.1. Definition … 21 unchanged lines … Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.11.2. Table 2.11.2 Label elements for self-heating substances and mixtures Classification Category 1 Category 2 Classification Category 1 Category 2 GHS Pictograms Signal Word Danger Warning Hazard Statement H251: Self-heating; may catch fire H252: Self-heating in large quantities; may catch fire Precautionary Statement Prevention P235 + P410 P280 P235 + P410 Precautionary Statement Prevention P235 P280 P235 P280 Precautionary Statement Response Precautionary Statement Storage P407 Precautionary Statement Response Precautionary Statement Storage P407 P413 P420 P407 P413 P420 Precautionary Statement Disposal 2.11.4. Additional Classification Considerations Precautionary Statement Disposal 2.11.4. Additional Classification Considerations 2.11.4.1. For detailed schemes for the decision logic for classification and the tests to be carried out for ascertaining the different categories, see Figure 2.11.1. 2.11.4.2. The classification procedure for self-heating substances or mixtures need not be applied if the results of a screening test can be adequately correlated with the classification test and an appropriate safety margin is applied. Examples of screening tests are: (a) The Grewer Oven test (VDI guideline 2263, Part 1, 1990, Test methods for the Determination of the Safety Characteristics of Dusts) with an onset temperature 80 K above the reference temperature for a volume of 1 l; … 47 unchanged lines … 2.12.3. Hazard Communication Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.12.2. Table 2.12.2 Label elements for substances or mixtures which in contact with water emit flammable gases Classification Category 1 Category 2 Category 3 Label elements for substances and mixtures which in contact with water emit flammable gases Classification Category 1 Category 2 Category 3 GHS Pictograms Signal Word Danger Danger Warning Hazard Statement H260: In contact with water releases flammable gases which may ignite spontaneously H261: In contact with water releases flammable gases H261: In contact with water releases flammable gases Precautionary Statement Prevention P223 Precautionary Statement Prevention P223 P231 + P232 P280 P223 P231 + P232 P280 P231 + P232 P280 Precautionary Statement Response P335 + P334 P370 + P378 P335 + P334 Precautionary Statement Response P302 + P335 + P334 P370 + P378 P302 + P335 + P334 P370 + P378 P370 + P378 Precautionary Statement Storage P402 + P404 P402 + P404 P402 + P404 Precautionary Statement Disposal P501 P501 P501 Precautionary Statement Storage P402 + P404 P402 + P404 P402 + P404 Precautionary Statement Disposal P501 P501 P501 2.12.4. Additional Classification Considerations 2.12.4.1. The classification procedure for this class need not be applied if: (a) the chemical structure of the substance or mixture does not contain metals or metalloids; or (b) experience in production or handling shows that the substance or mixture does not react with water, e.g. the substance is manufactured with water or washed with water; or (c) the substance or mixture is known to be soluble in water to form a stable mixture. 2.13. Oxidising liquids 2.13.1. Definition Oxidising liquid means a liquid substance or mixture which, while in itself not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material. 2.13.2. Classification criteria 2.13.2.1. An oxidising liquid shall be classified in one of the three categories for this class using test O.2 in Part III, sub-section 34.4.2 of the UN RTDG, Manual of Tests and Criteria in accordance with Table 2.13.1: Table 2.13.1 Criteria for oxidising liquids Category Criteria 1 Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and cellulose tested, spontaneously ignites; or the mean pressure rise time of a 1:1 mixture, by mass, of substance (or mixture) and cellulose is less than that of a 1:1 mixture, by mass, of 50 % perchloric acid and cellulose. 2 Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 40 % aqueous sodium chlorate solution and cellulose; and the criteria for Category 1 are not met. 3 Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 65 % aqueous nitric acid and cellulose; and the criteria for Category 1 and 2 are not met. 2.13.3. Hazard Communication Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.13.2. Table 2.13.2 Label elements for oxidising liquids Classification Category 1 Category 2 Category 3 Classification Category 1 Category 2 Category 3 GHS Pictograms Signal Word Danger Danger Warning Hazard Statement H271:May cause fire or explosion; strong oxidiser H272: May intensify fire; oxidiser H272: May intensify fire; oxidiser Precautionary Statement Prevention P210 Hazard Statement H271: May cause fire or explosion; strong oxidiser H272: May intensify fire; oxidiser H272: May intensify fire; oxidiser Precautionary Statement Prevention P210 P220 P221 P280 P283 P210 P220 P221 P280 P210 P220 P221 P280 Precautionary Statement Response P306 + P360 Precautionary Statement Response P306 + P360 P371 + P380 + P375 P370 + P378 P370 + P378 P370 + P378 Precautionary Statement Storage Precautionary Statement Disposal P501 P501 P501 Precautionary Statement Storage P420 Precautionary Statement Disposal P501 P501 P501 2.13.4. Additional Classification Considerations 2.13.4.1. For organic substances or mixtures the classification procedure for this class shall not apply if: (a) the substance or mixture does not contain oxygen, fluorine or chlorine; or (b) the substance or mixture contains oxygen, fluorine or chlorine and these elements are chemically bonded only to carbon or hydrogen. 2.13.4.2. For inorganic substances or mixtures the classification procedure for this class shall not apply if they do not contain oxygen or halogen atoms. 2.13.4.3. In the event of divergence between test results and known experience in the handling and use of substances or mixtures which shows them to be oxidising, judgments based on known experience shall take precedence over test results. 2.13.4.4. In cases where substances or mixtures generate a pressure rise (too high or too low), caused by chemical reactions not characterising the oxidising properties of the substance or mixture, the test described in Part III, sub-section 34.4.2 of the UN RTDG, Manual of Tests and Criteria shall be repeated with an inert substance, e.g. diatomite (kieselguhr), in place of the cellulose in order to clarify the nature of the reaction and to check for a false positive result. 2.14. Oxidising solids 2.14.1. Definition Oxidising solid means a solid substance or mixture which, while in itself is not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material. 2.14.2. Classification criteria 2.14.2.1. An oxidising solid shall be classified in one of the three categories for this class using test O.1 in Part III, sub-section 34.4.1 of the UN RTDG, Manual of Tests and Criteria in accordance with Table 2.14.1: 2.14.2.1. An oxidising solid shall be classified in one of the three categories for this class using test O.1 in Part III, sub-section 34.4.1 or test O.3 in Part III, sub-section 34.4 3 of the UN RTDG, Manual of Tests and Criteria in accordance with Table 2.14.1: Table 2.14.1 Criteria for oxidising solids Category Criteria 1 Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time less than the mean burning time of a 3:2 mixture, by mass, of potassium bromate and cellulose. 2 Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 2:3 mixture (by mass) of potassium bromate and cellulose and the criteria for Category 1 are not met. 3 Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 3:7 mixture (by mass) of potassium bromate and cellulose and the criteria for Categories 1 and 2 are not met. Category Criteria using test O.1 Criteria using test O.3 1 Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time less than the mean burning time of a 3:2 mixture, (by mass), of potassium bromate and cellulose. Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning rate greater than the mean burning rate of a 3:1 mixture (by mass) of calcium peroxide and cellulose. 2 Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 2:3 mixture (by mass) of potassium bromate and cellulose and the criteria for Category 1 are not met. Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning rate equal to or greater than the mean burning rate of a 1:1 mixture (by mass) of calcium peroxide and cellulose and the criteria for Category 1 are not met. 3 Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 3:7 mixture (by mass) of potassium bromate and cellulose and the criteria for Categories 1 and 2 are not met. Any substance or mixture which, in the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning rate equal to or greater than the mean burning rate of a 1:2 mixture (by mass) of calcium peroxide and cellulose and the criteria for Categories 1 and 2 are not met. Note 1 Some oxidising solids also present explosion hazards under certain conditions (when stored in large quantities). Some types of ammonium nitrate may give rise to an explosion hazard under extreme conditions and the Resistance to detonation test (BC Code, Annex 3, Test 5) can be used to assess this hazard. Appropriate information shall be made in the SDS. Some oxidising solids also present explosion hazards under certain conditions (when stored in large quantities). Some types of ammonium nitrate may give rise to an explosion hazard under extreme conditions and the Resistance to detonation test (IMSBC Code (International Maritime Solid Bulk Cargoes Code, IMO), Appendix 2, Section 5) can be used to assess this hazard. Appropriate information shall be made in the SDS. Note 2 The test shall be performed on the substance or mixture in its physical form as presented. If, for example, for the purposes of supply or transport, the same chemical is to be presented in a physical form different from that which was tested and which is considered likely to materially alter its performance in a classification test, the substance shall also be tested in the new form. 2.14.3. Hazard Communication Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.14.2. Table 2.14.2 Label elements for oxidising solids Category 1 Category 2 Category 3 Category 1 Category 2 Category 3 GHS Pictograms Signal Word Danger Danger Warning Hazard Statement H271: May cause fire or explosion; strong oxidiser H272: May intensify fire; oxidiser H272: May intensify fire; oxidiser Precautionary Statement Prevention P210 Precautionary Statement Prevention P210 P220 P221 P280 P283 P210 P220 P221 P280 P210 P220 P221 P280 Precautionary Statement Response P306 + P360 Precautionary Statement Response P306 + P360 P371 + P380 + P375 P370 + P378 P370 + P378 P370 + P378 Precautionary Statement Storage Precautionary Statement Disposal P501 P501 P501 Precautionary Statement Storage P420 Precautionary Statement Disposal P501 P501 P501 2.14.4. Additional Classification Considerations 2.14.4.1. For organic substances or mixtures the classification procedure for this class shall not apply if: (a) the substance or mixture does not contain oxygen, fluorine or chlorine; or … 45 unchanged lines … Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 2.15.1. Table 2.15.1 Label elements for organic peroxides See the introduction to Annex IV for details on the use of square brackets. Classification Type A Type B Type C & D Type E & F Type G GHS Pictograms There are no label elements allocated to this hazard category Signal Word Danger Danger Danger Warning Hazard Statement H240: Heating may cause an explosion H241: Heating may cause a fire or explosion H242: Heating may cause a fire H242: Heating may cause a fire Precautionary Statement Prevention P210 P220 Precautionary Statement Prevention P210 P234 P235 P240 P280 P210 P220 P234 P235 P240 P280 P210 P220 P234 P235 P240 P280 P210 P220 P234 P235 P240 P280 Precautionary Statement Response Precautionary Statement Storage P411 + P235 Precautionary Statement Response P370 + P372 + P380 + P373 P370 + P380 + P375[+ P378] P370 + P378 P370 + P378 Precautionary Statement Storage P403 P410 P420 P411 + P235 P411 P420 P403 P410 P420 P411 + P235 P411 P420 P403 P410 P420 P411 + P235 P411 P420 P403 P410 P420 Precautionary Statement Disposal P501 P501 P501 P501 Type G has no hazard communication elements assigned but shall be considered for properties belonging to other hazard classes. P411 P420 Precautionary Statement Disposal P501 P501 P501 P501 Type G has no hazard communication elements assigned but shall be considered for properties belonging to other hazard classes. 2.15.4. Additional Classification Considerations 2.15.4.1. Organic peroxides are classified by definition based on their chemical structure and on the available oxygen and hydrogen peroxide contents of the mixture (see 2.15.2.1). The properties of organic peroxides which are necessary for their classification shall be determined experimentally. The classification of organic peroxides shall be performed in accordance with test series A to H as described in Part II of the UN RTDG, Manual of Tests and Criteria. The procedure for classification is described in Figure 2.15.1. 2.15.4.2. Mixtures of already classified organic peroxides may be classified as the same type of organic peroxide as that of the most dangerous component. However, as two stable components can form a thermally less stable mixture, the SADT of the mixture shall be determined. Note: The sum of the individual parts can be more hazardous than the individual components. Figure 2.15.1 Organic Peroxides SUBSTANCE/MIXTURE Box 1 Test A Box 2 Test B 1.1 Yes Does it propogate a detonation? Type F Type E Type D Type C Type B Type A Type G 1.3 No 2.1 Yes Can it detonate as packaged? 2.2 No 1.2 Partial Box 3 Test C Can it propogate a detonation? 3.1 Yes, rapidly Box 4 Test C Can it propogate a detonation? 6.1 Yes 7.1 Violent Box 10 Test G 10.2 No 7.2 Medium 7.3 Low 7.4 None 8.1 Violent 8.2 Medium 8.3 Low 8.4 None 9.1 Violent 9.2 Medium 16.2 No 16.1 Yes Is a diluent with a boiling point of < 150 °C used? Box 16 15.2 No 15.1 Yes Is the substance a solid? Box 14 Test H 14.1 Yes 13.1 Low 12.2 Low What is the effect of heating it under defined confine- ment? Box 13 Test E 12.1 Not low 12.3 None Box 12 Test F 5.2 Yes, slowly 11.1 Yes Packaged in packages of more than 400 kg/450 l or to be considered for exemption? What is the effect of heating it under defined confinement? 9.3 Low 9.4 None Box 9 Test E Box 8 Test E What is the effect of heating it under defined confinement? What is the effect of heating it under defined confinement? Box 7 Test E 6.2 No Does it deflagrate rapidly in package? Box 6 Test D 5.1 Yes rapidly Box 5 Test C Box 6 Test D Can it propagate a defla-gration? 3.2 Yes, slowly 3.3 No 4.1 Yes rapidly Can it propogate a detonation? 4.2 Yes, slowly 5.1 Yes, rapidly 4.3 No Can it propagate a defla-gration? Box 4 Test C 4.1 Yes, rapidly Box 2 Test B Box 3 Test C Can it propagate a defla-gration? Does it propagate a deto-nation? 10.1 Yes 11.2 No 13.2 None 14.2 No Box 15 Box 11 Box 1 Test A 5.3 No Does it deflagrate rapidly in package? 6.2 No Box 7 Test E 5.2 Yes, slowly 6.1 Yes What is the effect of heating under confinement? Box 8 Test E 7.1 Violent What is the effect of heating under confinement? Box 9 Test E 7.2 Medium 8.1 Violent 7.3 Low 7.4 No What is the effect of heating under confinement? Box 10 Test G 9.3 Low 8.2 Medium 9.1 Violent 8.3 Low 9.4 No 1.2 Partial 3.1 Yes, rapidly 2.2 No 2.1 Yes 1.1 Yes Is the SADT <60°C in a 50 kg package? What is its explosive power? Can it explode as packaged? 10.2 No 8.4 No 9.2 Medium Box 11 Packaged in packages of more than 400 kg/450 l or to be considered for exemption? 11.1 Yes Box 12 Test F 11.2 No What is its explosive power? 12.3 None 10.1 Yes 12.1 Not low Box 13 Test E 12.2 Low What is the effect of heating it under confinement? 13.1 Low 13.2 None TYPE A TYPE B TYPE C TYPE D TYPE E TYPE F TYPE G Can it detonate as packaged? ORGANIC PEROXIDE 2.16. Corrosive to metals 2.16.1. Definition A substance or a mixture that is corrosive to metals means a substance or a mixture which by chemical action will materially damage, or even destroy, metals. … 36 unchanged lines … Acute dermal toxicity; Acute inhalation toxicity. 3.1.2. Criteria for classification of substances as acutely toxic 3.1.2.1. Substances can be allocated to one of four toxicity categories based on acute toxicity by the oral, dermal or inhalation route according to the numeric criteria shown in Table 3.1.1. Acute toxicity values are expressed as (approximate) LD50 (oral, dermal) or LC50 (inhalation) values or as acute toxicity estimates (ATE). Explanatory notes are shown following Table 3.1.1. 3.1.2.1. Substances can be allocated to one of four hazard categories based on acute toxicity by the oral, dermal or inhalation route according to the numeric criteria shown in Table 3.1.1. Acute toxicity values are expressed as (approximate) LD50 (oral, dermal) or LC50 (inhalation) values or as acute toxicity estimates (ATE). Explanatory notes are shown following Table 3.1.1. Table 3.1.1 Acute toxicity hazard categories and acute toxicity estimates (ATE) defining the respective categories Gas concentrations are expressed in parts per million per volume (ppmV). … 34 unchanged lines … 3.1.2.2.1. The preferred test species for evaluation of acute toxicity by the oral and inhalation routes is the rat, while the rat or rabbit are preferred for evaluation of acute dermal toxicity. When experimental data for acute toxicity are available in several animal species, scientific judgement shall be used in selecting the most appropriate LD50 value from among valid, well-performed tests. 3.1.2.3. Specific considerations for classification of substances as acutely toxic by the inhalation route 3.1.2.3.1. Units for inhalation toxicity are a function of the form of the inhaled material. Values for dusts and mists are expressed in mg/l. Values for gases are expressed in ppmV. Acknowledging the difficulties in testing vapours, some of which consist of mixtures of liquid and vapour phases, the table provides values in units of mg/l. However, for those vapours which are near the gaseous phase, classification shall be based on ppmV. 3.1.2.3.2. Of particular importance in classifying for inhalation toxicity is the use of well articulated values in the high toxicity categories for dusts and mists. Inhaled particles between 1 and 4 microns mean mass aerodynamic diameter (MMAD) will deposit in all regions of the rat respiratory tract. This particle size range corresponds to a maximum dose of about 2 mg/l. In order to achieve applicability of animal experiments to human exposure, dusts and mists would ideally be tested in this range in rats. 3.1.2.3.2. Of particular importance in classifying for inhalation toxicity is the use of well articulated values in the highest hazard categories for dusts and mists. Inhaled particles between 1 and 4 microns mean mass aerodynamic diameter (MMAD) will deposit in all regions of the rat respiratory tract. This particle size range corresponds to a maximum dose of about 2 mg/l. In order to achieve applicability of animal experiments to human exposure, dusts and mists would ideally be tested in this range in rats. 3.1.2.3.3. In addition to classification for inhalation toxicity, if data are available that indicates that the mechanism of toxicity was corrosivity, the substance or mixture shall also be labelled as corrosive to the respiratory tract (see note 1 in 3.1.4.1). Corrosion of the respiratory tract is defined by destruction of the respiratory tract tissue after a single, limited period of exposure analogous to skin corrosion; this includes destruction of the mucosa. The corrosivity evaluation can be based on expert judgment using such evidence as: human and animal experience, existing (in vitro) data, pH values, information from similar substances or any other pertinent data. 3.1.3. Criteria for classification of mixtures as acutely toxic 3.1.3.1. The criteria for classification of substances for acute toxicity as outlined in section 3.1.2 are based on lethal dose data (tested or derived). For mixtures, it is necessary to obtain or derive information that allows the criteria to be applied to the mixture for the purpose of classification. The approach to classification for acute toxicity is tiered, and is dependent upon the amount of information available for the mixture itself and for its ingredients. The flow chart of Figure 3.1.1 outlines the process to be followed. … 35 unchanged lines … 3.1.3.6. Classification of mixtures based on ingredients of the mixture (Additivity formula) 3.1.3.6.1. Data available for all ingredients In order to ensure that classification of the mixture is accurate, and that the calculation need only be performed once for all systems, sectors, and categories, the acute toxicity estimate (ATE) of ingredients shall be considered as follows: (a) include ingredients with a known acute toxicity, which fall into any of the acute toxicity categories shown in Table 3.1.1; (a) include ingredients with a known acute toxicity, which fall into any of the acute hazard categories shown in Table 3.1.1; (b) ignore ingredients that are presumed not acutely toxic (e.g., water, sugar); (c) ignore components if the data available are from a limit dose test (at the upper threshold for Category 4 for the appropriate route of exposure as provided in Table 3.1.1) and do not show acute toxicity. Components that fall within the scope of this section are considered to be components with a known acute toxicity estimate (ATE). See note (b) to Table 3.1.1 and section 3.1.3.3 for appropriate application of available data to the equation below, and section 3.1.3.6.2.3. … 134 unchanged lines … In the event that an ingredient without any useable information at all is used in a mixture at a concentration of 1 % or greater, the mixture shall be labelled with the additional statement that x percent of the mixture consists of ingredient(s) of unknown toxicity — see advice at 3.1.3.6.2.2. 3.1.4.2. The acute toxicity hazard statements differentiate the hazard based on the route of exposure. Communication of acute toxicity classification should also reflect this differentiation. If a substance or mixture is classified for more than one route of exposure then all relevant classifications should be communicated on the safety data sheet as specified in Annex II to Regulation (EC) No 1907/2006 and the relevant hazard communication elements included on the label as prescribed in section 3.1.3.2. If the statement x % of the mixture consists of ingredient(s) of unknown acute toxicity is communicated, as prescribed in section 3.1.3.6.2.2, then, in the information provided in the safety data sheet, it can also be differentiated based on the route of exposure. For example, x % of the mixture consists of ingredient(s) of unknown acute oral toxicity and x % of the mixture consists of ingredient(s) of unknown acute dermal toxicity. 3.2. Skin corrosion/irritation 3.2.1. Definitions 3.2.1.1. Skin Corrosion means the production of irreversible damage to the skin; namely, visible necrosis through the epidermis and into the dermis, following the application of a test substance for up to 4 hours. Corrosive reactions are typified by ulcers, bleeding, bloody scabs, and, by the end of observation at 14 days, by discolouration due to blanching of the skin, complete areas of alopecia, and scars. Histopathology shall be considered to evaluate questionable lesions. Skin Irritation means the production of reversible damage to the skin following the application of a test substance for up to 4 hours. 3.2.1. Definitions and general considerations 3.2.1.1. Skin corrosion means the production of irreversible damage to the skin; namely, visible necrosis through the epidermis and into the dermis, following the application of a test substance for up to 4 hours. Corrosive reactions are typified by ulcers, bleeding, bloody scabs, and, by the end of observation at 14 days, by discolouration due to blanching of the skin, complete areas of alopecia, and scars. Histopathology shall be considered to evaluate questionable lesions. Skin irritation means the production of reversible damage to the skin following the application of a test substance for up to 4 hours. 3.2.1.2. In a tiered approach, emphasis shall be placed upon existing human data, followed by existing animal data, followed by in vitro data and then other sources of information. Classification results directly when the data satisfy the criteria. In some cases, classification of a substance or a mixture is made on the basis of the weight of evidence within a tier. In a total weight of evidence approach all available information bearing on the determination of skin corrosion/irritation is considered together, including the results of appropriate validated in vitro tests, relevant animal data, and human data such as epidemiological and clinical studies and well-documented case reports and observations (see Annex I, Part 1, Sections 1.1.1.3, 1.1.1.4 and 1.1.1.5). 3.2.2. Classification criteria for substances 3.2.2.1. Several factors need to be considered in determining the corrosion and irritation potential of substances before testing is undertaken. Solid substances (powders) may become corrosive or irritant when moistened or in contact with moist skin or mucous membranes. Existing human experience and animal data from single or repeated exposure shall be the first line of analysis, as they give information directly relevant to effects on the skin. In vitro alternatives that have been validated and accepted may also be used to help make classification decisions (see Article 5). In some cases enough information may be available from structurally related compounds to make classification decisions. 3.2.2.2. Likewise, pH extremes like ≤ 2 and ≥ 11,5 may indicate the potential to cause skin effects, especially when buffering capacity is known, although the correlation is not perfect. Generally, such substances are expected to produce significant effects on the skin. If consideration of alkali/acid reserve suggests the substance may not be corrosive despite the low or high pH value, then further testing shall be carried out to confirm this, preferably by use of an appropriate validated in vitro test. 3.2.2.3. If a substance is highly toxic by the dermal route, a skin irritation/corrosion study is not practicable since the amount of test substance to be applied considerably exceeds the toxic dose and, consequently, results in the death of the animals. When observations are made of skin irritation/corrosion in acute toxicity studies and are observed up through the limit dose, additional testing is not needed, provided that the dilutions used and species tested are equivalent. 3.2.2.4. All the above information that is available on a substance shall be used in determining the need for in vivo skin irritation testing. Although information might be gained from the evaluation of single parameters within a tier (see paragraph 3.2.2.5), e.g. caustic alkalis with extreme pH shall be considered as skin corrosives, there is merit in considering the totality of existing information and making an overall weight of evidence determination. This is especially true when there is information available on some but not all parameters. Generally, primary emphasis shall be placed upon existing human experience and data, followed by animal experience and testing data, followed by other sources of information, but case-by-case determinations are necessary. 3.2.2.5. A tiered approach to the evaluation of initial information shall be considered, where applicable, recognising that all elements may not be relevant in certain cases. 3.2.2.6. Corrosion 3.2.2.6.1. On the basis of the results of animal testing a substance is classified as corrosive, as shown in Table 3.2.1. A corrosive substance is a substance that produces destruction of skin tissue, namely, visible necrosis through the epidermis and into the dermis, in at least 1 tested animal after exposure up to a 4 hour duration. Corrosive reactions are typified by ulcers, bleeding, bloody scabs and, by the end of observation at 14 days, by discoloration due to blanching of the skin, complete areas of alopecia and scars. Histopathology shall be considered to discern questionable lesions. 3.2.2.6.2. Three subcategories are provided within the corrosive category: subcategory 1A — where responses are noted following up to 3 minutes exposure and up to 1 hour observation; subcategory 1B — where responses are described following exposure between 3 minutes and 1 hour and observations up to 14 days; and subcategory 1C — where responses occur after exposures between 1 hour and 4 hours and observations up to 14 days. 3.2.2.6.3. The use of human data is discussed in paragraphs 3.2.2.1 and 3.2.2.4 and also in paragraphs 1.1.1.3, 1.1.1.4 and.1.1.1.5. Substances shall be allocated to one of the following two categories within this hazard class: (a) Category 1 (skin corrosion) This category is further subdivided in three sub-categories (1A, 1B, 1C). Corrosive substances shall be classified in Category 1 where data is not sufficient for sub-categorisation. When data are sufficient, substances shall be classified in one of the three sub-categories 1A, 1B, or 1C (see Table 3.2.1.) (b) Category 2 (skin irritation) (see Table 3.2.2). 3.2.2.1. Classification based on standard animal test data 3.2.2.1.1. Skin corrosion 3.2.2.1.1.1. A substance is corrosive to skin when it produces destruction of skin tissue, namely, visible necrosis through the epidermis and into the dermis in at least one tested animal after exposure for up to 4 hours. 3.2.2.1.1.2. Corrosive substances shall be classified in Category 1 where data is not sufficient for sub-categorisation. 3.2.2.1.1.3. When data are sufficient substances shall be classified in one of the three sub-categories 1A, 1B, or 1C in accordance with the criteria in Table 3.2.1. 3.2.2.1.1.4. Three sub-categories are provided within the corrosion category: sub-category 1A — where corrosive responses are noted following up to 3 minutes exposure and up to 1 hour observation; sub-category 1B — where corrosive responses are described following exposure greater than 3 minutes and up to 1 hour and observations up to 14 days; and sub-category 1C — where corrosive responses occur after exposures greater than 1 hour and up to 4 hours and observations up to 14 days. Table 3.2.1 Skin Corrosive category and subcategories Corrosive in > 1 of 3 animals Corrosive subcategories Exposure Observation Category 1: Corrosive 1A ≤ 3 minutes ≤ 1 hour 1B > 3 minutes - ≤ 1 hour ≤ 14 days 1C > 1 hour - ≤ 4 hours ≤ 14 days 3.2.2.7. Irritation 3.2.2.7.1. Using the results of animal testing a single irritant category (Category 2) is presented in Table 3.2.2. The use of human data is discussed in paragraphs 3.2.2.1 and 3.2.2.4 and also in paragraphs 1.1.1.3, 1.1.1.4 and.1.1.1.5. The major criterion for the irritant category is that at least 2 of 3 tested animals have a mean score of ≥ 2,3 - ≤ 4,0. Skin corrosion category and sub-categories See the conditions for the use of Category 1 in paragraph (a) of Section 3.2.2. Category Criteria Category 1 Destruction of skin tissue, namely, visible necrosis through the epidermis and into the dermis, in at least one tested animal after exposure ≤ 4 h Sub-Category 1A Corrosive responses in at least one animal following exposure ≤ 3 min during an observation period ≤ 1 h Sub-Category 1B Corrosive responses in at least one animal following exposure > 3 min and ≤ 1 h and observations ≤ 14 days Sub-Category 1C Corrosive responses in at least one animal after exposures > 1 h and ≤ 4 h and observations ≤ 14 days 3.2.2.1.1.5. The use of human data is discussed in Sections 3.2.1.2 and 3.2.2.2 and also in Sections 1.1.1.3, 1.1.1.4 and 1.1.1.5. 3.2.2.1.2. Skin irritation 3.2.2.1.2.1. A substance is irritant to skin when it produces reversible damage to the skin following its application for up to 4 hours. The major criterion for the irritation category is that at least 2 of 3 tested animals have a mean score of ≥ 2,3 and ≤ 4,0. 3.2.2.1.2.2. A single irritation category (Category 2) is presented in Table 3.2.2, using the results of animal testing. 3.2.2.1.2.3. Reversibility of skin lesions is also considered in evaluating irritant responses. When inflammation persists to the end of the observation period in 2 or more test animals, taking into consideration alopecia (limited area), hyperkeratosis, hyperplasia and scaling, then a material shall be considered to be an irritant. 3.2.2.1.2.4. Animal irritant responses within a test can be variable, as they are with corrosion. A separate irritant criterion accommodates cases where there is a significant irritant response but less than the mean score criterion for a positive test. For example, a test material might be designated as an irritant if at least 1 of 3 tested animals shows a very elevated mean score throughout the study, including lesions persisting at the end of an observation period of normally 14 days. Other responses could also fulfil this criterion. However, it should be ascertained that the responses are the result of chemical exposure. Table 3.2.2 Skin irritation category Grading criteria are understood as described in Regulation (EC) No 440/2008. Category Criteria Category 2: Irritant (1) Mean value of ≥ 2,3 - ≤ 4,0 for erythema/eschar or for oedema in at least 2 of 3 tested animals from gradings at 24, 48 and 72 hours after patch removal or, if reactions are delayed, from grades on 3 consecutive days after the onset of skin reactions; or (2) Inflammation that persists to the end of the observation period normally 14 days in at least 2 animals, particularly taking into account alopecia (limited area), hyperkeratosis, hyperplasia, and scaling; or (3) In some cases where there is pronounced variability of response among animals, with very definite positive effects related to chemical exposure in a single animal but less than the criteria above. 3.2.2.8. Comments on responses obtained in skin irritation tests in animals 3.2.2.8.1. Animal irritant responses within a test can be quite variable, as they are with corrosion. The major criterion for classification of a substance as irritant to skin, as shown in paragraph 3.2.2.7.1, is the mean value of the scores for either erythema/eschar or oedema calculated in at least 2 of 3 tested animals. A separate irritant criterion accommodates cases when there is a significant irritant response but less than the mean score criterion for a positive test. For example, a test material might be designated as an irritant if at least 1 of 3 tested animals shows a very elevated mean score throughout the study, including lesions persisting at the end of an observation period of normally 14 days. Other responses could also fulfil this criterion. However, it should be ascertained that the responses are the result of chemical exposure. 3.2.2.8.2. Reversibility of skin lesions is another consideration in evaluating irritant responses. When inflammation persists to the end of the observation period in 2 or more test animals, taking into consideration alopecia (limited area), hyperkeratosis, hyperplasia and scaling, then a material shall be considered to be an irritant. Irritation (Category 2) (1) Mean score of ≥ 2,3 and ≤ 4,0 for erythema/eschar or for oedema in at least 2 of 3 tested animals from gradings at 24, 48 and 72 hours after patch removal or, if reactions are delayed, from grades on 3 consecutive days after the onset of skin reactions; or (2) Inflammation that persists to the end of the observation period normally 14 days in at least 2 animals, particularly taking into account alopecia (limited area), hyperkeratosis, hyperplasia, and scaling reactions; or (3) In some cases where there is pronounced variability of response among animals, with very definite positive effects related to chemical exposure in a single animal but less than the criteria above . 3.2.2.1.2.5. The use of human data is discussed in Sections 3.2.1.2 and 3.2.2.2 and also in Sections 1.1.1.3, 1.1.1.4 and 1.1.1.5. 3.2.2.2. Classification in a tiered approach 3.2.2.2.1. A tiered approach to the evaluation of initial information shall be considered, where applicable, recognising that not all elements may be relevant. 3.2.2.2.2. Existing human and animal data including information from single or repeated exposure shall be the first line of evaluation, as they give information directly relevant to effects on the skin. 3.2.2.2.3. Acute dermal toxicity data may be used for classification. If a substance is highly toxic by the dermal route, a skin corrosion/irritation study is not practicable since the amount of test substance to be applied considerably exceeds the toxic dose and, consequently, results in the death of the animals. When observations are made of skin corrosion/irritation in acute toxicity studies and are observed up through the limit dose, these data may be used for classification, provided that the dilutions used and species tested are equivalent. Solid substances (powders) may become corrosive or irritant when moistened or in contact with moist skin or mucous membranes. 3.2.2.2.4. In vitro alternatives that have been validated and accepted shall be used to make classification decisions. 3.2.2.2.5. Likewise, pH extremes like ≤ 2 and ≥ 11,5 may indicate the potential to cause skin effects, especially when associated with significant acid/alkaline reserve (buffering capacity). Generally, such substances are expected to produce significant effects on the skin. In the absence of any other information, a substance is considered as corrosive to skin (Skin Corrosion Category 1) if it has a pH ≤ 2 or a pH ≥ 11,5. However, if consideration of acid/alkaline reserve suggests the substance may not be corrosive despite the low or high pH value, this needs to be confirmed by other data, preferably by data from an appropriate validated in vitro test. 3.2.2.2.6. In some cases, sufficient information may be available from structurally related substances to make classification decisions. 3.2.2.2.7. The tiered approach provides guidance on how to organize existing information on a substance and to make a weight of evidence decision about hazard assessment and hazard classification. Although information might be gained from the evaluation of single parameters within a tier (see Section 3.2.2.2.1.), consideration shall be given to the totality of existing information and making an overall weight of evidence determination. This is especially true when there is conflict in information available on some parameters. 3.2.3. Classification criteria for mixtures 3.2.3.1. Classification of mixtures when data are available for the complete mixture 3.2.3.1.1. The mixture will be classified using the criteria for substances, and taking into account the testing and evaluation strategies to develop data for these hazard classes. 3.2.3.1.2. Unlike other hazard classes, there are alternative tests available for skin corrosivity of certain types of substances and mixtures that can give an accurate result for classification purposes, as well as being simple and relatively inexpensive to perform. When considering testing of the mixture, classifiers are encouraged to use a tiered weight of evidence strategy as included in the criteria for classification of substances for skin corrosion and irritation (paragraph 3.2.2.5), to help ensure an accurate classification as well as avoid unnecessary animal testing. A mixture is considered corrosive to skin (Skin Corrosive Category 1) if it has a pH of 2 or less or a pH of 11,5 or greater. If consideration of alkali/acid reserve suggests the substance or mixture may not be corrosive despite the low or high pH value, then further testing shall be carried out to confirm this, preferably by use of an appropriate validated in vitro test. 3.2.3.1.1. The mixture shall be classified using the criteria for substances, taking into account the tiered approach to evaluate data for this hazard class. 3.2.3.1.2. When considering testing of the mixture, classifiers are encouraged to use a tiered weight of evidence approach as included in the criteria for classification of substances for skin corrosion and irritation (Sections 3.2.1.2 and 3.2.2.2), to help ensure an accurate classification as well as to avoid unnecessary animal testing. In the absence of any other information, a mixture is considered corrosive to skin (Skin Corrosion Category 1) if it has a pH ≤ 2 or a pH ≥ 11,5. However, if consideration of acid/alkaline reserve suggests the mixture may not be corrosive despite the low or high pH value, this needs to be confirmed by other data, preferably by data from an appropriate validated in vitro test. 3.2.3.2. Classification of mixtures when data are not available for the complete mixture: bridging principles 3.2.3.2.1. Where the mixture itself has not been tested to determine its skin irritation/corrosion hazards, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these data shall be used in accordance with the bridging rules set out in section 1.1.3. 3.2.3.3. Classification of mixtures when data are available for all components or only for some components of the mixture 3.2.3.3.1. In order to make use of all available data for purposes of classifying the skin irritation/corrosion hazards of mixtures, the following assumption has been made and is applied where appropriate in the tiered approach: Assumption: the relevant ingredients of a mixture are those which are present in concentrations of 1 % (w/w for solids, liquids, dusts, mists and vapours and v/v for gases) or greater, unless there is a presumption (e.g., in the case of corrosive ingredients) that an ingredient present at a concentration of less than 1 % can still be relevant for classifying the mixture for skin irritation/corrosion. 3.2.3.3.2. In general, the approach to classification of mixtures as irritant or corrosive to skin when data are available on the components, but not on the mixture as a whole, is based on the theory of additivity, such that each corrosive or irritant component contributes to the overall irritant or corrosive properties of the mixture in proportion to its potency and concentration. A weighting factor of 10 is used for corrosive components when they are present at a concentration below the generic concentration limit for classification with Category 1, but are at a concentration that will contribute to the classification of the mixture as an irritant. The mixture is classified as corrosive or irritant when the sum of the concentrations of such components exceeds a concentration limit. 3.2.3.3.3. Table 3.2.3 provides the generic concentration limits to be used to determine if the mixture is considered to be an irritant or a corrosive to the skin. 3.2.3.3.4.1. Particular care must be taken when classifying certain types of mixtures containing substances such as acids and bases, inorganic salts, aldehydes, phenols, and surfactants. The approach explained in paragraphs 3.2.3.3.1 and 3.2.3.3.2 may not be applicable given that many of such substances are corrosive or irritant at concentrations < 1 %. 3.2.3.3.4.2. For mixtures containing strong acids or bases the pH shall be used as a classification criterion (see paragraph 3.2.3.1.2) since pH is a better indicator of corrosion than the concentration limits of Table 3.2.3. 3.2.3.3.4.3. A mixture containing ingredients that are corrosive or irritant to the skin and that cannot be classified on the basis of the additivity approach (Table 3.2.3), due to chemical characteristics that make this approach unworkable, shall be classified as Skin Corrosive Category 1A, 1B or 1C if it contains ≥ 1 % of an ingredient classified in Category 1A, 1B or 1C respectively or as Category 2 when it contains ≥ 3 % of an irritant ingredient. Classification of mixtures with ingredients for which the approach in Table 3.2.3 does not apply is summarised in Table 3.2.4. 3.2.3.3.5. On occasion, reliable data may show that the skin corrosion/irritation hazard of an ingredient will not be evident when present at a level at or above the generic concentration limits mentioned in Tables 3.2.3 and 3.2.4 in section 3.2.3.3.6. In these cases the mixture shall be classified according to that data (see also Articles 10 and 11). On other occasions, when it is expected that the skin corrosion/irritation hazard of an ingredient is not evident when present at a level at or above the generic concentration limits mentioned in Tables 3.2.3 and 3.2.4, testing of the mixture shall be considered. In those cases the tiered weight of evidence strategy shall be applied, as set out in section 3.2.2.5. 3.2.3.3.6. If there are data showing that (an) ingredient(s) is/are corrosive or irritant at a concentration of < 1 % (corrosive) or < 3 % (irritant), the mixture shall be classified accordingly. 3.2.3.2.1. Where the mixture itself has not been tested to determine its skin corrosion/irritation potential, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these data shall be used in accordance with the bridging rules set out in Section 1.1.3. 3.2.3.3. Classification of mixtures when data are available for all ingredients or only for some ingredients of the mixture 3.2.3.3.1. In order to make use of all available data for purposes of classifying the skin corrosion/irritation hazards of mixtures, the following assumption has been made and is applied where appropriate in the tiered approach: The relevant ingredients of a mixture are those which are present in concentrations ≥ 1 % (w/w for solids, liquids, dusts, mists and vapours and v/v for gases), unless there is a presumption (e.g., in the case of skin corrosive ingredients) that an ingredient present at a concentration < 1 % can still be relevant for classifying the mixture for skin corrosion/irritation. 3.2.3.3.2. In general, the approach to classification of mixtures as corrosive or irritant to skin when data are available on the ingredients, but not on the mixture as a whole, is based on the theory of additivity, such that each skin corrosive or skin irritant ingredient contributes to the overall skin corrosive or skin irritant properties of the mixture in proportion to its potency and concentration. A weighting factor of 10 is used for skin corrosive ingredients when they are present at a concentration below the generic concentration limit for classification with Category 1, but are at a concentration that will contribute to the classification of the mixture as skin irritant. The mixture is classified as corrosive or irritant to skin when the sum of the concentrations of such ingredients exceeds a concentration limit. 3.2.3.3.3. Table 3.2.3 provides the generic concentration limits to be used to determine if the mixture is considered to be corrosive or irritant to the skin. 3.2.3.3.4.1. Particular care must be taken when classifying certain types of mixtures containing substances such as acids and bases, inorganic salts, aldehydes, phenols, and surfactants. The approach explained in Sections 3.2.3.3.1 and 3.2.3.3.2 may not be applicable given that many such substances are corrosive or irritant to the skin at concentrations < 1 %. 3.2.3.3.4.2. For mixtures containing strong acids or bases the pH shall be used as a classification criterion (see Section 3.2.3.1.2) since pH is a better indicator of skin corrosion than the concentration limits in Table 3.2.3. 3.2.3.3.4.3. A mixture containing ingredients that are corrosive or irritant to the skin and that cannot be classified on the basis of the additivity approach (Table 3.2.3), due to chemical characteristics that make this approach unworkable, shall be classified as Skin Corrosion Category 1 if it contains ≥ 1 % of an ingredient classified as Skin Corrosion or as Skin Irritation (Category 2) when it contains ≥ 3 % of an skin irritant ingredient. Classification of mixtures with ingredients for which the approach in Table 3.2.3 does not apply is summarised in Table 3.2.4. 3.2.3.3.5. On occasion, reliable data may show that the skin corrosion/irritation hazard of an ingredient will not be evident when present at a level at or above the generic concentration limits mentioned in Tables 3.2.3 and 3.2.4 in Section 3.2.3.3.6. In these cases the mixture shall be classified according to that data (see also Articles 10 and 11). On other occasions, when it is expected that the skin corrosion/irritation hazard of an ingredient is not evident when present at a level at or above the generic concentration limits mentioned in Tables 3.2.3 and 3.2.4, testing of the mixture shall be considered. In those cases the tiered weight of evidence approach shall be applied, as described in Section 3.2.2.2. 3.2.3.3.6. If there are data showing that (an) ingredient(s) is/are corrosive or irritant to skin at a concentration of < 1 % (skin corrosive) or < 3 % (skin irritant), the mixture shall be classified accordingly. Table 3.2.3 Generic concentration limits of ingredients classified for skin corrosive/irritant hazard (Category 1 or 2) that trigger classification of the mixture as corrosive/irritant to skin Generic concentration limits of ingredients classified as skin corrosion (Category 1, 1A, 1B or 1C)/skin irritation (Category 2) that trigger classification of the mixture as skin corrosion/skin irritation where the additivity approach applies Sum of ingredients classified as: Concentration triggering classification of a mixture as: Skin Corrosive Skin Irritant Category 1 (see note below) Category 2 Skin Corrosive Categories 1A, 1B, 1C ≥ 5 % ≥ 1 % but < 5 % Skin irritant Category 2 ≥ 10 % (10 × Skin Corrosive Category 1A, 1B, 1C) + Skin irritant Category 2 ≥ 10 % Note The sum of all ingredients of a mixture classified as Skin Corrosive Category 1A, 1B or 1C respectively, shall each be ≥ 5 % respectively in order to classify the mixture as either Skin Corrosive Category 1A, 1B or 1C. If the sum of the Skin Corrosive Category 1A ingredients is < 5 % but the sum of Category 1A+1B ingredients is ≥ 5 %, the mixture shall be classified as Skin Corrosive Category 1B. Similarly, if the sum of Skin Corrosive Category 1A+1B ingredients is < 5 % but the sum of Category 1A+1B+1C ingredients is ≥ 5 % the mixture shall be classified as Skin Corrosive Category 1C. Skin corrosion Skin irritation Category 1 (see note below) Category 2 Skin corrosion Sub-Category 1A, 1B, 1C or Category 1 ≥ 5 % ≥ 1 % but < 5 % Skin irritation Category 2 ≥ 10 % (10 × Skin corrosion Sub-Category 1A, 1B, 1C or Category 1) + Skin irritation Category 2 ≥ 10 % Note: The sum of all ingredients of a mixture classified as Skin Corrosion Sub-Category 1A, 1B, or 1C respectively, shall each be ≥ 5 % in order to classify the mixture as either Skin Corrosion Sub-Category 1A, 1B or 1C. If the sum of the ingredients classified as Skin Corrosion Sub-Category 1A is < 5 % but the sum of ingredients classified as Skin Corrosion Sub-Category 1A + 1B is ≥ 5 %, the mixture shall be classified as Skin Corrosion Sub-Category 1B. Similarly, if the sum of ingredients classified as Skin Corrosion Sub-Category 1A + 1B ingredients is < 5 % but the sum of ingredients classified as Sub-Category 1A + 1B + 1C is ≥ 5 % the mixture shall be classified as Skin Corrosion Sub-Category 1C. Where at least one relevant ingredient in a mixture is classified as Category 1 without sub-categorisation, the mixture shall be classified as Category 1 without sub-categorisation if the sum of all ingredients corrosive to skin is ≥ 5 %. Table 3.2.4 Generic concentration limits of ingredients of a mixture for which the additivity approach does not apply, that trigger classification of the mixture as corrosive/irritant to skin Ingredient: Concentration: Mixture classified as: Skin Acid with pH ≤ 2 ≥ 1 % Category 1 Base with pH ≥ 11,5 ≥ 1 % Category 1 Other corrosive (Categories 1A, 1B, 1C) ingredients for which additivity does not apply ≥ 1 % Category 1 Other irritant (Category 2) ingredients for which additivity does not apply, including acids and bases ≥ 3 % Category 2 Generic concentration limits of ingredients that trigger classification of the mixture as skin corrosion/skin irritation, where the additivity approach does not apply Ingredient: Concentration: Mixture classified as: Acid with pH ≤ 2 ≥ 1 % Skin corrosion Category 1 Base with pH ≥ 11,5 ≥ 1 % Skin corrosion Category 1 Other skin corrosive (Sub-Categories 1A, 1B, 1C or Category 1) ingredients ≥ 1 % Skin corrosion Category 1 Other skin irritant (Category 2) ingredients, including acids and bases ≥ 3 % Skin irritation Category 2 3.2.4. Hazard Communication 3.2.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 3.2.5. 3.2.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 3.2.5. Table 3.2.5 Label elements for skin corrosion/irritation Classification Category 1 A/1 B/1 C Category 2 Classification Sub-Categories 1A/1B/1C and Category 1 Category 2 GHS Pictograms Signal Word Danger Warning Hazard Statement H314: Causes severe skin burns and eye damage H315: Causes skin irritation Precautionary Statement Prevention P260 P264 P280 P264 P280 Precautionary Statement Response P301 + P330 + P331 P303 + P361 + P353 P363 P304 + P340 P310 P321 P305 + P351 + P338 P302 + P352 P321 P332 + P313 P362 + P364 Precautionary Statement Storage P405 Precautionary Statement Disposal P501 3.3. Serious eye damage/eye irritation 3.3.1. Definitions 3.3.1. Definitions and general considerations 3.3.1.1. Serious eye damage means the production of tissue damage in the eye, or serious physical decay of vision, following application of a test substance to the anterior surface of the eye, which is not fully reversible within 21 days of application. Eye irritation means the production of changes in the eye following the application of test substance to the anterior surface of the eye, which are fully reversible within 21 days of application. Eye irritation means the production of changes in the eye following the application of test substance to the anterior surface of the eye, which are fully reversible within 21 days of application. 3.3.1.2. In a tiered approach, emphasis shall be placed upon existing human data, followed by existing animal data, followed by in vitro data, and then other sources of information. Classification results directly when the data satisfy the criteria. In other cases, classification of a substance or a mixture is made on the basis of the weight of evidence within a tier. In a total weight of evidence approach all available information bearing on the determination of serious eye damage/eye irritation is considered together, including the results of appropriate validated in vitro tests, relevant animal data, and human data such as epidemiological and clinical studies and well-documented case reports and observations (see Annex I, Part 1, Section 1.1.1.3). 3.3.2. Classification criteria for substances 3.3.2.1. The classification system for substances involves a tiered testing and evaluation scheme, combining pre-existing information on serious ocular tissue damage and on eye irritation (including data relating to historical human or animal experience) as well as considerations on (Q)SAR and the output of validated in vitro tests in order to avoid unnecessary animal testing. 3.3.2.2. Before any in vivo testing for serious eye damage/eye irritation is carried out, all existing information on a substance shall be reviewed. Preliminary decisions can often be made from existing data as to whether a substance causes serious (i.e. irreversible) damage to the eyes. If a substance can be classified on the basis of these data, no testing is required. 3.3.2.3. Several factors need to be considered in determining the serious eye damage or irritation potential of a substance before testing is undertaken. Accumulated human and animal experience shall be the first line of analysis, as it gives information directly relevant to effects on the eye. In some cases enough information may be available from structurally related compounds to make hazard decisions. Likewise, pH extremes like ≤ 2 and ≥ 11,5 may produce serious eye damage, especially when associated with significant buffering capacity. Such substances are expected to produce significant effects on the eyes. Possible skin corrosion has to be evaluated prior to consideration of serious eye damage/eye irritation in order to avoid testing for local effects on eyes with skin corrosive substances. Skin corrosive substances shall be considered as leading to serious damage to the eyes as well (Category 1), while skin irritant substances may be considered as leading to eye irritation (Category 2). In vitro alternatives that have been validated and accepted can be used to make classification decisions (see Article 5). 3.3.2.4. All the above information that is available on a substance shall be used in determining the need for in vivo eye irritation testing. Although information may be gained from the evaluation of single parameters within a tier (e.g. caustic alkalis with extreme pH shall be considered as local corrosives), the totality of existing information shall be considered in making an overall weight of evidence determination, particularly when there is information available on some but not all parameters. Generally, primary emphasis shall be placed upon expert judgement, considering human experience with the substance, followed by the outcome of skin irritation testing and of well-validated alternative methods. Animal testing with corrosive substances or mixtures shall be avoided whenever possible. 3.3.2.5. A tiered approach to the evaluation of initial information shall be considered where applicable, while recognising that all elements may not be relevant in certain cases. 3.3.2.6. Irreversible effects on the eye/serious damage to eyes (Category 1) 3.3.2.6.1. Substances that have the potential to seriously damage the eyes are classified in Category 1 (irreversible effects on the eye). Substances are classified in this hazard category on the basis of the results of animal testing, in accordance with the criteria listed in Table 3.3.1. These observations include animals with grade 4 cornea lesions and other severe reactions (e.g., destruction of cornea) observed at any time during the test, as well as persistent corneal opacity, discoloration of the cornea by a dye substance, adhesion, pannus, and interference with the function of the iris or other effects that impair sight. In this context, persistent lesions are considered those which are not fully reversible within an observation period of normally 21 days. Substances are also classified in Category 1 if they fulfil the criteria of corneal opacity ≥ 3 or iritis > 1,5 detected in a Draize eye test with rabbits, recognising that such severe lesions usually do not reverse within a 21-day observation period. Substances are allocated to one of the categories within this hazard class, Category 1 (serious eye damage) or Category 2 (eye irritation), as follows: (a) Category 1 (serious eye damage): substances that have the potential to seriously damage the eyes (see Table 3.3.1). (b) Category 2 (eye irritation): substances that have the potential to induce reversible eye irritation (see Table 3.3.2). 3.3.2.1. Classification based on standard animal test data 3.3.2.1.1. Serious eye damage (Category 1) 3.3.2.1.1.1. A single hazard category (Category 1) is adopted for substances that have the potential to seriously damage the eyes. This hazard category includes as criteria the observations listed in Table 3.3.1. These observations include animals with grade 4 cornea lesions and other severe reactions (e.g. destruction of cornea) observed at any time during the test, as well as persistent corneal opacity, discoloration of the cornea by a dye substance, adhesion, pannus, and interference with the function of the iris or other effects that impair sight. In this context, persistent lesions are considered those which are not fully reversible within an observation period of normally 21 days. Hazard classification as Category 1 also contains substances fulfilling the criteria of corneal opacity ≥ 3 or iritis > 1,5 observed in at least 2 of 3 tested animals, because severe lesions like these usually do not reverse within a 21-day observation period. 3.3.2.1.1.2. The use of human data is discussed in Section 3.3.2.2 and also in Sections 1.1.1.3, 1.1.1.4 and 1.1.1.5. Table 3.3.1 Category for irreversible eye effects Serious eye damage Grading criteria are understood as described in Regulation (EC) No 440/2008. Category Criteria Irreversible effects on the eye (Category 1) If, when applied to the eye of an animal, a substance produces: at least in one animal effects on the cornea, iris or conjunctiva that are not expected to reverse or have not fully reversed within an observation period of normally 21 days; and/or at least in 2 of 3 tested animals, a positive response of: corneal opacity ≥ 3 and/or iritis > 1,5 calculated as the mean scores following grading at 24, 48 and 72 hours after installation of the test material. 3.3.2.6.2. The use of human data is discussed in paragraphs 3.3.2.1, 3.3.2.4, and also in paragraphs 1.1.1.3, 1.1.1.4 and 1.1.1.5. 3.3.2.7. Reversible effects on the eye (Category 2) 3.3.2.7.1. Substances that have the potential to induce reversible eye irritation are classified in Category 2 (irritating to eyes). Category 1 A substance that produces: (a) in at least one animal effects on the cornea, iris or conjunctiva that are not expected to reverse or have not fully reversed within an observation period of normally 21 days; and/or (b) in at least 2 of 3 tested animals, a positive response of: (i) corneal opacity ≥ 3; and/or (ii) iritis > 1,5; calculated as the mean scores following grading at 24, 48 and 72 hours after instillation of the test material. 3.3.2.1.2. Eye irritation (Category 2) 3.3.2.1.2.1. Substances that have the potential to induce reversible eye irritation shall be classified in Category 2 (eye irritation). 3.3.2.1.2.2. For those substances where there is pronounced variability among animal responses, this information shall be taken into account in determining the classification. 3.3.2.1.2.3. The use of human data is addressed in Sections 3.3.2.2, and also in Sections 1.1.1.3, 1.1.1.4 and 1.1.1.5. Table 3.3.2 Category for reversible eye effects Eye irritation Grading criteria are understood as described in Regulation (EC) No 440/2008. Category Criteria Irritating to eyes (Category 2) if, when applied to the eye of an animal, a substance produces: at least in 2 of 3 tested animals, a positive response of: corneal opacity ≥ 1 and/or iritis ≥ 1, and/or conjunctival redness ≥ 2 and/or conjunctival oedema (chemosis) ≥ 2 calculated as the mean scores following grading at 24, 48 and 72 hours after installation of the test material, and which fully reverses within an observation period of 21 days 3.3.2.7.2. For those substances where there is pronounced variability among animal responses, this information shall be taken into account in determining the classification. Category 2 Substances that produce in at least 2 of 3 tested animals a positive response of: (a) corneal opacity ≥ 1; and/or (b) iritis ≥ 1; and/or (c) conjunctival redness ≥ 2; and/or (d) conjunctival oedema (chemosis) ≥ 2 calculated as the mean scores following grading at 24, 48 and 72 hours after instillation of the test material, and which fully reverses within an observation period of normally 21 days. 3.3.2.2. Classification in a tiered approach 3.3.2.2.1. A tiered approach to the evaluation of initial information shall be considered where applicable, recognizing that not all elements may be relevant. 3.3.2.2.2. Existing human and animal data shall be the first line of evaluation as they give information directly relevant to effects on the eye. Possible skin corrosion has to be evaluated prior to consideration of any testing for serious eye damage/eye irritation in order to avoid testing for local effects on eyes with skin corrosive substances. Skin corrosive substances shall be considered as leading to serious eye damage (Category 1) as well, while skin irritant substances may be considered as leading to eye irritation (Category 2). 3.3.2.2.3. In vitro alternatives that have been validated and accepted shall be used to make classification decisions. 3.3.2.2.4. Likewise, pH extremes like ≤ 2 and ≥ 11,5, may indicate serious eye damage, especially when associated with significant acid/alkaline reserve (buffering capacity). Generally such substances are expected to produce significant effects on the eyes. In the absence of any other information, a substance is considered to cause serious eye damage (Category 1) if it has a pH ≤ 2 or ≥ 11,5. However, if consideration of acid/alkaline reserve suggests the substance may not cause serious eye damage despite the low or high pH value, this needs to be confirmed by other data, preferably by data from an appropriate validated in vitro test. 3.3.2.2.5. In some cases sufficient information may be available from structurally related substances to make classification decisions. 3.3.2.2.6. The tiered approach provides guidance on how to organize existing information and to make a weight-of-evidence decision about hazard assessment and hazard classification. Animal testing with corrosive substances shall be avoided whenever possible. Although information might be gained from the evaluation of single parameters within a tier (see 3.3.2.1.1) consideration shall be given to the totality of existing information and making an overall weight of evidence determination. This is especially true when there is conflict in information available on some parameters. 3.3.3. Classification criteria for mixtures 3.3.3.1. Classification of mixtures when data are available for the complete mixture 3.3.3.1.1. The mixture will be classified using the criteria for substances, and taking into account the testing and evaluation strategies used to develop data for these hazard classes. 3.3.3.1.2. Unlike other hazard classes, there are alternative tests available for skin corrosivity of certain types of mixtures that give an accurate result for classification purposes, as well as being simple and relatively inexpensive to perform. When considering testing of the mixture classifiers are encouraged to use a tiered weight of evidence strategy as included in the criteria for classification of substances for skin corrosion and serious eye damage and eye irritation to help ensure an accurate classification, as well as avoid unnecessary animal testing. A mixture is considered to cause serious eye damage (Category 1) if it has a pH ≤ 2,0 or ≥ 11,5. If consideration of alkali/acid reserve suggests the mixture may not have the potential to cause serious eye damage despite the low or high pH value, then further testing needs to be carried out to confirm this, preferably by use of an appropriate validated in vitro test. 3.3.3.1.1. The mixture shall be classified using the criteria for substances, and taking into account the tiered approach to evaluate data for this hazard class. 3.3.3.1.2. When considering testing of the mixture classifiers are encouraged to use a tiered weight of evidence approach as included in the criteria for classification of substances for skin corrosion and serious eye damage/eye irritation to help ensure an accurate classification, as well as to avoid unnecessary animal testing. In the absence of any other information, a mixture is considered to cause serious eye damage (Category 1) if it has a pH ≤ 2 or ≥ 11,5. However, if consideration of acid/alkali reserve suggests the mixture may not cause serious eye damage despite the low or high pH value, this needs to be confirmed by other data, preferably data from an appropriate validated in vitro test. 3.3.3.2. Classification of mixtures when data are not available for the complete mixture: bridging principles 3.3.3.2.1. Where the mixture itself has not been tested to determine its skin corrosivity or potential to cause serious eye damage or irritation, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these data shall be used in accordance with the bridging rules set out in section 1.1.3. 3.3.3.3. Classification of mixtures when data are available for all components or only for some components of the mixture 3.3.3.3.1. In order to make use of all available data for purposes of classifying the eye irritation/serious eye damaging properties of the mixtures, the following assumption has been made and is applied where appropriate in the tiered approach: Assumption: The relevant ingredients of a mixture are those which are present in concentrations of 1 % (w/w for solids, liquids, dusts, mists and vapours and v/v for gases) or greater, unless there is a presumption (e.g. in the case of corrosive ingredients) that an ingredient present at a concentration of less than 1 % is still relevant for classifying the mixture for eye irritation/serious eye damage. 3.3.3.3.2. In general, the approach to classification of mixtures as eye irritant or seriously damaging to the eye when data are available on the components, but not on the mixture as a whole, is based on the theory of additivity, such that each corrosive or irritant component contributes to the overall irritant or corrosive properties of the mixture in proportion to its potency and concentration. A weighting factor of 10 is used for corrosive components when they are present at a concentration below the generic concentration limit for classification in Category 1, but are at a concentration that will contribute to the classification of the mixture as an irritant. The mixture is classified as seriously damaging to the eye or eye irritant when the sum of the concentrations of such components exceeds a concentration limit. 3.3.3.3.3. Table 3.3.3 provides the generic concentration limits to be used to determine if the mixture shall be classified as irritant or as seriously damaging to the eye. 3.3.3.3.4.1. Particular care must be taken when classifying certain types of mixtures containing substances such as acids and bases, inorganic salts, aldehydes, phenols, and surfactants. The approach explained in paragraphs 3.3.3.3.1 and 3.3.3.3.2 might not work given that many of such substances are corrosive or irritant at concentrations < 1 %. 3.3.3.3.4.2. For mixtures containing strong acids or bases the pH shall be used as classification criteria (see paragraph 3.3.2.3) since pH will be a better indicator of serious eye damage than the generic concentration limits of Table 3.3.3. 3.3.3.3.4.3. A mixture containing corrosive or irritant ingredients that cannot be classified based on the additivity approach (Table 3.3.3), due to chemical characteristics that make this approach unworkable, shall be classified as Category 1 for effects on the eye if it contains ≥ 1 % of a corrosive ingredient and as Category 2 when it contains ≥ 3 % of an irritant ingredient. Classification of mixtures with ingredients for which the approach in Table 3.3.3 does not apply is summarised in Table 3.3.4. 3.3.3.3.5. On occasion, reliable data may show that the reversible/irreversible eye effects of an ingredient will not be evident when present at a level at or above the generic concentration limits mentioned in Tables 3.3.3 and 3.3.4 in section 3.3.3.3.6. In these cases the mixture shall be classified according to those data. On other occasions, when it is expected that the skin corrosion/irritation hazards or the reversible/irreversible eye effects of an ingredient will not be evident when present at a level at or above the generic concentration limits mentioned in Tables 3.3.3 and 3.3.4, testing of the mixture shall be considered. In those cases, the tiered weight of evidence strategy shall be applied. 3.3.3.3.6. If there are data showing that (an) ingredient(s) may be corrosive or irritant at a concentration of < 1 % (corrosive) or < 3 % (irritant), the mixture shall be classified accordingly. Table 3.3.3 Generic concentration limits of ingredients of a mixture classified as Skin corrosive Category 1 and/or eye Category 1 or 2 for effects on the eye that trigger classification of the mixture for effects on the eye (Category 1 or 2) 3.3.3.2.1. Where the mixture itself has not been tested to determine its skin corrosivity or potential to cause serious eye damage/eye irritation, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these data shall be used in accordance with the bridging rules set out in Section 1.1.3. 3.3.3.3. Classification of mixtures when data are available for all ingredients or only for some ingredients of the mixture 3.3.3.3.1. In order to make use of all available data for purposes of classifying the serious eye damage/eye irritation properties of the mixtures, the following assumption has been made and is applied where appropriate in the tiered approach: The relevant ingredients of a mixture are those which are present in concentrations ≥ 1 % (w/w for solids, liquids, dusts, mists and vapours and v/v for gases), unless there is a presumption (e.g. in the case of skin corrosive ingredients) that an ingredient present at a concentration < 1 % can still be relevant for classifying the mixture for serious eye damage/eye irritation. 3.3.3.3.2. In general, the approach to classification of mixtures as seriously damaging to the eye/eye irritant when data are available on the ingredients, but not on the mixture as a whole, is based on the theory of additivity, such that each skin corrosive or serious eye damaging/eye irritant ingredient contributes to the overall serious eye damage/eye irritation properties of the mixture in proportion to its potency and concentration. A weighting factor of 10 is used for skin corrosive and serious eye damaging ingredients when they are present at a concentration below the generic concentration limit for classification with Category 1, but are at a concentration that will contribute to the classification of the mixture as eye irritant. The mixture is classified as seriously damaging to the eye or eye irritant when the sum of the concentrations of such ingredients exceeds a concentration limit. 3.3.3.3.3. Table 3.3.3 provides the generic concentration limits to be used to determine if the mixture shall be classified as seriously damaging to the eye or as eye irritant. 3.3.3.3.4.1. Particular care must be taken when classifying certain types of mixtures containing substances such as acids and bases, inorganic salts, aldehydes, phenols, and surfactants. The approach explained in Sections 3.3.3.3.1 and 3.3.3.3.2 might not work given that many such substances are seriously damaging to the eye/eye irritant at concentrations < 1 %. 3.3.3.3.4.2. For mixtures containing strong acids or bases the pH shall be used as classification criterion (see Section 3.3.3.1.2) since pH will be a better indicator of serious eye damage (subject to consideration of acid/alkali reserve) than the generic concentration limits in Table 3.3.3. 3.3.3.3.4.3. A mixture containing skin corrosive or serious eye damaging/eye irritating ingredients that cannot be classified based on the additivity approach (Table 3.3.3) due to chemical characteristics that make this approach unworkable, shall be classified as Serious Eye Damage (Category 1) if it contains ≥ 1 % of a skin corrosive or serious eye damaging ingredient and as Eye Irritation (Category 2) when it contains ≥ 3 % of an eye irritant ingredient. Classification of mixtures with ingredients for which the approach in Table 3.3.3 does not apply is summarised in Table 3.3.4. 3.3.3.3.5. On occasion, reliable data may show that the effects of serious eye damage/eye irritation of an ingredient will not be evident when present at a level at or above the generic concentration limits mentioned in Tables 3.3.3 and 3.3.4 in Section 3.3.3.3.6. In these cases the mixture shall be classified according to those data (see also Articles 10 and 11). On other occasions, when it is expected that the skin corrosion/irritation hazards or the effects of serious eye damage/eye irritation of an ingredient will not be evident when present at a level at or above the generic concentration limits mentioned in Tables 3.3.3 and 3.3.4, testing of the mixture shall be considered. In those cases, the tiered weight of evidence approach shall be applied. 3.3.3.3.6. If there are data showing that (an) ingredient(s) may be corrosive to the skin or seriously damaging to the eye/eye irritating at a concentration of < 1 % (corrosive to the skin or seriously damaging to the eye) or < 3 % (eye irritant), the mixture shall be classified accordingly. Table 3.3.3 Generic concentration limits of ingredients classified as skin corrosion (Category 1, 1A, 1B or 1C) and/or serious eye damage (Category 1) or eye irritation (Category 2) that trigger classification of the mixture as serious eye damage/eye irritation where the additivity approach applies If an ingredient is classified as both Skin Corrosion Sub-Category 1A, 1B, 1C or Category 1 and Serious Eye Damage (Category 1), its concentration is considered only once in the calculation. Sum of ingredients classified as: Concentration triggering classification of a mixture as: Irreversible Eye Effects Reversible Eye Effects Category 1 Category 2 Eye Effects Category 1 or Skin Corrosive Category 1A, 1B, 1C ≥ 3 % ≥ 1 % but < 3 % Eye Effects Category 2 ≥ 10 % (10 × Eye Effects Category 1) + Eye effects Category 2 ≥ 10 % Skin Corrosive Category 1A, 1B, 1C + Eye effects Category 1 ≥ 3 % ≥ 1 % but < 3 % 10 × (Skin Corrosive Category 1A, 1B, 1C + Eye Effects Category 1) + Eye Effects Category 2 ≥ 10 % Table 3.3.4 Generic concentration limits of ingredients of a mixture for which the additivity approach does not apply, that trigger classification of the mixture as hazardous to the eye Ingredient Concentration Mixture classified as: Eye Acid with pH ≤ 2 ≥ 1 % Category 1 Base with pH ≥ 11,5 ≥ 1 % Category 1 Other corrosive (Category 1) ingredients for which additivity does not apply ≥ 1 % Category 1 Other irritant (Category 2) ingredients for which additivity does not apply, including acids and bases ≥ 3 % Category 2 Serious eye damage Eye irritation Category 1 Category 2 Skin corrosion Sub-Category 1A, 1B, 1C or Category 1 + Serious eye damage (Category 1) ≥ 3 % ≥ 1 % but < 3 % Eye irritation (Category 2) ≥ 10 % 10 × (Skin corrosion Sub-Category 1A, 1B, 1C or Skin corrosion Category 1 + Serious eye damage (Category 1)) + Eye irritation (Category 2) ≥ 10 % Table 3.3.4 Generic concentration limits of ingredients that trigger classification of the mixture as serious eye damage (Category 1) or eye irritation (Category 2), where the additivity approach does not apply Ingredient Concentration Mixture classified as: Acid with pH ≤ 2 ≥ 1 % Serious eye damage (Category 1) Base with pH ≥ 11,5 ≥ 1 % Serious eye damage (Category 1) Other ingredient classified as skin corrosion (Sub-Category 1A, 1B, 1C or Category 1) or serious eye damage (Category 1) ≥ 1 % Serious eye damage (Category 1) Other ingredient classified as eye irritation (Category 2) ≥ 3 % Eye irritation (Category 2) 3.3.4. Hazard Communication 3.3.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 3.3.5. Table 3.3.5 3.3.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 3.3.5. Table 3.3.5 Label elements for serious eye damage/eye irritation Classification Category 1 Category 2 Where a chemical is classified as skin corrosion Sub-Category 1A, 1B, 1C or Category 1, labelling for serious eye damage/eye irritation can be omitted as this information is already included in the hazard statement for skin corrosion Category 1 (H314). Classification Category 1 Category 2 GHS Pictograms Signal Word Danger Warning Hazard Statement H318: Causes serious eye damage H319: Causes serious eye irritation Precautionary Statement Prevention P280 P264 Precautionary Statement Prevention P280 P264 P280 Precautionary Statement Response P305 + P351 + P338 Precautionary Statement Response P305 + P351 + P338 P310 P305 + P351 + P338 P337 + P313 Precautionary Statement Storage Precautionary Statement Disposal 3.4. Respiratory or skin sensitisation Precautionary Statement Storage Precautionary Statement Disposal 3.4. Respiratory or skin sensitisation 3.4.1. Definitions and general considerations 3.4.1.1. Respiratory sensitiser means a substance that will lead to hypersensitivity of the airways following inhalation of the substance. 3.4.1.2. Skin sensitiser means a substance that will lead to an allergic response following skin contact. … 755 unchanged lines … 4.1.1. Definitions and general considerations 4.1.1.1. Definitions (a) acute aquatic toxicity means the intrinsic property of a substance to be injurious to an aquatic organism in a short-term aquatic exposure to that substance. (b) acute (short-term) hazard means for classification purposes the hazard of a substance or mixture caused by its acute toxicity to an organism during short-term aquatic exposure to that substance or mixture. (b) short-term (acute) hazard means for classification purposes the hazard of a substance or mixture caused by its acute toxicity to an organism during short-term aquatic exposure to that substance or mixture. (c) availability of a substance means the extent to which this substance becomes a soluble or disaggregate species. For metal availability, the extent to which the metal ion portion of a metal (M°) compound can disaggregate from the rest of the compound (molecule). (d) bioavailability or biological availability means the extent to which a substance is taken up by an organism, and distributed to an area within the organism. It is dependent upon physico-chemical properties of the substance, anatomy and physiology of the organism, pharmacokinetics, and route of exposure. Availability is not a prerequisite for bioavailability. (e) bioaccumulation means the net result of uptake, transformation and elimination of a substance in an organism due to all routes of exposure (i.e. air, water, sediment/soil and food). (f) bioconcentration means the net result of uptake, transformation and elimination of a substance in an organism due to waterborne exposure. (g) chronic aquatic toxicity means the intrinsic property of a substance to cause adverse effects to aquatic organisms during aquatic exposures which are determined in relation to the life-cycle of the organism. (h) degradation means the decomposition of organic molecules to smaller molecules and eventually to carbon dioxide, water and salts. (i) ECx means the effect concentration associated with x% response. (j) long-term hazard means for classification purposes the hazard of a substance or mixture caused by its chronic toxicity following long-term exposure in the aquatic environment. (j) long-term (chronic) hazard means for classification purposes the hazard of a substance or mixture caused by its chronic toxicity following long-term exposure in the aquatic environment. (k) no observed effect concentration (NOEC) means the test concentration immediately below the lowest tested concentration with statistically significant adverse effect. The NOEC has no statistically significant adverse effect compared to the control. 4.1.1.2. Basic elements 4.1.1.2.0. Hazardous to the aquatic environment is differentiated into: acute aquatic hazard, long-term aquatic hazard. short-term (acute) aquatic hazard long-term (chronic) aquatic hazard. 4.1.1.2.1. The basic elements used for classification for aquatic environmental hazards are: acute aquatic toxicity, chronic aquatic toxicity, potential for or actual bioaccumulation, and degradation (biotic or abiotic) for organic chemicals. 4.1.1.2.2. Preferably data shall be derived using the standardised test methods referred to in Article 8(3). In practice data from other standardised test methods such as national methods shall also be used where they are considered as equivalent. Where valid data are available from non-standard testing and from non-testing methods, these shall be considered in classification provided they fulfil the requirements specified in section 1 of Annex XI to Regulation (EC) No 1907/2006. In general, both freshwater and marine species toxicity data are considered suitable for use in classification provided the test methods used are equivalent. Where such data are not available classification shall be based on the best available data. See also Part 1 of Annex I to Regulation (EC) No 1272/2008. 4.1.1.3. Other considerations 4.1.1.3.1. Classification of substances and mixtures for environmental hazards requires the identification of the hazards they present to the aquatic environment. The aquatic environment is considered in terms of the aquatic organisms that live in the water, and the aquatic ecosystem of which they are part. The basis, therefore, of the identification of acute (short-term) and long-term hazards is the aquatic toxicity of the substance or mixture, although this shall be modified by taking account of further information on the degradation and bioaccumulation behaviour, if appropriate. 4.1.1.3.1. Classification of substances and mixtures for environmental hazards requires the identification of the hazards they present to the aquatic environment. The aquatic environment is considered in terms of the aquatic organisms that live in the water, and the aquatic ecosystem of which they are part. The basis, therefore, of the identification of short-term (acute) and long-term (chronic) hazards is the aquatic toxicity of the substance or mixture, although this shall be modified by taking account of further information on the degradation and bioaccumulation behaviour, if appropriate. 4.1.1.3.2. While the classification system applies to all substances and mixtures, it is recognised that for special cases (e.g. metals) the European Chemicals Agency has issued guidance. 4.1.2. Classification criteria for substances 4.1.2.1. The system for classification recognises that the intrinsic hazard to aquatic organisms is represented by both the acute and long-term hazard of a substance. For the long-term hazard, separate hazard categories are defined representing a gradation in the level of hazard identified. The lowest of the available toxicity values between and within the different trophic levels (fish, crustacean, algae/aquatic plants) shall normally be used to define the appropriate hazard category(ies). There are circumstances, however, when a weight of evidence approach is appropriate. 4.1.2.2. The core classification system for substances consists of one acute hazard classification category and three long-term hazard classification categories. The acute and the long-term hazard classification categories are applied independently. 4.1.2.3. The criteria for classification of a substance in category Acute 1 are defined on the basis of acute aquatic toxicity data only (EC50 or LC50). The criteria for classification of a substance into the categories Chronic 1 to 3 follow a tiered approach where the first step is to see if available information on chronic toxicity merits long-term hazard classification. In absence of adequate chronic toxicity data, the subsequent step is to combine two types of information, i.e. acute aquatic toxicity data and environmental fate data (degradability and bioaccumulation data) (see figure 4.1.1). 4.1.2.1. The system for classification recognises that the intrinsic hazard to aquatic organisms is represented by both the acute and chronic toxicity of a substance. For the long-term (chronic) hazard, separate hazard categories are defined representing a gradation in the level of hazard identified. The lowest of the available toxicity values between and within the different trophic levels (fish, crustacean, algae/aquatic plants) shall normally be used to define the appropriate hazard category(ies). There are circumstances, however, when a weight of evidence approach is appropriate. 4.1.2.2. The core classification system for substances consists of one short-term (acute) hazard classification category and three long-term (chronic) hazard classification categories. The short-term (acute) and long-term (chronic) classification categories are applied independently. 4.1.2.3. The criteria for classification of a substance in Acute 1 are defined on the basis of acute aquatic toxicity data only (EC50 or LC 50). The criteria for classification of a substance into Chronic 1 to 3 follow a tiered approach where the first step is to see if available information on chronic toxicity merits long-term (chronic) hazard classification. In absence of adequate chronic toxicity data, the subsequent step is to combine two types of information, i.e. acute aquatic toxicity data and environmental fate data (degradability and bioaccumulation data) (see Figure 4.1.1). Figure 4.1.1 Categories for substances long-term hazardous to the aquatic environment Categories for substances long-term (chronic) hazardous to the aquatic environment Are there adequate chronic toxicity data available for all three trophic levels? Yes Classify according to the criteria given in Table 4.1.0(b) (i) or 4.1.0(b)(ii) depending on information on rapid degradation No Are there adequate chronic toxicity data available for one or two trophic levels? Yes Assess both: (a) according to the criteria given in Table 4.1.0(b)(i) or 4.1.0(b)(ii) (depending on information on rapid degradation), and (b) (if for the other trophic level(s) adequate acute toxicity data are available) according to the criteria given in Table 4.1.0(b) (iii), and classify according to the most stringent outcome No Are there adequate acute toxicity data available? Yes Classify according to the criteria given in Table 4.1.0(b) (iii) 4.1.2.4. The system also introduces a safety net classification (referred to as category Chronic 4) for use when the data available do not allow classification under the formal criteria for acute 1 or chronic 1 to 3 but there are nevertheless some grounds for concern (see example in Table 4.1.0). 4.1.2.4. The system also introduces a safety net classification (referred to as Chronic 4) for use when the data available do not allow classification under the formal criteria for Acute 1 or Chronic 1 to 3 but there are nevertheless some grounds for concern (see example Table 4.1.0). 4.1.2.5. Substances with acute toxicities below 1 mg/l or chronic toxicities below 0,1 mg/l (if non-rapidly degradable) and 0,01 mg/l (if rapidly degradable) contribute as components of a mixture to the toxicity of the mixture even at a low concentration and shall normally be given increased weight in applying the summation of classification approach (see note 1 of Table 4.1.0 and section 4.1.3.5.5). 4.1.2.6. The criteria for classifying and categorising substances as hazardous to the aquatic environment are summarised in Table 4.1.0. Table 4.1.0 Classification categories for hazardous to the aquatic environment (a) Acute (short-term) aquatic hazard Category Acute 1: (Note 1) 96 hr LC50 (for fish) ≤ 1 mg/l and/or 48 hr EC50 (for crustacea) ≤ 1 mg/l and/or 72 or 96 hr ErC50 (for algae or other aquatic plants) ≤ 1 mg/l. (Note 2) (b) Long-term aquatic hazard Classification categories for substances hazardous to the aquatic environment (a) Short-term (acute) aquatic hazard Category Acute 1: (Note 1) 96 hr LC50 (for fish) ≤ 1 mg/l and/or 48 hr EC50 (for crustacea) ≤ 1 mg/l and/or 72 or 96 hr ErC50 (for algae or other aquatic plants) ≤ 1 mg/l. (Note 2) (b) Long-term (chronic) aquatic hazard (i) Non-rapidly degradable substances (Note 3) for which there are adequate chronic toxicity data available Category Chronic 1: (Note 1) Chronic NOEC or ECx (for fish) ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0,1 mg/l. Chronic NOEC or ECx (for fish) ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0,1 mg/l. Category Chronic 2: Chronic NOEC or ECx (for fish) > 0,1 to ≤ 1 mg/l and/or Chronic NOEC or ECx (for crustacea) > 0,1 to ≤ 1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) > 0,1 to ≤ 1 mg/l. Chronic NOEC or ECx (for fish) ≤ 1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 1 mg/l. (ii) Rapidly degradable substances (Note 3) for which there are adequate chronic toxicity data available Category Chronic 1: (Note 1) Chronic NOEC or ECx (for fish) ≤ 0,01 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0,01 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0,01 mg/l. Chronic NOEC or ECx (for fish) ≤ 0,01 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0,01 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0,01 mg/l. Category Chronic 2: Chronic NOEC or ECx (for fish) > 0,01 to ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for crustacea) > 0,01 to ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) > 0,01 to ≤ 0,1 mg/l. Chronic NOEC or ECx (for fish) ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 0,1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 0,1 mg/l. Category Chronic 3: Chronic NOEC or ECx (for fish) > 0,1 to ≤ 1 mg/l and/or Chronic NOEC or ECx (for crustacea) > 0,1 to ≤ 1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) > 0,1 to ≤ 1 mg/l. Chronic NOEC or ECx (for fish) ≤ 1 mg/l and/or Chronic NOEC or ECx (for crustacea) ≤ 1 mg/l and/or Chronic NOEC or ECx (for algae or other aquatic plants) ≤ 1 mg/l. (iii) Substances for which adequate chronic toxicity data are not available Category Chronic 1: (Note 1) 96 hr LC50 (for fish) ≤ 1 mg/l and/or 48 hr EC50 (for crustacea) ≤ 1 mg/l and/or 72 or 96 hr ErC50 (for algae or other aquatic plants) ≤ 1 mg/l. (Note 2) and the substance is not rapidly degradable and/or the experimentally determined BCF ≥ 500 (or, if absent, the log Kow≥ 4). (Note 3). 96 hr LC50 (for fish) ≤ 1 mg/l and/or 48 hr EC50 (for crustacea) ≤ 1 mg/l and/or 72 or 96 hr ErC50 (for algae or other aquatic plants) ≤ 1 mg/l. (Note 2) and the substance is not rapidly degradable and/or the experimentally determined BCF ≥ 500 (or, if absent, the log Kow ≥ 4). (Note 3). Category Chronic 2: 96 hr LC50 (for fish) > 1 to ≤10 mg/l and/or 48 hr EC50 (for crustacea) > 1 to ≤10 mg/l and/or 72 or 96 hr ErC50 (for algae or other aquatic plants) > 1 to ≤10 mg/l (Note 2) and the substance is not rapidly degradable and/or the experimentally determined BCF ≥ 500 (or, if absent, the log Kow≥ 4). (Note 3). 96 hr LC50 (for fish) > 1 to ≤ 10 mg/l and/or 48 hr EC50 (for crustacea) > 1 to ≤ 10 mg/l and/or 72 or 96 hr ErC50 (for algae or other aquatic plants) > 1 to ≤ 10 mg/l. (Note 2) and the substance is not rapidly degradable and/or the experimentally determined BCF ≥ 500 (or, if absent, the log Kow ≥ 4). (Note 3). Category Chronic 3: 96 hr LC50 (for fish) > 10 to ≤ 100 mg/l and/or 48 hr EC50 (for crustacea) > 10 to ≤ 100 mg/l and/or 72 or 96 hr ErC50 (for algae or other aquatic plants) > 10 to ≤ 100 mg/l. (Note 2) and the substance is not rapidly degradable and/or the experimentally determined BCF ≥ 500 (or, if absent, the log Kow≥ 4). (Note 3). 72 or 96 hr ErC50 (for algae or other aquatic plants) > 10 to ≤ 100 mg/l. (Note 2) and the substance is not rapidly degradable and/or the experimentally determined BCF ≥ 500 (or, if absent, the log Kow ≥ 4). (Note 3). Safety net classification Category Chronic 4 Cases when data do not allow classification under the above criteria but there are nevertheless some grounds for concern. This includes, for example, poorly soluble substances for which no acute toxicity is recorded at levels up to the water solubility (note 4), and which are not rapidly degradable in accordance with section 4.1.2.9.5 and have an experimentally determined BCF ≥ 500 (or, if absent, a log Kow ≥ 4), indicating a potential to bioaccumulate, which will be classified in this category unless other scientific evidence exists showing classification to be unnecessary. Such evidence includes chronic toxicity NOECs > water solubility or > 1 mg/l, or other evidence of rapid degradation in the environment than the ones provided by any of the methods listed in section 4.1.2.9.5. Cases when data do not allow classification under the above criteria but there are nevertheless some grounds for concern. This includes, for example, poorly soluble substances for which no acute toxicity is recorded at levels up to the water solubility (note 4), and which are not rapidly degradable in accordance with Section 4.1.2.9.5 and have an experimentally determined BCF ≥ 500 (or, if absent, a log Kow ≥ 4), indicating a potential to bioaccumulate, which will be classified in this category unless other scientific evidence exists showing classification to be unnecessary. Such evidence includes chronic toxicity NOECs > water solubility or > 1 mg/l, or other evidence of rapid degradation in the environment than the ones provided by any of the methods listed in Section 4.1.2.9.5. Note 1: When classifying substances as Acute Category 1 and/or Chronic Category 1 it is necessary at the same time to indicate the appropriate M-factor(s) (see Table 4.1.3). Note 2: … 30 unchanged lines … classification based on tested mixtures, classification based on bridging principles, the use of summation of classified components and/or an additivity formula. Figure 4.1.2 Tiered approach to classification of mixtures for acute and long-term aquatic environmental hazards Aquatic toxicity test data available on the mixture as a whole Figure 4.1.2 Tiered approach to classification of mixtures for short-term (acute) and long-term (chronic) aquatic environmental hazards Apply summation method (see 4.1.3.5.5) using: · Percentage of all components classified as "Chronic" · Percentage of components classified as "Acute" · Percentage of components with acute or chronic toxicity data: apply additivity formulas (see 4.1.3.5.2) and convert the derived L(E)C50 or EqNOECm to the appropriate "Acute" or "Chronic" category CLASSIFY for short-term (acute)/long-term chronic hazard CLASSIFY for short-term (acute)/long-term (chronic) aquatic hazard CLASSIFY for short-term(acute)/long-term (chronic)aquatic hazard (see 4.1.3.3) Apply bridging principles (see 4.1.3.4.) CLASSIFY for short-term (acute)/long-term (chronic) hazard Apply summation method and/or additivity formula (see 4.1.3.5) and apply 4.1.3.6 Use available hazard data of known components Either aquatic toxicity or classification data available for all relevant components Sufficient data available on similar mixtures to estimate hazards No No Yes CLASSIFY for acute/long-term aquatic hazard (see 4.1.3.3) Sufficient data available on similar mixtures to estimate hazards Yes Apply bridging principles (see 4.1.3.4.) CLASSIFY for acute/long-term aquatic hazard Yes No Either aquatic toxicity or classification data available for all relevant components Yes Apply summation method (see 4.1.3.5.5) using: • Percentage of all components classified as ‘Chronic’ • Percentage of components classified as ‘Acute’ • Percentage of components with acute or chronic toxicity data: apply additivity formulas (see 4.1.3.5.2) and convert the derived L(E)C50 or EqNOECm to the appropriate ‘Acute’ or ‘Chronic’ category CLASSIFY for acute/long-term aquatic hazard No Use available hazard data of known components Apply summation method and/or additivity formula (see 4.1.3.5) and apply 4.1.3.6 CLASSIFY for acute/long-term aquatic hazard Aquatic toxicity test data available on the mixture as a whole 4.1.3.3. Classification of mixtures when toxicity data are available for the complete mixture 4.1.3.3.1. When the mixture as a whole has been tested to determine its aquatic toxicity, this information can be used for classifying the mixture according to the criteria that have been agreed for substances. The classification is normally based on the data for fish, crustacea and algae/plants (see sections 4.1.2.7.1 and 4.1.2.7.2). When adequate acute or chronic toxicity data for the mixture as a whole are lacking, bridging principles or summation method should be applied (see sections 4.1.3.4 and 4.1.3.5). 4.1.3.3.2. The long-term hazard classification of mixtures requires additional information on degradability and in certain cases bioaccumulation. Degradability and bioaccumulation tests for mixtures are not used as they are usually difficult to interpret, and such tests may be meaningful only for single substances. 4.1.3.3.2. The long-term (chronic) hazard classification of mixtures requires additional information on degradability and in certain cases bioaccumulation. Degradability and bioaccumulation tests for mixtures are not used as they are usually difficult to interpret, and such tests may be meaningful only for single substances. 4.1.3.3.3. Classification for category Acute 1 (a) When there are adequate acute toxicity test data (LC50 or EC50) available for the mixture as a whole showing L(E)C50 ≤ 1 mg/l: Classify mixture as Acute 1 in accordance with point (a) of Table 4.1.0. (b) When there are acute toxicity test data (LC50(s) or EC50(s)) available for the mixture as a whole showing L(E)C50(s) > 1 mg/l for normally all trophic levels: No need to classify for acute hazard. No need to classify for short-term (acute) hazard. 4.1.3.3.4. Classification for categories Chronic 1, 2 and 3 (a) When there are adequate chronic toxicity data (ECxx or NOEC) available for the mixture as a whole showing ECx or NOEC of the tested mixture ≤ 1mg/l: (i) Classify the mixture as Chronic 1, 2 or 3 in accordance with point (b)(ii) of Table 4.1.0 as rapidly degradable if the available information allows the conclusion that all relevant components of the mixture are rapidly degradable; (ii) Classify the mixture as Chronic 1 or 2 in all other cases in accordance with point (b)(i) of Table 4.1.0 as non-rapidly degradable; (b) When there are adequate chronic toxicity data (ECx or NOEC) available for the mixture as a whole showing ECx(s) or NOEC(s) of the tested mixture > 1 mg/l for normally all trophic levels: No need to classify for long-term hazard in categories Chronic 1, 2 or 3. No need to classify for long-term (chronic) hazard in categories Chronic 1, 2 or 3. 4.1.3.3.5. Classification for category Chronic 4 If there are nevertheless reasons for concern: Classify the mixture as Chronic 4 (safety net classification) in accordance with Table 4.1.0. … 15 unchanged lines … number of components, and i is running from 1 to n; L(E)C50m L(E) C50 of the part of the mixture with test data. The calculated toxicity may be used to assign that portion of the mixture an acute hazard category which is then subsequently used in applying the summation method; The calculated toxicity may be used to assign that portion of the mixture a short-term (acute) hazard category which is then subsequently used in applying the summation method; (b) Based on chronic aquatic toxicity: CiCjEqNOECmnCiNOECinCj0,1NOECj where: Ci concentration of component i (weight percentage) covering the rapidly degradable components; Cj concentration of component j (weight percentage) covering the non- rapidly degradable components; NOECi NOEC (or other recognised measures for chronic toxicity) for component i covering the rapidly degradable components, in mg/l; NOECj NOEC (or other recognised measures for chronic toxicity) for component j covering the non-rapidly degradable components, in mg/l; n number of components, and i and j are running from 1 to n; EqNOECm Equivalent NOEC of the part of the mixture with test data. The equivalent toxicity thus reflects the fact that non-rapidly degrading substances are classified one hazard category level more severe than rapidly degrading substances. The calculated equivalent toxicity may be used to assign that portion of the mixture a long-term hazard category, in accordance with the criteria for rapidly degradable substances (point (b)(ii) of Table 4.1.0), which is then subsequently used in applying the summation method. The calculated equivalent toxicity may be used to assign that portion of the mixture a long-term (chronic) hazard category, in accordance with the criteria for rapidly degradable substances (point (b)(ii) of Table 4.1.0), which is then subsequently used in applying the summation method. 4.1.3.5.3. When applying the additivity formula for part of the mixture, it is preferable to calculate the toxicity of this part of the mixture using for each substance toxicity values that relate to the same taxonomic group (i.e. fish, crustacean, algae or equivalent) and then to use the highest toxicity (lowest value) obtained (i.e. use the most sensitive of the three taxonomic groups). However, when toxicity data for each component are not available in the same taxonomic group, the toxicity value of each component is selected in the same manner that toxicity values are selected for the classification of substances, i.e. the higher toxicity (from the most sensitive test organism) is used. The calculated acute and chronic toxicity is then used to assess whether this part of the mixture shall be classified as Acute 1 and/or Chronic 1, 2 or 3 using the same criteria described for substances. 4.1.3.5.4. If a mixture is classified in more than one way, the method yielding the more conservative result shall be used. 4.1.3.5.5. Summation method 4.1.3.5.5.1. Rationale 4.1.3.5.5.1.1. In case of the substance classification categories Chronic 1 to Chronic 3, the underlying toxicity criteria differ by a factor of 10 in moving from one category to another. Substances with a classification in a high toxicity band therefore contribute to the classification of a mixture in a lower band. The calculation of these classification categories therefore needs to consider the contribution of any substance classified as Chronic 1, 2 or 3. 4.1.3.5.5.1.2. When a mixture contains components classified as Acute 1 or Chronic 1, attention must be paid to the fact that such components, when their acute toxicity is below 1 mg/l and/or chronic toxicity is below 0,1 mg/l (if non rapidly degradable) and 0,01 mg/l (if rapidly degradable) contribute to the toxicity of the mixture even at a low concentration. Active ingredients in pesticides often possess such high aquatic toxicity but also some other substances like organometallic compounds. Under these circumstances the application of the normal generic concentration limits leads to an under-classification of the mixture. Therefore, multiplying factors shall be applied to account for highly toxic components, as described in section 4.1.3.5.5.5. 4.1.3.5.5.2. Classification procedure 4.1.3.5.5.2.1. In general a more severe classification for mixtures overrides a less severe classification, e.g. a classification with Chronic 1 overrides a classification with Chronic 2. As a consequence, in this example, the classification procedure is already completed if the result of the classification is Chronic 1. A more severe classification than Chronic 1 is not possible. Therefore it is not necessary to undergo the further classification procedure. 4.1.3.5.5.3. Classification for category Acute 1 4.1.3.5.5.3.1. First all components classified as Acute 1 are considered. If the sum of the concentrations (in %) of these components multiplied by their corresponding M-factors is greater than 25 % the whole mixture is classified as Acute 1. 4.1.3.5.5.3.2. The classification of mixtures for acute hazards based on this summation of classified components is summarised in Table 4.1.1. 4.1.3.5.5.3.2. The classification of mixtures for short-term (acute) hazards based on this summation of classified components is summarised in Table 4.1.1. Table 4.1.1 Classification of a mixture for acute hazards, based on summation of classified components Classification of a mixture for short-term (acute) hazards based on summation of classified components For explanation of the M-factor, see 4.1.3.5.5.5. Sum of components classified as: Mixture is classified as: Acute 1 × M ≥ 25 % Acute 1 4.1.3.5.5.4. Classification for the categories Chronic 1, 2, 3 and 4 4.1.3.5.5.4.1. First all components classified as Chronic 1 are considered. If the sum of the concentrations (in %) of these components multiplied by their corresponding M-factors is equal to or greater than 25 %, the mixture is classified as Chronic 1. If the result of the calculation is a classification of the mixture as Chronic 1, the classification procedure is completed. 4.1.3.5.5.4.2. In cases where the mixture is not classified as Chronic 1, classification of the mixture as Chronic 2 is considered. A mixture is classified as Chronic 2 if 10 times the sum of the concentrations (in %) of all components classified as Chronic 1 multiplied by their corresponding M-factors plus the sum of the concentrations (in %) of all components classified as Chronic 2 is equal to or greater than 25 %. If the result of the calculation is classification of the mixture as Chronic 2, the classification process is completed. 4.1.3.5.5.4.3. In cases where the mixture is not classified either as Chronic 1 or Chronic 2, classification of the mixture as Chronic 3 is considered. A mixture is classified as Chronic 3 if 100 times the sum of the concentrations (in %) of all components classified as Chronic 1 multiplied by their corresponding M-factors plus 10 times the sum of the concentrations (in %) of all components classified with Chronic 2 plus the sum of the concentrations (in %) of all components classified as Chronic 3 is ≥ 25 %. 4.1.3.5.5.4.4. If the mixture is still not classified in Chronic 1, 2 or 3, classification of the mixture as Chronic 4 shall be considered. A mixture is classified as Chronic 4 if the sum of the concentrations (in %) of components classified as Chronic 1, 2, 3 and 4 is equal to or greater than 25 %. 4.1.3.5.5.4.5. The classification of mixtures for long-term hazards, based on this summation of the concentrations of classified components, is summarised in Table 4.1.2. 4.1.3.5.5.4.5. The classification of mixtures for long-term (chronic) hazards, based on this summation of the concentrations of classified components, is summarised in Table 4.1.2. Table 4.1.2 Classification of a mixture for long-term hazards, based on summation of the concentrations of classified components Classification of a mixture for long-term (chronic) hazards, based on summation of the concentration of classified components For explanation of the M-factor, see 4.1.3.5.5.5. Sum of components classified as: Mixture is classified as: Chronic 1 × M ≥ 25 % Chronic 1 … 16 unchanged lines … 0,00001 < L(E)C50 ≤ 0,0001 10000 0,000001 < NOEC ≤ 0,00001 10000 1000 (continue in factor 10 intervals) (continue in factor 10 intervals) 4.1.3.6. Classification of mixtures with components without any useable information 4.1.3.6.1. In the event that no useable information on acute and/or long-term aquatic hazard is available for one or more relevant components, it is concluded that the mixture cannot be attributed to one or more definitive hazard category(ies). In this situation the mixture shall be classified based on the known components only, with the additional statement on the label and in the SDS that: Contains x % of components with unknown hazards to the aquatic environment. 4.1.3.6.1. In the event that no useable information on short-term (acute) and/or long-term (chronic) aquatic hazard is available for one or more relevant components, it is concluded that the mixture cannot be attributed to one or more definitive hazard category(ies). In this situation the mixture shall be classified based on the known components only, with the additional statement on the label and in the SDS that: Contains x % of components with unknown hazards to the aquatic environment. 4.1.4. Hazard communication 4.1.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 4.1.4. Table 4.1.4 Label elements for hazardous to the aquatic environment ACUTE AQUATIC HAZARD SHORT-TERM (ACUTE) AQUATIC HAZARD Acute 1 GHS pictogram Signal word Warning Hazard statement H400: Very toxic to aquatic life Precautionary statement prevention P273 Precautionary statement response P391 Precautionary statement storage Precautionary statement disposal P501 LONG-TERM AQUATIC HAZARD Chronic 1 Chronic 2 Chronic 3 Chronic 4 GHS pictograms No pictogram is used No pictogram is used Signal word Warning No signal word is used No signal word is used No signal word is used Hazard statement H410: Very toxic to aquatic life with long lasting effects H411: Toxic to aquatic life with long lasting effects H412: Harmful to aquatic life with long lasting effects H413: May cause long lasting harmful effects to aquatic life Precautionary statement prevention P273 P273 P273 P273 Precautionary statement response P391 P391 Precautionary statement storage Precautionary statement disposal P501 P501 P501 P501 GHS Pictogram Signal Word Warning Hazard Statement H400: Very toxic to aquatic life Precautionary Statement Prevention P273 Precautionary Statement Response P391 Precautionary Statement Storage Precautionary Statement Disposal P501 LONG-TERM (CHRONIC) AQUATIC HAZARD Chronic 1 Chronic 2 Chronic 3 Chronic 4 GHS Pictograms No pictogram is used No pictogram is used Signal Word Warning No signal word is used No signal word is used No signal word is used Hazard Statement H410: Very toxic to aquatic life with long lasting effects H411: Toxic to aquatic life with long lasting effects H412: Harmful to aquatic life with long lasting effects H413: May cause long lasting harmful effects to aquatic life Precautionary Statement Prevention P273 P273 P273 P273 Precautionary Statement Response P391 P391 Precautionary Statement Storage Precautionary Statement Disposal P501 P501 P501 P501 5. PART 5: ADDITIONAL HAZARDS 5.1. Hazardous to the ozone layer 5.1.1. Definitions and general considerations 5.1.1.1. Ozone depleting potential (ODP) is an integrative quantity, distinct for each halocarbon source species, that represents the extent of ozone depletion in the stratosphere expected from the halocarbon on a mass-for-mass basis relative to CFC-11. The formal definition of ODP is the ratio of integrated perturbations to total ozone, for a differential mass emission of a particular compound relative to an equal emission of CFC-11. Substance hazardous to the ozone layer means a substance which, on the basis of the available evidence concerning its properties and its predicted or observed environmental fate and behaviour may present a danger to the structure and/or the functioning of the stratospheric ozone layer. This includes substances which are listed in Annex I to Regulation (EC) No 1005/2009 of the European Parliament and of the Council of 16 September 2009 on substances that deplete the ozone layerOJ L 286, 31.10.2009, p. 1.. 5.1.2. Classification criteria for substances 5.1.2.1. A substance shall be classified as hazardous to the ozone layer (Category 1) if the available evidence concerning its properties and its predicted or observed environmental fate and behaviour indicate that it may present a danger to the structure and/or the functioning of the stratospheric ozone layer. 5.1.3. Classification criteria for mixtures 5.1.3.1. Mixtures shall be classified as hazardous to the ozone layer (Category 1) on the basis of the individual concentration of the substance(s) contained therein that are also classified as hazardous to the ozone layer (Category 1), in accordance with Table 5.1. Table 5.1 Generic concentration limits for substances (in a mixture), classified as hazardous to the ozone layer (Category 1), that trigger classification of the mixture as hazardous to the ozone layer (Category 1) Classification of the substance Classification of the mixture Hazardous to the ozone layer (Category 1) C ≥ 0,1 % 5.1.4. Hazard communication 5.1.4.1. Label elements shall be used for substances or mixtures meeting the criteria for classification in this hazard class in accordance with Table 5.2. Table 5.2 Label elements for hazardous to the ozone layer Symbol/pictogram Signal word Warning Hazard statement H420: Harms public health and the environment by destroying ozone in the upper atmosphere Precautionary statements P502

MODIFIED +146 −0 Annex II SPECIAL RULES FOR LABELLING AND PACKAGING OF CERTAIN SUBSTANCES AND MIXTURES

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Section 2.8 now adds a sentence stating that where a mixture is labelled in accordance with Section 2.4 or 2.5, the EUH208 statement may be omitted from the label for the substance concerned.

The earlier version of section 2.8 contained no such allowance to omit EUH208 in those circumstances.

Cited: Annex II, v2 · Annex II, v1

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ANNEX II SPECIAL RULES FOR LABELLING AND PACKAGING OF CERTAIN SUBSTANCES AND MIXTURES This Annex consists of 5 parts: Part 1 contains special rules for the labelling of certain classified substances and mixtures. Part 2 sets out rules for additional hazard statements to be … 1,152 unchanged words … addition to the one that leads to the classification of the mixture) and present in a concentration equal to or greater than that specified in Table 3.4.6 of Annex I shall bear the name(s) of that/those substance(s) on the label. Where a mixture is labelled in accordance with Section 2.4 or 2.5, the statement EUH208 may be omitted from the label for the substance concerned. 2.9. Liquid mixtures containing halogenated hydrocarbons For liquid mixtures which show no flashpoint or a flashpoint higher than 60 oC but not more than 93 oC and contain a halogenated hydrocarbon and more than 5 % highly flammable or flammable substances, … 1,106 unchanged words … the following wording: EUH401 — To avoid risks to human health and the environment, comply with the instructions for use 5. PART 5: LIST OF HAZARDOUS SUBSTANCES AND MIXTURES TO WHICH ARTICLE 29(3) APPLIES Ready mixed cement and concrete in the wet state.

MODIFIED +623 −618 Annex III LIST OF HAZARD STATEMENTS, SUPPLEMENTAL HAZARD INFORMATION AND SUPPLEMENTAL LABEL ELEMENTS

applies from: unchanged

No explanation shipped — the difference between the two versions lies beyond the characters this stage can show, so no explanation was requested.

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ANNEX III LIST OF HAZARD STATEMENTS, SUPPLEMENTAL HAZARD INFORMATION AND SUPPLEMENTAL LABEL ELEMENTS 1. Part 1: hazard statements … 967 unchanged lines … SL Zdravju škodljivo v stiku s kožo. FI Haitallista joutuessaan iholle. SV Skadligt vid hudkontakt. H314 Language 3.2 — Skin corrosion/irritation, Hazard Category 1A, 1B, 1C H314 Language 3.2 — Skin corrosion/irritation, Hazard Category 1, Sub-Categories 1A, 1B, 1C BG Причинява тежки изгаряния на кожата и сериозно увреждане на очите. ES Provoca quemaduras graves en la piel y lesiones oculares graves. CS Způsobuje těžké poleptání kůže a poškození očí. DA Forårsager svære forbrændinger af huden og øjenskader. CS Způsobuje těžké poleptání kůže a poškození očí. DA Forårsager svære ætsninger af huden og øjenskader. DE Verursacht schwere Verätzungen der Haut und schwere Augenschäden. ET Põhjustab rasket nahasöövitust ja silmakahjustusi. EL Προκαλεί σοβαρά δερματικά εγκαύματα και οφθαλμικές βλάβες. EN Causes severe skin burns and eye damage. FR Provoque des brûlures de la peau et des lésions oculaires graves. FR Provoque des brûlures de la peau et de graves lésions des yeux. GA Ina chúis le dónna tromchúiseacha craicinn agus le damáiste don tsúil. HR Uzrokuje teške opekline kože i ozljede oka. IT Provoca gravi ustioni cutanee e gravi lesioni oculari. LV Izraisa smagus ādas apdegumus un acu bojājumus. LT Smarkiai nudegina odą ir pažeidžia akis. HU Súlyos égési sérülést és szemkárosodást okoz. MT Jagħmel ħruq serju lill-ġilda u ħsara lill-għajnejn. NL Veroorzaakt ernstige brandwonden en oogletsel. PL Powoduje poważne oparzenia skóry oraz uszkodzenia oczu. PL Powoduje poważne oparzenia skóry oraz uszkodzenia oczu . PT Provoca queimaduras na pele e lesões oculares graves. RO Provoacă arsuri grave ale pielii și lezarea ochilor. SK Spôsobuje vážne poleptanie kože a poškodenie očí. … 50 unchanged lines … SL Lahko povzroči alergijski odziv kože. FI Voi aiheuttaa allergisen ihoreaktion. SV Kan orsaka allergisk hudreaktion. H318 Language 3.3 — Serious eye damage/eye irritation, Hazard Category 1 H318 Language 3.3 — Serious eye damage/eye irritation, Hazard Category 1 BG Предизвиква сериозно увреждане на очите. ES Provoca lesiones oculares graves. CS Způsobuje vážné poškození očí. DA Forårsager alvorlig øjenskade. DE Verursacht schwere Augenschäden. ET Põhjustab raskeid silmakahjustusi. EL Προκαλεί σοβαρή οφθαλμική βλάβη. EN Causes serious eye damage. FR Provoque des lésions oculaires graves. FR Provoque de graves lésions des yeux. GA Ina chúis le damáiste tromchúiseach don tsúil. HR Uzrokuje teške ozljede oka. IT Provoca gravi lesioni oculari. … 627 unchanged lines … BG Токсичен при контакт с кожата или при вдишване ES Tóxico en contacto con la piel o si se inhala CS Toxický při styku s kůží a při vdechování DA Livsfarlig ved hudkontakt eller indånding DA Giftig ved hudkontakt eller indånding DE Giftig bei Hautkontakt oder Einatmen ET Nahale sattumisel või sissehingamisel mürgine EL Τοξικό σε επαφή με το δέρμα ή σε περίπτωση εισπνοής EN Toxic in contact with skin or if inhaled FR Toxique par contact cutané ou par inhalation GA Ábhar tocsaineach má theagmhaíonn leis an gcraiceann nó má ionanálaítear é HR Otrovno u dodiru s kožom ili ako se udiše IT Tossico a contatto con la pelle o se inalato LV Toksisks saskarē ar ādu vai ja iekļūst elpceļos LT Toksiška susilietus su oda arba įkvėpus HU Bőrrel érintkezve vagy belélegezve mérgező MT Tossika jekk tmiss mal-ġilda jew tittieħeb bin-nifs MT Tossika jekk tmiss mal-ġilda jew tittieħeb bin- nifs NL Giftig bij contact met de huid en bij inademing PL Działa toksycznie w kontakcie ze skórą lub w następstwie wdychania PT Tóxico em contacto com a pele ou por inalação … 35 unchanged lines … BG Вреден при поглъщане или при контакт с кожата ES Nocivo en caso de ingestión o en contacto con la piel CS Zdraví škodlivý při požití a při styku s kůží DA Livsfarlig ved indtagelse eller hudkontakt DA Farlig ved indtagelse eller hudkontakt DE Gesundheitsschädlich bei Verschlucken oder Hautkontakt ET Allaneelamisel või nahale sattumisel kahjulik EL Επιβλαβές σε περίπτωση κατάποσης ή σε επαφή με το δέρμα EN Harmful if swallowed or in contact with skin FR Nocif en cas d'ingestion ou de contact cutané GA Ábhar dochrach má shlogtar é nó má theagmhaíonn leis an gcraiceann HR Štetno ako se proguta ili u dodiru s kožom IT Nocivo se ingerito o a contatto con la pelle LV Kaitīgs, ja norīts vai saskaras ar ādu LT Kenksminga prarijus arba susilietus su oda HU Lenyelve vagy bőrrel érintkezve ártalmas MT Tagħmel ħsara jekk tinbela' jew jekk tmiss mal-ġilda MT Tagħmel ħsara jekk tinbela' jew jekk tmiss mal- ġilda NL Schadelijk bij inslikken en bij contact met de huid PL Działa szkodliwie po połknięciu lub w kontakcie ze skórą PT Nocivo por ingestão ou contacto com a pele … 913 unchanged lines … SL Da bi se izognili tveganjem za ljudi in okolje, ravnajte v skladu z navodili za uporabo. FI Noudata käyttöohjeita ihmisen terveydelle ja ympäristölle aiheutuvien vaarojen välttämiseksi. SV För att undvika risker för människors hälsa och för miljön, följ bruksanvisningen.

MODIFIED +79,412 −51,738 Annex IV LIST OF PRECAUTIONARY STATEMENTS

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The introductory notes gain a new sentence explaining that where column 5 states a precautionary statement may be omitted because another statement is given on the label, that information may be used when selecting statements under Articles 22 and 28, and the wording describing the backslash/diagonal mark symbol is rephrased from 'a backslash or diagonal mark' to 'a forward slash or diagonal mark'.

Within Part 1's tables of precautionary statements, numerous individual entries such as P202, P220, P222, P223, P230 to P243, P250, P280, P282, P283, P302, P312, P321, P334, P353, P370 to P381, P401, P403, P406, P407, P411 to P413, P420 and related combined codes have revised wording, revised hazard class/category listings, or revised conditions-for-use text compared with the earlier version.

New combined codes such as P336 + P315, P302 + P335 + P334, P370 + P372 + P380 + P373 and P370 + P380 + P375 + [P378] appear among the response statements that were not present before.

Cited: Annex IV, v2 · Annex IV, v1

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ANNEX IV LIST OF PRECAUTIONARY STATEMENTS In selecting the precautionary statements in accordance with Articles 22 and 28(3), suppliers may combine the Precautionary Statements in the table below, having regard to clarity and comprehensibility of the precautionary advice. Where square brackets […] appear around some text in a precautionary statement in column (2), this indicates that the text in square brackets is not appropriate in every case and should be used only in certain circumstances. In these cases, conditions for use explaining when the text should be used are given in column (5). When a backslash or diagonal mark [/] appears in a precautionary statement text in column (2), it indicates that a choice has to be made between the phrases they separate in accordance with the indications provided in column (5). When a forward slash or diagonal mark [/] appears in a precautionary statement text in column (2), this indicates that a choice has to be made between the phrases they separate in accordance with the indications provided in column (5). When three full stops […] appear in a precautionary statement text in column (2), details on the information to be provided are indicated in column (5). Where the text in column 5 indicates that a precautionary statement may be omitted if another precautionary statement is given on the label, this information may be used in selecting precautionary statements in accordance with Articles 22 and 28. 1. Part 1: Criteria for the selection of precautionary statements Table 6.1 Precautionary statements — General Code General precautionary statements Hazard class Hazard category Conditions for use (1) (2) (3) (4) (5) P101 If medical advice is needed, have product container or label at hand. as appropriate Consumer products P102 Keep out of reach of children. as appropriate Consumer products P103 Read label before use. as appropriate Consumer products Table 6.2 Precautionary statements — Prevention Code Prevention precautionary statements Hazard class Hazard category Conditions for use (1) (2) (3) (4) (5) P201 Obtain special instructions before use. Explosives (section 2.1) Unstable explosive Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Reproductive toxicity — effects on or via lactation (section 3.7) Additional category P202 Do not handle until all safety precautions have been read and understood. Explosives (section 2.1) Unstable explosive Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Flammable gases (including chemically unstable gases) (section 2.2) A, B (chemically unstable gases) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Flammable gases (section 2.2) 1, 2 P202 Do not handle until all safety precautions have been read and understood. Flammable gases (including chemically unstable gases) (Section 2.2) A, B (chemically unstable gases) Germ cell mutagenicity (Section 3.5) 1A, 1B, 2 Carcinogenicity (Section 3.6) 1A, 1B, 2 Reproductive toxicity (Section 3.7) 1A, 1B, 2 P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Flammable gases (section 2.2) 1, 2 Aerosols (section 2.3) 1, 2, 3 Flammable liquids (section 2.6) 1, 2, 3 Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 Organic peroxides (section 2.15) Types A, B, C, D, E, F P211 Do not spray on an open flame or other ignition source. Aerosols (section 2.3) 1, 2 P220 Keep/Store away from clothing/…/combustible materials. Oxidising gases (section 2.4) 1 …Manufacturer/supplier to specify other incompatible materials. Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Oxidising liquids (section 2.13) 1 — specify to keep away from clothing and other combustible materials. 2, 3 …Manufacturer/supplier to specify other incompatible materials. Oxidising solids (section 2.14) 1 — specify to keep away from clothing and other combustible materials. 2, 3 …Manufacturer/supplier to specify other incompatible materials. Organic peroxides (section 2.15) Types A, B, C, D, E, F P211 Do not spray on an open flame or other ignition source. Aerosols (section 2.3) 1, 2 P220 Keep away from clothing and other combustible materials. Oxidising gases (Section 2.4) 1 Oxidising liquids (Section 2.13) 1, 2, 3 Oxidising solids (Section 2.14) 1, 2, 3 P221 Take any precaution to avoid mixing with combustibles/… Oxidising liquids (section 2.13) 1, 2, 3 … Manufacturer/supplier to specify incompatible materials. Oxidising solids (section 2.14) 1, 2, 3 P222 Do not allow contact with air. Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 P223 Do not allow contact with water. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2 P230 Keep wetted with … Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.5 … Manufacturer/supplier to specify appropriate material. if drying out increases explosion hazard, except as needed for manufacturing or operating processes (e.g. nitrocellulose). P231 Handle under inert gas. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P232 Protect from moisture. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P233 Keep container tightly closed. Flammable liquids (section 2.6) 1, 2, 3 Acute toxicity — inhalation (section 3.1) 1, 2, 3 if product is volatile so as to generate hazardous atmosphere. Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P234 Keep only in original container. Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Organic peroxides (section 2.15) Types A, B, C, D, E, F Corrosive to metals (section 2.16) 1 P235 Keep cool. Flammable liquids (section 2.6) 1, 2, 3 Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F Self-heating substances and mixtures (section 2.11) 1, 2 Organic peroxides (section 2.15) Types A, B, C, D, E, F P240 Ground/bond container and receiving equipment. Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 if the explosive is electrostatically sensitive. Flammable liquids (section 2.6) 1, 2, 3 if electrostatically sensitive material is for reloading. if product is volatile so as to generate hazardous atmosphere. Flammable solids (section 2.7) 1, 2 if electrostatically sensitive material is for reloading. P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. Flammable liquids (section 2.6) 1, 2, 3 … Manufacturer/supplier to specify other equipment. Flammable solids (section 2.7) 1, 2 … Manufacturer/supplier to specify other equipment. if dust clouds can occur. P242 Use only non-sparking tools. Flammable liquids (section 2.6) 1, 2, 3 P243 Take precautionary measures against static discharge. Flammable liquids (section 2.6) 1, 2, 3 P244 Keep valves and fittings free from oil and grease. Oxidising gases (section 2.4) 1 P250 Do not subject to grinding/shock/…/friction. Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 … Manufacturer/supplier to specify applicable rough handling. P222 Do not allow contact with air. Pyrophoric liquids (Section 2.9) 1 — if emphasis of the hazard statement is deemed necessary Pyrophoric solids (Section 2.10) 1 P223 Do not allow contact with water. Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2 — if emphasis of the hazard statement is deemed necessary P230 Keep wetted with … Explosives (Section 2.1) Divisions 1.1, 1.2, 1.3, 1.5 — for substances and mixtures which are wetted, diluted, dissolved or suspended with a phlegmatiser in order to reduce or suppress their explosive properties (desensitised explosives) … Manufacturer/supplier to specify appropriate material. P231 Handle and store contents under inert gas/… Pyrophoric liquids (Section 2.9) 1 … Manufacturer/supplier to specify appropriate liquid or gas if inert gas is not appropriate. Pyrophoric solids (Section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2, 3 — if the substance or mixture reacts readily with moisture in air. … Manufacturer/supplier to specify appropriate liquid or gas if inert gas is not appropriate. P232 Protect from moisture. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P233 Keep container tightly closed. Flammable liquids (Section 2.6) 1, 2, 3 — if the liquid is volatile and may generate an explosive atmosphere Pyrophoric liquids (Section 2.9) 1 Pyrophoric solids (Section 2.10) 1 Acute toxicity — inhalation (Section 3.1) 1, 2, 3 — if the chemical is volatile and may generate a hazardous atmosphere Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) 3 Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) 3 P234 Keep only in original packaging. Explosives (Section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F Organic peroxides (Section 2.15) Types A, B, C, D, E, F Corrosive to metals (Section 2.16) 1 P235 Keep cool. Flammable liquids (Section 2.6) 1, 2, 3 — for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F — may be omitted if P411 is given on the label Self-heating substances and mixtures (Section 2.11) 1, 2 — may be omitted if P413 is given on the label Organic peroxides (Section 2.15) Types A, B, C, D, E, F — may be omitted if P411 is given on the label P240 Ground and bond container and receiving equipment. Explosives (Section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 — if the explosive is electrostatically sensitive Flammable liquids (Section 2.6) 1, 2, 3 — if the liquid is volatile and may generate an explosive atmosphere Flammable solids (Section 2.7) 1, 2 — if the solid is electrostatically sensitive Self-reactive substances and mixtures (Section 2.8) Types A,B,C, D, E, F — if electrostatically sensitive and able to generate an explosive atmosphere Organic peroxides (Section 2.15) P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment. Flammable liquids (Section 2.6) 1, 2, 3 if the liquid is volatile and may generate an explosive atmosphere. text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate. Flammable solids (Section 2.7) 1, 2 if dust clouds can occur. text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate. P242 Use non-sparking tools. Flammable liquids (Section 2.6) 1, 2, 3 — if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide). P243 Take action to prevent static discharges. Flammable liquids (Section 2.6) 1, 2, 3 — if the liquid is volatile and may generate an explosive atmosphere. P244 Keep valves and fittings free from oil and grease. Oxidising gases (section 2.4) 1 P250 Do not subject to grinding/shock/friction … Explosives (Section 2.1) Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 — if the explosive is mechanically sensitive … Manufacturer/supplier to specify applicable rough handling. P251 Do not pierce or burn, even after use. Aerosols (section 2.3) 1, 2, 3 P260 Do not breathe dust/fume/gas/mist/vapours/spray. Acute toxicity — inhalation (section 3.1) 1, 2 Manufacturer/supplier to specify applicable conditions. Specific target organ toxicity — single exposure (section 3.8) 1, 2 Specific target organ toxicity — repeated exposure (section 3.9) 1, 2 Skin corrosion (section 3.2) 1A, 1B, 1C Specify do not breathe dusts or mists. if inhalable particles of dusts or mists may occur during use. Reproductive toxicity — effects on or via lactation (section 3.7) Additional category P261 Avoid breathing dust/fume/gas/mist/vapours/spray. Acute toxicity — inhalation (section 3.1) 3, 4 Manufacturer/supplier to specify applicable conditions. may be omitted if P260 is given on the label Respiratory sensitisation (section 3.4) 1, 1A, 1B Skin sensitisation (section 3.4) 1, 1A, 1B Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P262 Do not get in eyes, on skin, or on clothing. Acute toxicity — dermal (section 3.1) 1, 2 P263 Avoid contact during pregnancy/while nursing. Reproductive toxicity — effects on or via lactation (section 3.7) Additional category P264 Wash … thoroughly after handling. Acute toxicity — oral (section 3.1) 1, 2, 3, 4 Manufacturer/supplier to specify parts of the body to be washed after handling. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. Acute toxicity — inhalation (Section 3.1) 3, 4 — may be omitted if P260 is given on the label Manufacturer/supplier to specify applicable conditions. Respiratory sensitisation (Section 3.4) 1, 1A, 1B Skin sensitisation (Section 3.4) 1, 1A, 1B Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) 3 Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) 3 P262 Do not get in eyes, on skin, or on clothing. Acute toxicity — dermal (section 3.1) 1, 2 P263 Avoid contact during pregnancy and while nursing. Reproductive toxicity — effects on or via lactation (Section 3.7) Additional category P264 Wash … thoroughly after handling. Acute toxicity — oral (section 3.1) 1, 2, 3, 4 Manufacturer/supplier to specify parts of the body to be washed after handling. Acute toxicity — dermal (section 3.1) 1, 2 Skin corrosion (section 3.2) 1A, 1B, 1C Skin irritation (section 3.2) 2 Eye irritation (section 3.3) 2 Reproductive toxicity — effects on or via lactation (section 3.7) Additional category Specific target organ toxicity — single exposure (section 3.8) 1, 2 Specific target organ toxicity — repeated exposure (section 3.9) 1 P270 Do not eat, drink or smoke when using this product. Acute toxicity — oral (section 3.1) 1, 2, 3, 4 Acute toxicity — dermal (section 3.1) 1, 2 Reproductive toxicity — effects on or via lactation (section 3.7) Additional category Specific target organ toxicity — single exposure (section 3.8) 1, 2 Specific target organ toxicity — repeated exposure (section 3.9) 1 P271 Use only outdoors or in a well-ventilated area. Acute toxicity — inhalation (section 3.1) 1, 2, 3, 4 Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P272 Contaminated work clothing should not be allowed out of the workplace. Skin sensitisation (section 3.4) 1, 1A, 1B P273 Avoid release to the environment. Hazardous to the aquatic environment — acute aquatic hazard (section 4.1) 1 if this is not the intended use. Hazardous to the aquatic environment — long-term aquatic hazard (section 4.1) 1, 2, 3, 4 Hazardous to the ozone layer (section 5.1) 1 P280 Wear protective gloves/protective clothing/eye protection/face protection. Explosives (section 2.1) Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 Manufacturer/supplier to specify type of equipment. Specify face protection. Flammable liquids (section 2.6) 1, 2, 3 Manufacturer/supplier to specify type of equipment. Specify protective gloves and eye/face protection. Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Self-heating substances and mixtures (section 2.11) 1, 2 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 Organic peroxides (section 2.15) Types A, B, C, D, E, F Acute toxicity — dermal (section 3.1) 1, 2, 3, 4 Manufacturer/supplier to specify type of equipment. Specify protective gloves/clothing. Skin corrosion (section 3.2) 1A, 1B, 1C Manufacturer/supplier to specify type of equipment. Specify protective gloves/clothing and eye/face protection. Skin irritation (section 3.2) 2 Manufacturer/supplier to specify type of equipment. Specify protective gloves. Skin sensitisation (section 3.4) 1, 1A, 1B Severe eye damage/(section 3.3) 1 Manufacturer/supplier to specify type of equipment. Specify eye/face protection. Eye irritation (section 3.3) 2 Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Manufacturer/supplier to specify type of equipment. Carcinogenicity (section 3.6) 1A, 1B, 2 Manufacturer/supplier to specify type of equipment. Reproductive toxicity (section 3.7) 1A, 1B, 2 Manufacturer/supplier to specify type of equipment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Explosives (Section 2.1) Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 Manufacturer/supplier to specify the appropriate type of equipment. Flammable liquids (Section 2.6) 1, 2, 3 Flammable solids (Section 2.7) 1, 2 Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (Section 2.9) 1 Pyrophoric solids (Section 2.10) 1 Self-heating substances and mixtures (Section 2.11) 1, 2 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2, 3 Oxidising liquids (Section 2.13) 1, 2, 3 Oxidising solids (Section 2.14) 1, 2, 3 Organic peroxides (Section 2.15) Types A, B, C, D, E, F Acute toxicity — dermal (Section 3.1) 1, 2, 3, 4 — Specify protective gloves/clothing Manufacturer/supplier may further specify type of equipment where appropriate. Skin corrosion (Section 3.2) 1, 1A, 1B, 1C — Specific protective gloves/clothing and eye/face protection Manufacturer/supplier may further specify type of equipment where appropriate. Skin irritation (Section 3.2) 2 — Specify protective gloves. Manufacturer/supplier may further specify type of equipment where appropriate. Skin sensitisation (Section 3.4) 1, 1A, 1B Serious eye damage (Section 3.3) 1 — Specify eye/face protection. Manufacturer/supplier may further specify type of equipment where appropriate. Eye irritation (Section 3.3) 2 Germ cell mutagenicity (Section 3.5) 1A, 1B, 2 Manufacturer/ supplier to specify the appropriate type of equipment. Carcinogenicity (Section 3.6) 1A, 1B, 2 Reproductive toxicity (Section 3.7) 1A, 1B, 2 P281 Use personal protective equipment as required. Explosives (section 2.1) Unstable explosive Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 P282 Wear cold insulating gloves/face shield/eye protection. Gases under pressure (section 2.5) Refrigerated liquefied gas P283 Wear fire/flame resistant/retardant clothing. Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P284 [In case of inadequate ventilation] wear respiratory protection. Acute toxicity — inhalation (section 3.1) 1, 2 Manufacturer/supplier to specify equipment. text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use. Respiratory sensitisation (section 3.4) 1, 1A, 1B P282 Wear cold insulating gloves and either face shield or eye protection. Gases under pressure (Section 2.5) Refrigerated liquefied gas P283 Wear fire resistant or flame retardant clothing. Oxidising liquids (Section 2.13) 1 Oxidising solids (Section 2.14) 1 P284 [In case of inadequate ventilation] wear respiratory protection. Acute toxicity — inhalation (Section 3.1) 1, 2 — text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use. Manufacturer/supplier to specify equipment. Respiratory sensitisation (Section 3.4) 1, 1A, 1B P285 In case of inadequate ventilation wear respiratory protection. Respiratory sensitisation (section 3.4) 1, 1A, 1B Manufacturer/supplier to specify equipment. P231 + P232 Handle under inert gas. Protect from moisture. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P235 + P410 Keep cool. Protect from sunlight. Self-heating substances and mixtures (section 2.11) 1, 2 Table 6.3 P231 + P232 Handle and store contents under inert gas/… Protect from moisture. Pyrophoric liquids (Section 2.9) 1 … Manufacturer/supplier to specify the appropriate liquid or gas if inert gas is not appropriate. Pyrophoric solids (Section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2, 3 — if the substance or mixture reacts readily with moisture in air. … Manufacturer/supplier to specify appropriate liquid or gas if inert gas is not appropriate. P235 + P410 Keep cool. Protect from sunlight. Self-heating substances and mixtures (section 2.11) 1, 2 Table 6.3 Precautionary statements — Response Code Response precautionary statements Hazard class Hazard category Conditions for use (1) (2) (3) (4) (5) P301 IF SWALLOWED: Acute toxicity — oral (section 3.1) 1, 2, 3, 4 Skin corrosion (section 3.2) 1A, 1B, 1C Aspiration Hazard (section 3.10) 1 P302 IF ON SKIN: Pyrophoric liquids (section 2.9) 1 Acute toxicity — dermal (section 3.1) 1, 2, 3, 4 Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B P303 IF ON SKIN (or hair): Flammable liquids (section 2.6) 1, 2, 3 Skin corrosion (section 3.2) 1A, 1B, 1C P302 IF ON SKIN: Pyrophoric liquids (Section 2.9) 1 Pyrophoric solids (Section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2 Acute Toxicity, dermal (Section 3.1) 1, 2, 3, 4 Skin irritation (Section 3.2) 2 Skin sensitisation (Section 3.4) 1, 1A, 1B P303 IF ON SKIN (or hair): Flammable liquids (section 2.6) 1, 2, 3 Skin corrosion (section 3.2) 1A, 1B, 1C P304 IF INHALED: Acute toxicity — inhalation (section 3.1) 1, 2, 3, 4 Skin corrosion (section 3.2) 1A, 1B, 1C Respiratory sensitisation (section 3.4) 1, 1A, 1B Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P305 IF IN EYES: Skin corrosion (section 3.2) 1A, 1B, 1C Serious eye damage/eye irritation (section 3.3) 1 Eye irritation (section 3.3) 2 P306 IF ON CLOTHING: Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P307 IF exposed: Specific target organ toxicity — single exposure (section 3.8) 1 P308 IF exposed or concerned: Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Reproductive toxicity — effects on or via lactation (section 3.7) Additional category Specific target organ toxicity, single exposure (section 3.8) 1, 2 P309 IF exposed or if you feel unwell: Specific target organ toxicity — single exposure (section 3.8) 2 P310 Immediately call a POISON CENTER/doctor/… Acute toxicity — oral (section 3.1) 1, 2, 3 …Manufacturer/supplier to specify the appropriate source of emergency medical advice. Acute toxicity — dermal (section 3.1) 1, 2 Acute toxicity — inhalation (section 3.1) 1, 2 Skin corrosion (section 3.2) 1A, 1B, 1C Serious eye damage/eye irritation (section 3.3) 1 Aspiration hazard (section 3.10) 1 P311 Call a POISON CENTER/doctor/… Acute toxicity — inhalation (section 3.1) 3 …Manufacturer/supplier to specify the appropriate source of emergency medical advice. Respiratory sensitisation (section 3.4) 1, 1A, 1B Specific target organ toxicity — single exposure (section 3.8) 1, 2 P312 Call a POISON CENTER/doctor/…/if you feel unwell. Acute toxicity — oral (section 3.1) 4 …Manufacturer/supplier to specify the appropriate source of emergency medical advice. Acute toxicity — dermal (section 3.1) 3, 4 Acute toxicity — inhalation (section 3.1) 4 Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P312 Call a POISON CENTRE/doctor/… if you feel unwell. Acute toxicity — oral (Section 3.1) 4 … Manufacturer/supplier to specify the appropriate source of emergency medical advice. Acute toxicity — dermal (Section 3.1) 3, 4 Acute toxicity — inhalation (Section 3.1) 4 Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) 3 Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) 3 P313 Get medical advice/attention. Skin irritation (section 3.2) 2, 3 Eye irritation (section 3.3) 2 Skin sensitisation (section 3.4) 1, 1A, 1B Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Reproductive toxicity — effects on or via lactation (section 3.7) Additional category P314 Get medical advice/attention if you feel unwell. Specific target organ toxicity — repeated exposure (section 3.9) 1, 2 P315 Get immediate medical advice/attention. Gases under pressure (section 2.5) Refrigerated liquefied gas P320 Specific treatment is urgent (see … on this label). Acute toxicity — inhalation (section 3.1) 1, 2 … Reference to supplemental first aid instruction. if immediate administration of antidote is required. P321 Specific treatment (see … on this label). Acute toxicity — oral (section 3.1) 1, 2, 3 … Reference to supplemental first aid instruction. if immediate administration of antidote is required. Acute toxicity, dermal (section 3.1) 1, 2, 3, 4 … Reference to supplemental first aid instruction. if immediate measures, such as specific cleansing agent, are advised. Acute toxicity — inhalation (section 3.1) 3 … Reference to supplemental first aid instruction. if immediate specific measures are required. Skin corrosion (section 3.2) 1A, 1B, 1C … Reference to supplemental first aid instruction. manufacturer/supplier may specify a cleansing agent if appropriate. Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A,1B Specific target organ toxicity — single exposure (section 3.8) 1 … Reference to supplemental first aid instruction. if immediate measures are required. P314 Get medical advice/attention if you feel unwell. Specific target organ toxicity — repeated exposure (section 3.9) 1, 2 P315 Get immediate medical advice/attention. Gases under pressure (section 2.5) Refrigerated liquefied gas P320 Specific treatment is urgent (see … on this label). Acute toxicity — inhalation (Section 3.1) 1, 2 — if immediate administration of antidote is required. … Reference to supplemental first aid instruction. P321 Specific treatment (see … on this label). Acute toxicity — oral (Section 3.1) 1, 2, 3 — if immediate administration of antidote is required. … Reference to supplemental first aid instruction. Acute toxicity, dermal (Section 3.1) 1, 2, 3, 4 — if immediate measures such as specific cleansing agent are advised. … Reference to supplemental first aid instruction. Acute toxicity — inhalation (Section 3.1) 3 — if immediate specific measures are required. … Reference to supplemental first aid instruction. Skin corrosion (Section 3.2) 1, 1A, 1B, 1C … Reference to supplemental first aid instruction. Manufacturer/supplier may specify a cleansing agent if appropriate. Skin irritation (Section 3.2) 2 Skin sensitisation (Section 3.4) 1, 1A, 1B Specific target organ toxicity — single exposure (Section 3.8) 1 — if immediate measures are required. … Reference to supplemental first aid instruction. P322 Specific measures (see … on this label). Acute toxicity — dermal (section 3.1) 1, 2 … Reference to supplemental first aid instruction. if immediate measures such as specific cleansing agent is advised. Acute toxicity — dermal (section 3.1) 3, 4 … Reference to supplemental first aid instruction. if measures such as specific cleansing agent is advised. P330 Rinse mouth. Acute toxicity — oral (section 3.1) 1, 2, 3, 4 Skin corrosion (section 3.2) 1A, 1B, 1C P331 Do NOT induce vomiting. Skin corrosion (section 3.2) 1A, 1B, 1C Aspiration hazard (section 3.10) 1 P332 If skin irritation occurs: Skin irritation (section 3.2) 2, 3 P333 If skin irritation or rash occurs: Skin sensitisation (section 3.4) 1, 1A, 1B P334 Immerse in cool water/wrap in wet bandages. Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2 P332 If skin irritation occurs: Skin irritation (section 3.2) 2, 3 P333 If skin irritation or rash occurs: Skin sensitisation (section 3.4) 1, 1A, 1B P334 Immerse in cool water [or wrap in wet bandages]. Pyrophoric liquids (Section 2.9) 1 — text in square brackets to be used for pyrophoric liquids and solids Pyrophoric solids (Section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2 Use only immerse in cool water. Text in square brackets should not be used. P335 Brush off loose particles from skin. Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2 P336 Thaw frosted parts with lukewarm water. Do not rub affected area. Gases under pressure (section 2.5) Refrigerated liquefied gas P337 If eye irritation persists: Eye irritation (section 3.3) 2 P338 Remove contact lenses, if present and easy to do. Continue rinsing. Skin corrosion (section 3.2) 1A, 1B, 1C Serious eye damage/eye irritation (section 3.3) 1 Eye irritation (section 3.3) 2 P340 Remove person to fresh air and keep comfortable for breathing. Acute toxicity — inhalation (section 3.1) 1, 2, 3, 4 Skin corrosion (section 3.2) 1A, 1B, 1C Respiratory sensitisation (section 3.4) 1, 1A, 1B Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Respiratory sensitisation (section 3.4) 1, 1A, 1B P342 If experiencing respiratory symptoms: Respiratory sensitisation (section 3.4) 1, 1A, 1B P350 Gently wash with plenty of soap and water. Acute toxicity — dermal (section 3.1) 1, 2 P351 Rinse cautiously with water for several minutes. Skin corrosion (section 3.2) 1A, 1B, 1C Serious eye damage/eye irritation (section 3.3) 1 Eye irritation (section 3.3) 2 P352 Wash with plenty of water/… Acute toxicity — dermal (section 3.1) 1, 2, 3, 4 …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B P353 Rinse skin with water/shower. Flammable liquids (section 2.6) 1, 2, 3 Skin corrosion (section 3.2) 1A, 1B, 1C P353 Rinse skin with water [or shower]. Flammable liquids (Section 2.6) 1, 2, 3 — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. Skin corrosion (Section 3.2) 1, 1A, 1B, 1C P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P361 Take off immediately all contaminated clothing. Flammable liquids (section 2.6) 1, 2, 3 Acute toxicity — dermal (section 3.1) 1, 2, 3 Skin corrosion (section 3.2) 1A, 1B, 1C P362 Take off contaminated clothing. Acute toxicity, dermal (section 3.1) 4 Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B P363 Wash contaminated clothing before reuse. Skin corrosion (section 3.2) 1A, 1B, 1C P364 And wash it before reuse. Acute toxicity, dermal (section 3.1) 1, 2, 3, 4 Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B P370 In case of fire: Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Oxidising gases (section 2.4) 1 Flammable liquids (section 2.6) 1, 2, 3 Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 P363 Wash contaminated clothing before reuse. Skin corrosion (section 3.2) 1A, 1B, 1C P364 And wash it before reuse. Acute toxicity, dermal (section 3.1) 1, 2, 3, 4 Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B P370 In case of fire: Explosives (Section 2.1) Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 Oxidising gases (Section 2.4) 1 Flammable liquids (Section 2.6) 1, 2, 3 Flammable solids (Section 2.7) 1, 2 Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (Section 2.9) 1 Pyrophoric solids (Section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2, 3 Oxidising liquids (Section 2.13) 1, 2, 3 Oxidising solids (Section 2.14) 1, 2, 3 Organic Peroxides (Section 2.15) Types A, B, C, D, E, F P371 In case of major fire and large quantities: Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P372 Explosion risk in case of fire. Explosives (section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 except if explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P373 DO NOT fight fire when fire reaches explosives. Explosives (section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 P374 Fight fire with normal precautions from a reasonable distance. Explosives (section 2.1) Division 1.4 if explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P375 Fight fire remotely due to the risk of explosion. Self-reactive substances and mixtures (section 2.8) Types A, B Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P372 Explosion risk. Explosives (Section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5 Division 1.4 — except for explosives of division 1.4 (compatibility group S) in transport packaging. Self-reactive substances and mixtures (Section 2.8) Type A Organic peroxides (Section 2.15) Type A P373 DO NOT fight fire when fire reaches explosives. Explosives (Section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5 Division 1.4 — except for explosives of division 1.4 (compatibility group S) in transport packaging. Self-reactive substances and mixtures (Section 2.8) Type A Organic peroxides (Section 2.15) Type A P374 Fight fire with normal precautions from a reasonable distance. Explosives (section 2.1) Division 1.4 if explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P375 Fight fire remotely due to the risk of explosion. Explosives (Section 2.1) Division 1.4 — for explosives of division 1.4 (compatibility group S) in transport packaging. Self-reactive substances and mixtures (Section 2.8) Type B Oxidising liquids (Section 2.13) 1 Oxidising solids (Section 2.14) 1 Organic peroxides (Section 2.15) Type B P376 Stop leak if safe to do so. Oxidising gases (section 2.4) 1 P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Flammable gases (section 2.2) 1, 2 P378 Use…to extinguish Flammable liquids (section 2.6) 1, 2, 3 … Manufacturer/supplier to specify appropriate media if water increases risk. Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 P380 Evacuate area. Explosives (section 2.1) Unstable explosives Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Self-reactive substances and mixtures (section 2.8) Types A, B Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P381 Eliminate all ignition sources if safe to do so. Flammable gases (section 2.2) 1, 2 P390 Absorb spillage to prevent material damage. Corrosive to metals (section 2.16) 1 P391 Collect spillage. Hazardous to the aquatic environment – acute aquatic hazard (section 4.1) 1 Hazardous to the aquatic environment – long-term aquatic hazard (section 4.1) 1, 2 Do not extinguish, unless leak can be stopped safely. Flammable gases (section 2.2) 1, 2 P378 Use … to extinguish. Flammable liquids (Section 2.6) 1, 2, 3 — if water increases risk … Manufacturer/supplier to specify appropriate media Flammable solids (Section 2.7) 1, 2 Self-reactive substances and mixtures (Section 2.8) Types B, C, D, E, F Pyrophoric liquids (Section 2.9) 1 Pyrophoric solids (Section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2, 3 Oxidising liquids (Section 2.13) 1, 2, 3 Oxidising solids (Section 2.14) 1, 2, 3 Organic peroxides (Section 2.15) Types B, C, D, E, F P380 Evacuate area. Explosives (Section 2.1) Unstable explosives, Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Self-reactive substances and mixtures (Section 2.8) Types A, B Oxidising liquids (Section 2.13) 1 Oxidising solids (Section 2.14) 1 Organic peroxides (Section 2.15) Types A, B P381 In case of leakage, eliminate all ignition sources. Flammable gases (Section 2.2) 1, 2 P390 Absorb spillage to prevent material damage. Corrosive to metals (section 2.16) 1 P391 Collect spillage. Hazardous to the aquatic environment – acute aquatic hazard (section 4.1) 1 Hazardous to the aquatic environment – long-term aquatic hazard (section 4.1) 1, 2 P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/… Acute toxicity — oral (section 3.1) 1, 2, 3 …Manufacturer/supplier to specify the appropriate source of emergency medical advice. Aspiration hazard (section 3.10) 1 P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell. Acute toxicity — oral (section 3.1) 4 …Manufacturer/supplier to specify the appropriate source of emergency medical advice. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Skin corrosion (section 3.2) 1A, 1B, 1C P302 + P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages. Pyrophoric liquids (section 2.9) 1 P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water. Acute toxicity — dermal (section 3.1) 1, 2 P302 + P352 IF ON SKIN: Wash with plenty of water/… Acute toxicity — dermal (section 3.1) 1, 2, 3, 4 …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. P301 + P312 IF SWALLOWED: Call a POISON CENTRE/doctor/… if you feel unwell. Acute toxicity — oral (Section 3.1) 4 … Manufacturer/supplier to specify the appropriate source of emergency medical advice. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Skin corrosion (section 3.2) 1A, 1B, 1C P302 + P334 IF ON SKIN: Immerse in cool water or wrap in wet bandages. Pyrophoric liquids (Section 2.9) 1 P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water. Acute toxicity — dermal (section 3.1) 1, 2 P302 + P352 IF ON SKIN: Wash with plenty of water/… Acute toxicity — dermal (section 3.1) 1, 2, 3, 4 …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Flammable liquids (section 2.6) 1, 2, 3 Skin corrosion (section 3.2) 1A, 1B, 1C P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Acute toxicity — inhalation (section 3.1) 1, 2, 3, 4 Skin corrosion (section 3.2) 1A, 1B, 1C Respiratory sensitisation (section 3.4) 1, 1A, 1B Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Respiratory sensitisation (section 3.4) 1, 1A, 1B P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin corrosion (section 3.2) 1A, 1B, 1C Serious eye damage/eye irritation (section 3.3) 1 Eye irritation (section 3.3) 2 P306 + P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P308 + P311 IF exposed or concerned: Call a POISON CENTER/doctor/… Specific target organ toxicity — single exposure (section 3.8) 1, 2 …Manufacturer/supplier to specify the appropriate source of emergency medical advice. P308 + P313 IF exposed or concerned: Get medical advice/attention. Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Reproductive toxicity — effects on or via lactation (section 3.7) Additional category P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. Specific target organ toxicity — single exposure (section 3.8) 2 P332 + P313 If skin irritation occurs: Get medical advice/attention. Skin irritation (section 3.2) 2 P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. Skin sensitisation (section 3.4) 1, 1A, 1B P335 + P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2 P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. Specific target organ toxicity — single exposure (section 3.8) 2 P332 + P313 If skin irritation occurs: Get medical advice/attention. Skin irritation (Section 3.2) 2 — may be omitted when P333 + P313 is given on the label. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. Skin sensitisation (section 3.4) 1, 1A, 1B P336 + P315 Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention. Gases under pressure (Section 2.5) Refrigerated liquefied gas P335 + P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2 P337 + P313 If eye irritation persists: Get medical advice/attention. Eye irritation (section 3.3) 2 P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/… Respiratory sensitisation (section 3.4) 1, 1A, 1B …Manufacturer/supplier to specify the appropriate source of emergency medical advice. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. Acute toxicity, dermal (section 3.1) 1, 2, 3 P362 + P364 Take off contaminated clothing and wash it before reuse. Acute toxicity, dermal (section 3.1) 4 Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B P370 + P376 In case of fire: Stop leak if safe to do so. Oxidizing gases (section 2.4) 1 P370 + P378 In case of fire: Use … to extinguish. Flammable liquids (section 2.6) 1, 2, 3 …Manufacturer/supplier to specify appropriate media. if water increases risk. Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 P370 + P380 In case of fire: Evacuate area. Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Self-reactive substances and mixtures (section 2.8) Types A, B P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P370 + P376 In case of fire: Stop leak if safe to do so. Oxidizing gases (section 2.4) 1 P370 + P378 In case of fire: Use … to extinguish. Flammable liquids (Section 2.6) 1, 2, 3 — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. Flammable solids (Section 2.7) 1, 2 Self-reactive substances and mixtures (Section 2.8) Types C, D, E, F Pyrophoric liquids (Section 2.9) 1 Pyrophoric solids (Section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2, 3 Oxidising liquids (Section 2.13) 1, 2, 3 Oxidising solids (Section 2.14) 1, 2, 3 Organic peroxides (Section 2.15) Types C, D, E, F P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Skin corrosion (Section 3.2) 1, 1A, 1B, 1C P302 + P335 + P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. Pyrophoric solids (Section 2.10) 1 — text in square brackets to be used for pyrophoric solids Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2 — use only Immerse in cold water. Text in square brackets should not be used. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. Flammable liquids (Section 2.6) 1, 2, 3 — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. Skin corrosion (Section 3.2) 1, 1A, 1B, 1C P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin corrosion (Section 3.2) 1, 1A, 1B, 1C Serious eye damage/eye irritation (Section 3.3) 1 Eye irritation (Section 3.3) 2 P370 + P380 In case of fire: Evacuate area. Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Explosives (Section 2.1) Division 1.4 — for explosives of division 1.4 (compatibility group S) in transport packaging P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 P370 + P372 + P380 + P373 In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives Explosives (Section 2.1) Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5 Division 1.4 — except for explosives of division 1.4 (compatibility group S) in transport packaging. Self-reactive substances and mixtures (Section 2.8) Type A Organic peroxides (Section 2.15) Type A P370 + P380 + P375 + [P378] In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish]. Self-reactive substances and mixtures (Section 2.8) Type B — text in square brackets to be used if water increases risk. … Manufacturer/supplier to specify appropriate media. Organic peroxides (Section 2.15) Type B Table 6.4 Precautionary statements — Storage Code Storage precautionary statements Hazard class Hazard category Conditions for use (1) (2) (3) (4) (5) P401 Store … Explosives (section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 … in accordance with local/regional/national/international regulations (to be specified). P402 Store in a dry place. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P403 Store in a well-ventilated place. Flammable gases (section 2.2) 1, 2 if product is volatile so as to generate hazardous atmosphere. Oxidising gases (section 2.4) 1 Gases under pressure (section 2.5) Compressed gas Liquefied gas Refrigerated Liquefied gas Dissolved gas Flammable liquids (section 2.6) 1, 2, 3 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Acute toxicity — inhalation (section 3.1) 1, 2, 3 Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P401 Store in accordance with … Explosives (Section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 … Manufacturer/ supplier to specify local/regional/ national/international regulations as applicable. P402 Store in a dry place. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P403 Store in a well-ventilated place. Flammable gases (Section 2.2) 1, 2 Oxidising gases (Section 2.4) 1 Gases under pressure (Section 2.5) Compressed gas Liquefied gas Refrigerated Liquefied gas Dissolved gas Flammable liquids (Section 2.6) 1, 2, 3 — for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere. Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F — except for temperature controlled self-reactive substances and mixtures or organic peroxides because condensation and consequent freezing may take place. Organic peroxides (Section 2.15) Acute toxicity — inhalation (Section 3.1) 1, 2, 3 — if the substance or mixture is volatile and may generate a hazardous atmosphere. Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) 3 Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) 3 P404 Store in a closed container. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P405 Store locked up. Acute toxicity — oral (section 3.1) 1, 2, 3 Acute toxicity — dermal (section 3.1) 1, 2, 3 Acute toxicity — inhalation (section 3.1) 1, 2, 3 Skin corrosion (section 3.2) 1A, 1B, 1C Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Specific target organ toxicity — single exposure (section 3.8) 1, 2 Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 Aspiration hazard (section 3.10) 1 P406 Store in corrosive resistant/… container with a resistant inner liner. Corrosive to metals (section 2.16) 1 … Manufacturer/supplier to specify other compatible materials. P407 Maintain air gap between stacks/pallets. Self-heating substances and mixtures (section 2.11) 1, 2 P410 Protect from sunlight. Aerosols (section 2.3) 1,2, 3 Gases under pressure (section 2.5) Compressed gas P406 Store in a corrosion-resistant/… container with a resistant inner liner. Corrosive to metals (Section 2.16) 1 — may be omitted if P234 is given on the label … Manufacturer/supplier to specify other compatible materials. P407 Maintain air gap between stacks or pallets. Self-heating substances and mixtures (Section 2.11) 1, 2 P410 Protect from sunlight. Aerosols (section 2.3) 1,2, 3 Gases under pressure (section 2.5) Compressed gas Liquefied gas Dissolved gas — may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation Self-heating substances and mixtures (section 2.11) 1, 2 Organic peroxides (section 2.15) Types A, B, C, D, E, F P411 Store at temperatures not exceeding … oC/…oF. Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F … Manufacturer/supplier to specify temperature Organic peroxides (section 2.15) Types A, B, C, D, E, F P412 Do not expose to temperatures exceeding 50 °C/122 °F. Aerosols (section 2.3) 1, 2, 3 P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding … oC/…oF. Self-heating substances and mixtures (section 2.11) 1, 2 … Manufacturer/supplier to specify mass and temperature. P420 Store away from other materials. Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Self-heating substances and mixtures (section 2.11) 1, 2 Organic peroxides (section 2.15) Types A, B, C, D, E, F Self-heating substances and mixtures (section 2.11) 1, 2 Organic peroxides (section 2.15) Types A, B, C, D, E, F P411 Store at temperatures not exceeding … °C/… °F. Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F — if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary. … Manufacturer/supplier to specify temperature using the applicable temperature scale. Organic peroxides (Section 2.15) Types A, B, C, D, E, F P412 Do not expose to temperatures exceeding 50 °C/ 122 °F. Aerosols (Section 2.3) 1, 2, 3 Manufacturer/supplier to use applicable temperature scale. P413 Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F. Self-heating substances and mixtures (Section 2.11) 1, 2 … Manufacturer/supplier to specify mass and temperature using applicable scale. P420 Store separately. Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F Self-heating substances and mixtures (Section 2.11) 1,2 Oxidising liquids (Section 2.13) 1 Oxidising solids (Section 2.14) 1 Organic peroxides (Section 2.15) Types A,B,C,D,E,F P422 Store contents under … Pyrophoric liquids (section 2.9) 1 … Manufacturer/supplier to specify appropriate liquid or inert gas. Pyrophoric solids (section 2.10) 1 P402 + P404 Store in a dry place. Store in a closed container. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Acute toxicity — inhalation (section 3.1) 1, 2, 3 if product is volatile so as to generate hazardous atmosphere. Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 P403 + P235 Store in a well-ventilated place. Keep cool. Flammable liquids (section 2.6) 1, 2, 3 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F P410 + P403 Protect from sunlight. Store in a well-ventilated place. Gases under pressure (section 2.5) Compressed gas P402 + P404 Store in a dry place. Store in a closed container. Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 P403 + P233 Store in a well-ventilated place. Keep container tightly closed. Acute toxicity — inhalation (Section 3.1) 1, 2, 3 — if the substance or mixture is volatile and may generate a hazardous atmosphere. Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (Section 3.8) 3 P403 + P235 Store in a well-ventilated place. Keep cool. Flammable liquids (Section 2.6) 1, 2, 3 — for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere. P410 + P403 Protect from sunlight. Store in a well-ventilated place. Gases under pressure (Section 2.5) Compressed gas — P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation. Liquefied gas Dissolved gas — may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Aerosols (section 2.3) 1, 2, 3 P411 + P235 Store at temperatures not exceeding … oC/…oF. Keep cool. Organic peroxides (section 2.15) Types A, B, C, D, E, F … Manufacturer/supplier to specify temperature. Dissolved gas P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Aerosols (Section 2.3) 1, 2, 3 Manufacturer/ supplier to use applicable temperature scale. P411 + P235 Store at temperatures not exceeding … oC/…oF. Keep cool. Organic peroxides (section 2.15) Types A, B, C, D, E, F … Manufacturer/supplier to specify temperature. Table 6.5 Precautionary statements — Disposal Code Disposal precautionary statements Hazard class Hazard category Conditions for use (1) (2) (3) (4) (5) P501 Dispose of contents/container to … Explosives (section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 … in accordance with local/regional/national/international regulation (to be specified). Flammable liquids (section 2.6) 1, 2, 3 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 Organic peroxides (section 2.15) Types A, B, C, D, E, F Acute toxicity — oral (section 3.1) 1, 2, 3, 4 Acute toxicity — dermal (section 3.1) 1, 2, 3, 4 Acute toxicity — inhalation (section 3.1) 1, 2 Skin corrosion (section 3.2) 1A, 1B, 1C Respiratory sensitisation (section 3.4) 1, 1A, 1B Skin sensitisation (section 3.4) 1, 1A, 1B Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Specific target organ toxicity — single exposure (section 3.8) 1, 2 Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity — single exposure; narcosis (section 3.8) 3 Specific target organ toxicity — repeated exposure (section 3.9) 1, 2 Aspiration hazard (section 3.10) 1 Hazardous to the aquatic environment — acute aquatic hazard(section 4.1) 1 Hazardous to the aquatic environment — long-term aquatic hazard (section 4.1) 1, 2, 3, 4 P502 Refer to manufacturer/supplier for information on recovery/recycling Hazardous to the ozone layer (section 5.1) 1 2. Part 2: precautionary statements P501 Dispose of contents/container to … Explosives (Section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 … in accordance with local/regional/ national/international regulation (to be specified). Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both. Flammable liquids (Section 2.6) 1, 2, 3 Self-reactive substances and mixtures (Section 2.8) Types A, B, C, D, E, F Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) 1, 2, 3 Oxidising liquids (Section 2.13) 1, 2, 3 Oxidising solids (Section 2.14) 1, 2, 3 Organic peroxides (Section 2.15) Types A, B, C, D, E, F Acute toxicity — oral (Section 3.1) 1, 2, 3, 4 Acute toxicity — dermal (Section 3.1) 1, 2, 3, 4 Acute toxicity — inhalation (Section 3.1) 1, 2 Skin corrosion (Section 3.2) 1, 1A, 1B, 1C Respiratory sensitisation (Section 3.4) 1, 1A, 1B Skin sensitisation (Section 3.4) 1, 1A, 1B Germ cell mutagenicity (Section 3.5) 1A, 1B, 2 Carcinogenicity (Section 3.6) 1A, 1B, 2 Reproductive toxicity (Section 3.7) 1A, 1B, 2 Specific target organ toxicity — single exposure (Section 3.8) 1, 2 Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) 3 Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) 3 Specific target organ toxicity — repeated exposure (Section 3.9) 1, 2 Aspiration hazard (Section 3.10) 1 Hazardous to the aquatic environment — acute aquatic hazard (Section 4.1) 1 Hazardous to the aquatic environment — chronic aquatic hazard (Section 4.1) 1, 2, 3, 4 P502 Refer to manufacturer or supplier for information on recovery or recycling Hazardous to the ozone layer (Section 5.1) 1 2. Part 2: precautionary statements The precautionary statements shall be taken from this part of Annex IV and selected in accordance with Part 1. Table 1.1 Precautionary statements — General … 167 unchanged lines … SL Ne pršiti proti odprtemu ognju ali drugemu viru vžiga. FI Ei saa suihkuttaa avotuleen tai muuhun sytytyslähteeseen. SV Spreja inte över öppen låga eller andra antändningskällor. P220 Language BG Да се държи/съхранява далеч от облекло/…/горими материали ES Mantener o almacenar alejado de la ropa/…/materiales combustibles. CS Uchovávejte/skladujte odděleně od oděvů/…/hořlavých materiálů. DA Må ikke anvendes/opbevares i nærheden af tøj/…/brændbare materialer. DE Von Kleidung/…/brennbaren Materialien fernhalten/entfernt aufbewahren. ET Hoida eemal rõivastest/…/süttivast materjalist. EL Διατηρείται/Φυλάσσεται μακριά από ενδύματα/…/καύσιμα υλικά. EN Keep/Store away from clothing/…/combustible materials. FR Tenir/stocker à l’écart des vêtements/…/matières combustibles GA Coimeád/Stóráil glan ar éadaí/…/ábhair indóite. HR Čuvati/skladištiti odvojeno od odjeće/…/zapaljivih materijala. IT Tenere/conservare lontano da indumenti/…/materiali combustibili. LV Turēt/uzglabāt vietās, kur nav piekļuves drēbēm/…/uzliesmojošiem materiāliem. LT Laikyti/sandėliuoti atokiau nuo drabužių/…/degių medžiagų. HU Ruhától/…/éghető anyagtól távol tartandó/tárolandó. MT Żomm/Aħżen ‘il bogħod mill-ħwejjeġ/…/materjali li jaqbdu. NL Van kleding/…/brandbare stoffen verwijderd houden/bewaren. PL Trzymać/przechowywać z dala od odzieży/…/materiałów zapalnych. PT Manter/guardar afastado de roupa/…/matérias combustíveis. RO A se păstra/depozita departe de îmbrăcăminte/…/materiale combustibile. SK Uchovávajte/skladujte mimo odevov/…/horľavých materiálov. SL Hraniti ločeno od oblačil/…/vnetljivih materialov. FI Pidä/Varastoi erillään vaatetuksesta/…/syttyvistä materiaaleista. SV Hålls/förvarad åtskilt från kläder/…/brännbara material. P220 Language BG Да се държи далеч от облекло и други горими материали. ES Mantener alejado de la ropa y otros materiales combustibles. CS Uchovávejte odděleně od oděvů a jiných hořlavých materiálů. DA Holdes væk fra beklædningsgenstande og andre brændbare materialer. DE Von Kleidung und anderen brennbaren Materialien fernhalten. ET Hoida eemal rõivastest ja muust süttivast materjalist. EL Να φυλάσσεται μακριά από ενδύματα και άλλα καύσιμα υλικά. EN Keep away from clothing and other combustible materials. FR Tenir à l'écart des vêtements et d'autres matières combustibles. GA Coimeád glan ar éadaí agus ar ábhair indóite eile. HR Čuvati odvojeno od odjeće i drugih zapaljivih materijala. IT Tenere lontano da indumenti e altri materiali combustibili. LV Nepieļaut saskari ar apģērbu un citiem uzliesmojošiem materiāliem. LT Laikyti atokiau nuo drabužių bei kitų degiųjų medžiagų. HU Ruhától és más éghető anyagoktól távol tartandó. MT Żomm 'il bogħod mill-ħwejjeġ u materjali oħra li jaqbdu. NL Verwijderd houden van kleding en andere brandbare materialen. PL Trzymać z dala od odzieży i innych materiałów zapalnych. PT Manter afastado da roupa e de outras matérias combustíveis. RO A se păstra departe de îmbrăcăminte și de alte materiale combustibile. SK Uchovávajte mimo odevov a iných horľavých materiálov. SL Hraniti ločeno od oblačil in drugih vnetljivih materialov. FI Pidä erillään vaatetuksesta ja muista syttyvistä materiaaleista. SV Hålls åtskilt från kläder och andra brännbara material. P221 Language BG Вземете всички предпазни мерки за избягване на смесването с горими материали… ES Tomar todas las precauciones necesarias para no mezclar con materias combustibles… CS Proveďte preventivní opatření proti smíchání s hořlavými materiály… … 90 unchanged lines … SL Hraniti prepojeno z … FI Säilytä kostutettuna … SV Ska hållas fuktigt med… P231 Language BG Да се използва под инертен газ. ES Manipular en gas inerte. CS Manipulace pod inertním plynem. DA Håndteres under inaktiv gas. DE Unter inertem Gas handhaben. ET Käidelda inertgaasis. EL Χειρισμός σε αδρανή ατμόσφαιρα. EN Handle under inert gas. FR Manipuler sous gaz inerte. GA Láimhsigh faoi thriathghás. HR Rukovati u inertnom plinu. IT Manipolare in atmosfera di gas inerte. LV Rīkoties tikai inertas gāzes apstākļos. LT Tvarkyti inertinėse dujose. HU Inert gázban használandó. MT Immaniġġja taħt gass inerti. NL Onder inert gas werken. PL Używać w atmosferze obojętnego gazu. PT Manusear em atmosfera de gás inerte. RO A se manipula sub un gaz inert. SK Manipulujte v prostredí s inertným plynom. SL Hraniti v ustreznem inertnem plinu. FI Käsittele inertissä kaasussa. SV Hanteras under inert gas. P231 Language BG Да се използва и съхранява съдържанието под инертен газ/… ES Manipular y almacenar el contenido en un medio de gas inerte /… CS Manipulace a skladování pod inertním plynem /… DA Håndteres og opbevares under inert gas/… DE Inhalt unter inertem Gas/… handhaben und aufbewahren. ET Sisu käidelda ja hoida inertgaasis/… EL Ο χειρισμός και η αποθήκευση του υλικού να γίνεται υπό αδρανές αέριο/ … EN Handle and store contents under inert gas/… FR Manipuler et stocker le contenu sous gaz inerte/… GA Láimhsigh agus stóráil an t-ábhar faoi thriathghás/… HR Rukovati i skladištiti u inertnom plinu /… IT Manipolare e conservare in atmosfera di gas inerte/… LV Saturu izmantot un glabāt tikai inertas gāzes vidē/… LT Turinį tvarkyti ir laikyti inertinėse dujose/… HU Tartalma inert gázban /… használandó és tárolandó. MT Uża u aħżen il-kontenut taħt gass inerti /… NL Inhoud onder inert gas/… gebruiken en bewaren. PL Używać i przechowywać zawartość w atmosferze obojętnego gazu /… PT Manusear e armazenar o conteúdo em atmosfera de gás inerte/… RO A se manipula și a se depozita conținutul sub un gaz inert/… SK Manipulujte s obsahom a skladujte ho v prostredí s inertným plynom/… SL Ravnati z vsebino in jo hraniti v inertnem plinu/… FI Käsittele ja varastoi sisältö inertissä kaasussa/… SV Hantera och förvara innehållet under inert gas/… P232 Language BG Да се пази от влага. ES Proteger de la humedad. CS Chraňte před vlhkem. … 43 unchanged lines … FI Säilytä tiiviisti suljettuna. SV Behållaren ska vara väl tillsluten. P234 Language BG Да се съхранява само в оригиналната опаковка. ES Conservar únicamente en el recipiente original. CS Uchovávejte pouze v původním obalu. DA Opbevares kun i den originale beholder. DE Nur im Originalbehälter aufbewahren. ES Conservar únicamente en el embalaje original. CS Uchovávejte pouze v původním balení. DA Opbevares kun i originalemballagen. DE Nur in Originalverpackung aufbewahren. ET Hoida üksnes originaalpakendis. EL Να διατηρείται μόνο στον αρχικό περιέκτη. EN Keep only in original container. FR Conserver uniquement dans le récipient d’origine. GA Coimeád sa choimeádán bunaidh amháin. HR Čuvati samo u originalnom spremniku. IT Conservare soltanto nel contenitore originale. LV Turēt tikai oriģinālā iepakojumā. LT Laikyti tik originalioje talpykloje. HU Az eredeti edényben tartandó. MT Żomm biss fil-kontenitur oriġinali. EL Να διατηρείται μόνο στην αρχική συσκευασία. EN Keep only in original packaging. FR Conserver uniquement dans l'emballage d'origine. GA Coimeád sa phacáistiú bunaidh amháin. HR Čuvati samo u originalnom pakiranju. IT Conservare soltanto nell'imballaggio originale. LV Turēt tikai oriģināliepakojumā. LT Laikyti tik originalioje pakuotėje. HU Az eredeti csomagolásban tartandó. MT Żomm biss fl-imballaġġ oriġinali. NL Uitsluitend in de oorspronkelijke verpakking bewaren. PL Przechowywać wyłącznie w oryginalnym pojemniku. PT Conservar unicamente no recipiente de origem. RO Păstrați numai în recipientul original. SK Uchovávajte iba v pôvodnej nádobe. SL Hraniti samo v originalni posodi. PL Przechowywać wyłącznie w oryginalnym opakowaniu. PT Mantenha sempre o produto na sua embalagem original. RO A se păstra numai în ambalajul original. SK Uchovávajte iba v pôvodnom balení. SL Hraniti samo v originalni embalaži. FI Säilytä alkuperäispakkauksessa. SV Förvaras endast i originalbehållaren. SV Förvaras endast i originalförpackningen. P235 Language BG Да се държи на хладно. ES Mantener en lugar fresco. CS Uchovávejte v chladu. … 18 unchanged lines … SL Hraniti na hladnem. FI Säilytä viileässä. SV Förvaras svalt. P240 Language BG Заземяване/еквипотенциална връзка на съда и приемателното устройство. ES Conectar a tierra/enlace equipotencial del recipiente y del equipo de recepción. CS Uzemněte obal a odběrové zařízení. P240 Language BG Заземяване и еквипотенциална връзка на съда и приемателното устройство. ES Toma de tierra y enlace equipotencial del recipiente y del equipo receptor. CS Uzemněte a upevněte obal a odběrové zařízení. DA Beholder og modtageudstyr jordforbindes/potentialudlignes. DE Behälter und zu befüllende Anlage erden. ET Mahuti ja vastuvõtuseade maandada/ühendada. EL Γείωση/ισοδυναμική σύνδεση του περιέκτη και του εξοπλισμού δέκτη. EN Ground/bond container and receiving equipment. FR Mise à la terre/liaison équipotentielle du récipient et du matériel de réception. ET Mahuti ja vastuvõtuseade maandada ja ühendada. EL Γείωση και ισοδυναμική σύνδεση του περιέκτη και του εξοπλισμού του δέκτη. EN Ground and bond container and receiving equipment. FR Mise à la terre et liaison équipotentielle du récipient et du matériel de réception. GA Nasc an coimeádán agus an trealamh glactha leis an talamh. HR Uzemljiti/učvrstiti spremnik i opremu za prihvat kemikalije. IT Mettere a terra/massa il contenitore e il dispositivo ricevente. LV Tvertnes un iekārtas saņemšanai ievietot zemē/sasaistīt LT Įžeminti/įtvirtinti talpyklą ir priėmimo įrangą. HU A tárolóedényt és a fogadóedényt le kell földelni/át kell kötni. MT Poġġi ma' l-art/waħħal il-kontenitur u t-tagħmir li jirċievi. HR Uzemljiti i učvrstiti spremnik i opremu za prihvat kemikalije. IT Mettere a terra e a massa il contenitore e il dispositivo ricevente. LV Tvertnes un saņēmējiekārtas iezemēt un savienot. LT Įžeminti ir įtvirtinti talpyklą ir priėmimo įrangą. HU A tárolóedényt és a fogadóedényt le kell földelni és át kell kötni. MT Poġġi mal-art u waħħal il-kontenitur u t-tagħmir riċevitur. NL Opslag- en opvangreservoir aarden. PL Uziemić/połączyć pojemnik i sprzęt odbiorczy. PT Ligação à terra/equipotencial do recipiente e do equipamento receptor. RO Legătură la pământ/conexiune echipotențială cu recipientul și cu echipamentul de recepție. SK Uzemnite/upevnite nádobu a plniace zariadenie. SL Ozemljiti posodo in opremo za sprejem tekočine. FI Säiliö ja vastaanottavat laitteet on maadoitettava/yhdistettävä. SV Jorda/potentialförbind behållare och mottagarutrustning. P241 Language BG Използвайте електрическо/проветряващо/осветително/…/оборудване, обезопасено срещу експлозия ES Utilizar un material eléctrico, de ventilación o de iluminación/…/antideflagrante. CS Používejte elektrické/ventilační/osvětlovací/…/zařízení do výbušného prostředí. DA Anvend eksplosionssikkert elektrisk/ventilations-/lys-/…/udstyr. DE Explosionsgeschützte elektrische Geräte/Lüftungsanlagen/Beleuchtungsanlagen/… verwenden. ET Kasutada plahvatuskindlaid elektri-/ventilatsiooni-/valgustus-/…/seadmeid. EL Να χρησιμοποιείται αντιεκρηκτικός ηλεκτρολογικός/εξαερισμού/φωτιστικός/…/εξοπλισμός. EN Use explosion-proof electrical/ventilating/lighting/…/equipment. FR Utiliser du matériel électrique/de ventilation/d’éclairage/…/antidéflagrant. GA Bain úsáid as trealamh pléascdhíonach leictreach/aerála/soilsiúcháin/… HR Rabiti električnu/ventilacijsku/rasvjetnu/…/opremu koja neće izazvati eksploziju. IT Utilizzare impianti elettrici/di ventilazione/d’illuminazione/…/a prova di esplosione. LV Izmantot sprādziendrošas elektriskas/ar ventilāciju/izgaismotas/…/iekārtas LT Naudoti sprogimui atsparią elektros/ventiliacijos/apšvietimo/…/įrangą. HU Robbanásbiztos elektromos/szellőztető/világító/…/berendezés használandó. MT Uża’ tagħmir elettriku/ta’ ventilazzjoni/ta' dawl/…/li jiflaħ għal splużjoni. NL Explosieveilige elektrische/ventilatie-/verlichtings-/…apparatuur gebruiken. PL Używać elektrycznego/wentylującego/oświetleniowego/…/. przeciwwybuchowego sprzętu. PT Utilizar equipamento eléctrico/de ventilação/de iluminação/…/à prova de explosão. RO Utilizați echipamente electrice/de ventilare/de iluminat/…/antideflagrante. SK Používajte elektrické/ventilačné/osvetľovacie/…/zariadenie do výbušného prostredia. SL Uporabiti električno/prezračevalno opremo, opremo za razsvetljavo/…/, odporno proti eksplozijam. FI Käytä räjähdysturvallisia sähkö/ilmanvaihto/valaisin/…/laitteita. SV Använd explosionssäker elektrisk/ventilations-/belysnings-/…/utrustning. P242 Language BG Използвайте само инструменти, които не предизвикват искри. ES Utilizar únicamente herramientas que no produzcan chispas. CS Používejte pouze nářadí z nejiskřícího kovu. DA Anvend kun værktøj, som ikke frembringer gnister. DE Nur funkenfreies Werkzeug verwenden. PL Uziemić i połączyć pojemnik i sprzęt odbiorczy. PT Ligação à terra/equipotencial do recipiente e do equipamento recetor. RO Legătură la pământ și conexiune echipotențială cu recipientul și cu echipamentul de recepție. SK Uzemnite a upevnite nádobu a plniace zariadenie. SL Ozemljiti posodo in opremo za sprejem tekočine ter izenačiti potenciale. FI Maadoita ja yhdistä säiliö ja vastaanottavat laitteet. SV Jorda och potentialförbind behållare och mottagarutrustning. P241 Language BG Използвайте [електрическо/вентилационно/осветително/…] оборудване, обезопасено срещу експлозия. ES Utilizar material [eléctrico / de ventilación/iluminación / …] antideflagrante. CS Používejte [elektrické/ventilační/osvětlovací/…] zařízení do výbušného prostředí. DA Anvend eksplosionssikkert [elektrisk/ventilations-/lys-/…] udstyr. DE Explosionsgeschützte [elektrische/Lüftungs-/Beleuchtungs-/…] Geräte verwenden. ET Kasutada plahvatuskindlaid [elektri-/ventilatsiooni-/valgustus-/…] seadmeid. EL Να χρησιμοποιείται αντιεκρηκτικός εξοπλισμός [ηλεκτρολογικός /εξαερισμού/φωτιστικός/…]. EN Use explosion-proof [electrical/ventilating/lighting/…] equipment. FR Utiliser du matériel [électrique/de ventilation/d'éclairage/…] antidéflagrant. GA Bain úsáid as trealamh pléascdhíonach [leictreach/ aerála/soilsiúcháin/…]. HR Rabiti [električnu/ventilacijsku/rasvjetnu/…] opremu koja neće izazvati eksploziju. IT Utilizzare impianti [elettrici/di ventilazione/d'illuminazione/…] a prova di esplosione. LV Izmantot sprādziendrošas [elektriskās/ventilācijas/apgaismošanas/…] iekārtas. LT Naudoti sprogimui atsparią [elektros/ventiliacijos/apšvietimo/…] įrangą. HU Robbanásbiztos [elektromos/szellőztető/világító/…] berendezés használandó. MT Uża' tagħmir [elettriku / ta' ventilazzjoni / ta' dawl/…] li jiflaħ għal splużjoni. NL Explosieveilige [elektrische/ventilatie-/verlichtings-/…]apparatuur gebruiken. PL Używać [elektrycznego/wentylującego/oświetleniowego/…/] przeciwwybuchowego sprzętu. PT Utilizar equipamento [elétrico/de ventilação/de iluminação/…] à prova de explosão. RO Utilizați echipamente [electrice/de ventilare/de iluminat/…] antideflagrante. SK Používajte [elektrické/ventilačné/osvetľovacie/…] zariadenie do výbušného prostredia. SL Uporabiti [električno opremo/prezračevalno opremo/ opremo za razsvetljavo/…], odporno proti eksplozijam. FI Käytä räjähdysturvallisia [sähkö/ilmanvaihto/valaisin/…]laitteita. SV Använd explosionssäker [elektrisk/ventilations-/belysnings-/…]utrustning. P242 Language BG Използвайте инструменти, които не предизвикват искри. ES No utilizar herramientas que produzcan chispas. CS Používejte nářadí z nejiskřícího kovu. DA Anvend værktøj, som ikke frembringer gnister. DE Funkenarmes Werkzeug verwenden. ET Mitte kasutada seadmeid, mis võivad tekitada sädemeid. EL Να χρησιμοποιούνται μόνο εργαλεία που δεν παράγουν σπινθήρες. EN Use only non-sparking tools. FR Ne pas utiliser d'outils produisant des étincelles. GA Bain úsáid as uirlisí neamhspréachta amháin. HR Rabiti samo neiskreći alat. IT Utilizzare solo utensili antiscintillamento. EL Να χρησιμοποιούνται μη σπινθηρογόνα εργαλεία. EN Use non-sparking tools. FR Utiliser des outils ne produisant pas d'étincelles. GA Bain úsáid as uirlisí neamhspréachta. HR Rabiti neiskreći alat. IT Utilizzare utensili antiscintillamento. LV Izmantot instrumentus, kas nerada dzirksteles. LT Naudoti tik kibirkščių nekeliančius įrankius. LT Naudoti kibirkščių nekeliančius įrankius. HU Szikramentes eszközök használandók. MT Uża’ biss għodda li ma jtajrux żnied. NL Uitsluitend vonkvrij gereedschap gebruiken. PL Używać wyłącznie nieiskrzących narzędzi. PT Utilizar apenas ferramentas antichispa. MT Uża għodda li ma ttajjarx żnied. NL Vonkvrij gereedschap gebruiken. PL Używać nieiskrzących narzędzi. PT Utilizar ferramentas antichispa. RO Nu utilizați unelte care produc scântei. SK Používajte iba neiskriace prístroje. SL Uporabiti le orodje, ki ne povzroča isker. FI Käytä ainoastaan kipinöimättömiä työkaluja. SV Använd endast verktyg som inte ger upphov till gnistor. P243 Language BG Вземете предпазни мерки срещу освобождаване на статично електричество. ES Tomar medidas de precaución contra descargas electrostáticas. CS Proveďte preventivní opatření proti výbojům statické elektřiny. SK Používajte neiskriace prístroje. SL Uporabiti orodje, ki ne povzroča isker. FI Käytä kipinöimättömiä työkaluja. SV Använd verktyg som inte ger upphov till gnistor. P243 Language BG Предприемете действия за предотвратяване на освобождаването на статично електричество. ES Tomar medidas de precaución contra las descargas electrostáticas. CS Proveďte opatření proti výbojům statické elektřiny. DA Træf foranstaltninger mod statisk elektricitet. DE Maßnahmen gegen elektrostatische Entladungen treffen. ET Rakendada ettevaatusabinõusid staatilise elektri vastu. EL Λάβετε προστατευτικά μέτρα έναντι ηλεκτροστατικών εκκενώσεων. EN Take precautionary measures against static discharge. ET Rakendada abinõusid staatilise elektri vältimiseks. EL Λάβετε μέτρα για την αποτροπή ηλεκτροστατικών εκκενώσεων. EN Take action to prevent static discharges. FR Prendre des mesures de précaution contre les décharges électrostatiques. GA Déan bearta réamhchúraim in aghaidh díluchtú statach. HR Poduzeti mjere protiv pojave statičkog elektriciteta. IT Prendere precauzioni contro le scariche elettrostatiche. GA Déan bearta in aghaidh díluchtú statach. HR Poduzeti mjere za sprečavanje statičkog elektriciteta. IT Fare in modo di prevenire le scariche elettrostatiche. LV Nodrošināties pret statiskās enerģijas izlādi. LT Imtis atsargumo priemonių statinei iškrovai išvengti. LT Imtis veiksmų statinei iškrovai išvengti. HU Az elektrosztatikus kisülés megakadályozására óvintézkedéseket kell tenni. MT Ħu miżuri ta' prekawzjoni kontra l-ħruġ ta' elettriku statiku. NL Voorzorgsmaatregelen treffen tegen ontladingen van statische elektriciteit. PL Przedsięwziąć środki ostrożności zapobiegające statycznemu rozładowaniu. PT Evitar acumulação de cargas electrostáticas. MT Ħu azzjoni biex tipprevjeni l-ħruġ ta' elettriku statiku. NL Maatregelen treffen om ontladingen van statische elektriciteit te voorkomen. PL Podjąć działania zapobiegające wyładowaniom elektrostatycznym. PT Tomar medidas para evitar acumulação de cargas eletrostáticas. RO Luați măsuri de precauție împotriva descărcărilor electrostatice. SK Urobte preventívne opatrenia proti výbojom statickej elektriny. SL Preprečiti statično naelektrenje. SK Vykonajte opatrenia na zabránenie výbojom statickej elektriny. SL Ukrepati za preprečitev statičnega naelektrenja. FI Estä staattisen sähkön aiheuttama kipinöinti. SV Vidta åtgärder mot statisk elektricitet. P244 Language BG Поддържайте вентилите и фитингите чисти от масло и смазка. … 20 unchanged lines … SL Preprečiti stik ventilov in opreme z oljem in mastjo. FI Pidä venttiilit ja liittimet vapaana öljystä ja rasvasta. SV Håll ventiler och anslutningar fria från olja och fett. P250 Language BG Да не се подлага на стържене/удар/…/триене ES Evitar la abrasión/el choque/…/la fricción. CS Nevystavujte obrušování/nárazům/…/tření. DA Må ikke udsættes for slibning/stød/…/gnidning. DE Nicht schleifen/stoßen/…/reiben. ET Hoida kriimustamise/põrutuse/…/hõõrdumise eest. EL Να αποφεύγεται άλεση/κρούση/…/τριβή. EN Do not subject to grinding/shock/…/friction. FR Éviter les abrasions/les chocs/…/les frottements. GA Ná nocht do mheilt/do thurraing/…/do fhrithchuimilt. HR Ne izlagati mrvljenju/udarcima/…/trenju. IT Evitare le abrasioni/gli urti/…/gli attriti. LV Nepakļaut drupināšanai/triecienam/…/berzei P250 Language BG Да не се подлага на стържене/удар/триене… ES Evitar abrasiones/choques/fricciones/… . CS Nevystavujte obrušování/nárazům/tření/… . DA Må ikke udsættes for slibning/stød/gnidning/…. DE Nicht schleifen/stoßen/reiben/… . ET Hoida kriimustamise/põrutuse/hõõrdumise/… eest. EL Να αποφεύγεται άλεση/κρούση/τριβή/… . EN Do not subject to grinding/shock/friction/… . FR Éviter les abrasions/les chocs/les frottements/… . GA Ná nocht do mheilt/do thurraing/do fhrithchuimilt/… . HR Ne izlagati mrvljenju/udarcima/trenju/… IT Evitare le abrasioni/gli urti/gli attriti/… . LV Nepakļaut drupināšanai/triecienam/berzei/… . LT Nešlifuoti/netrankyti/…/netrinti. HU Tilos csiszolásnak/ütésnek/…/súrlódásnak kitenni. MT Tissottoponihomx għal brix/xokk/…/frizzjoni. NL Malen/schokken/…/wrijving vermijden. PL Nie poddawać szlifowaniu/wstrząsom/…/tarciu. PT Não submeter a trituração/choque/…/fricção. RO A nu supune la abraziuni/șocuri/…/frecare. SK Nevystavujte brúseniu/nárazu/…/treniu. SL Ne izpostavljati drgnjenju/udarcem/…/trenju. FI Suojele rasitukselta/iskuilta/…/hankaukselta. SV Får inte utsättas för gnidning/stötar/…/friktion. HU Tilos csiszolásnak/ütésnek/súrlódásnak/… kitenni. MT Tissottoponix għal brix / xokk / frizzjoni /… . NL Malen/schokken/wrijving/… vermijden. PL Nie poddawać szlifowaniu/wstrząsom/tarciu/…. PT Não submeter a trituração/choque/fricção/… . RO A nu se supune la abraziuni/șocuri/frecare/… . SK Nevystavujte brúseniu/nárazu/treniu/… . SL Ne izpostavljati drgnjenju/udarcem/trenju/… . FI Suojele rasitukselta/iskuilta/hankaukselta/…. SV Får inte utsättas för malning/stötar/friktion/… . P251 Language BG Да не се пробива и изгаря дори след употреба. ES No perforar ni quemar, incluso después de su uso. CS Nepropichujte nebo nespalujte ani po použití. … 90 unchanged lines … SL Preprečiti stik z očmi, kožo ali oblačili. FI Varo kemikaalin joutumista silmiin, iholle tai vaatteisiin. SV Får inte komma i kontakt med ögonen, huden eller kläderna. P263 Language BG Да се избягва контакт по време на бременност/при кърмене. ES Evitar el contacto durante el embarazo/la lactancia. CS Zabraňte styku během těhotenství/kojení. P263 Language BG Да се избягва контакт по време на бременност и при кърмене. ES Evitar todo contacto con la sustancia durante el embarazo y la lactancia. CS Zabraňte styku během těhotenství a kojení. DA Undgå kontakt under graviditet/amning. DE Kontakt während der Schwangerschaft/und der Stillzeit vermeiden. ET Vältida kokkupuudet raseduse/imetamise ajal. EL Aποφεύγετε την επαφή στη διάρκεια της εγκυμοσύνης/γαλουχίας. EN Avoid contact during pregnancy/while nursing. FR Éviter tout contact avec la substance au cours de la grossesse/pendant l’allaitement. GA Seachain teagmháil le linn toirchis/agus an chíoch á tabhairt. HR Izbjegavati dodir tijekom trudnoće/dojenja. IT Evitare il contatto durante la gravidanza/l’allattamento. LV Izvairīties no saskares grūtniecības laikā/barojot bērnu ar krūti. DE Berührung während Schwangerschaft und Stillzeit vermeiden. ET Vältida kokkupuudet raseduse ja imetamise ajal. EL Αποφεύγετε την επαφή στη διάρκεια της εγκυμοσύνης και της γαλουχίας. EN Avoid contact during pregnancy and while nursing. FR Éviter tout contact avec la substance au cours de la grossesse et pendant l'allaitement. GA Seachain teagmháil le linn toirchis agus fad agus atá an chíoch á tabhairt. HR Izbjegavati dodir tijekom trudnoće i dojenja. IT Evitare il contatto durante la gravidanza e l'allattamento. LV Izvairīties no saskares grūtniecības laikā un barojot bērnu ar krūti. LT Vengti kontakto nėštumo metu/maitinant krūtimi. HU A terhesség/szoptatás alatt kerülni kell az anyaggal való érintkezést. MT Evita l-kuntatt waqt it-tqala/waqt it-treddigħ. HU Terhesség és szoptatás alatt kerülni kell az anyaggal való érintkezést. MT Evita l-kuntatt waqt it-tqala u t-treddigħ. NL Bij zwangerschap of borstvoeding aanraking vermijden. PL Unikać kontaktu w czasie ciąży/karmienia piersią. PT Evitar o contacto durante a gravidez/o aleitamento. RO Evitați contactul în timpul sarcinii/alăptării. SK Zabráňte kontaktu počas tehotenstva a dojčenia. SL Preprečiti stik med nosečnostjo/dojenjem. FI Vältä kosketusta raskauden tai imetyksen aikana. SV Undvik kontakt under graviditet eller amning. PL Unikać kontaktu w czasie ciąży i podczas karmienia piersią. PT Evitar o contacto durante a gravidez e o aleitamento. RO Evitați contactul în timpul sarcinii și alăptării. SK Zabráňte kontaktu počas tehotenstva a dojčenia. SL Preprečiti stik med nosečnostjo in dojenjem. FI Vältä kosketusta raskauden ja imetyksen aikana. SV Undvik kontakt under graviditet och amning. P264 Language BG Да се измие… старателно след употреба. ES Lavarse … concienzudamente tras la manipulación. CS Po manipulaci důkladně omyjte … … 162 unchanged lines … SL Uporabiti predpisano osebno zaščitno opremo. FI Käytä vaadittuja henkilönsuojaimia. SV Använd föreskriven personlig skyddsutrustning. P282 Language BG Носете предпазващи от студ ръкавици/маска за лице/защитни очила. ES Llevar guantes que aíslen del frío/gafas/máscara. CS Používejte ochranné rukavice proti chladu/obličejový štít/ochranné brýle. DA Bær kuldeisolerende handsker/ansigtsskærm/øjenbeskyttelse. DE Schutzhandschuhe mit Kälteisolierung/Gesichtsschild/Augenschutz tragen. ET Kanda külmakaitsekindaid/kaitsemaski/kaitseprille. EL Φοράτε μονωτικά γάντια προστασίας από το ψύχος/προστατευτική μάσκα/προστατευτικά γυαλιά. EN Wear cold insulating gloves/face shield/eye protection. FR Porter des gants isolants contre le froid/un équipement de protection du visage/des yeux. GA Caith lámhainní inslithe fuachta/aghaidhsciath/cosaint súile. HR Nositi zaštitne rukavice za hladnoću/zaštitu za lice/zaštitu za oči. IT Utilizzare guanti termici/schermo facciale/Proteggere gli occhi. LV Izmantot aizsargcimdus/sejas aizsargus/acu aizsargus ar aukstuma izolāciju. LT Mūvėti nuo šalčio izoliuojančias pirštines/naudoti veido skydelį/akių apsaugos priemones. HU Hidegszigetelő kesztyű/arcvédő/szemvédő használata kötelező. MT Ilbies ingwanti kiesħa li ma jinfedx minnhom/ilqugħ għall-wiċċ/protezzjoni għall-għajnejn. NL Gelaatsbescherming/oogbescherming/koude-isolerende handschoenen dragen. PL Nosić rękawice izolujące od zimna/maski na twarz/ochronę oczu. PT Usar luvas de protecção contra o frio/escudo facial/protecção ocular. RO Purtați mănuși izolante împotriva frigului/echipament de protecție a feței/ochilor. SK Používajte termostabilné rukavice/ochranný štít/ochranné okuliare. SL Nositi hladne izolirne rokavice/zaščito za obraz/zaščito za oči. FI Käytä kylmäeristäviä suojakäsineitä/kasvonsuojainta/silmiensuojainta. SV Använd köldisolerande handskar/visir/ögonskydd. P283 Language BG Носете огнеупорно/огнезащитно облекло. ES Llevar prendas ignífugas/resistentes al fuego/resistentes a las llamas. CS Používejte ohnivzdorný/nehořlavý oděv. DA Bær brandbestandig/brandhæmmende beklædning. DE Schwer entflammbare/flammhemmende Kleidung tragen. ET Kanda tule-/leegikindlat/tule levikut aeglustavat rõivastust. EL Φοράτε αντιπυρικά/αλεξίφλογα πυράντοχα/βραδυφλεγή ενδύματα. EN Wear fire/flame resistant/retardant clothing. FR Porter des vêtements résistant au feu/aux flammes/ignifuges. GA Caith éadaí dódhíonacha/lasairdhíonacha nó dómhoillitheacha/lasairmhoillitheacha. HR Nositi otpornu na vatru/nezapaljivu odjeću. P282 Language BG Носете предпазващи от студ ръкавици, както и маска за лице или защитни очила. ES Usar guantes aislantes contra el frío y equipo de protección para la cara o los ojos. CS Používejte ochranné rukavice proti chladu a buď obličejový štít, nebo ochranné brýle. DA Bær kuldeisolerende handsker og enten ansigtsskærm eller øjenbeskyttelse. DE Schutzhandschuhe mit Kälteisolierung und zusätzlich Gesichtsschild oder Augenschutz tragen. ET Kanda külmakaitsekindaid ning kaitsemaski või kaitseprille. EL Να φοράτε μονωτικά γάντια και προστατευτικό κάλυμμα προσώπου ή εξοπλισμό προστασίας ματιών. EN Wear cold insulating gloves and either face shield or eye protection. FR Porter des gants isolants contre le froid et un équipement de protection du visage ou des yeux. GA Caith lámhainní inslithe fuachta agus aghaidhsciath nó cosaint súile. HR Nositi zaštitne rukavice za hladnoću i zaštitu za lice ili zaštitu za oči. IT Utilizzare guanti termici e schermo facciale o protezione per gli occhi. LV Izmantot aukstumizolējošus aizsargcimdus un sejas vai acu aizsargu. LT Mūvėti nuo šalčio izoliuojančias pirštines ir naudoti veido skydelį arba akių apsaugos priemones. HU Hidegszigetelő kesztyű és arcvédő vagy szemvédő használata kötelező. MT Ilbes ingwanti kiesħa li ma jinfidx minnhom u jew ilqugħ għall-wiċċ jew protezzjoni għall-għajnejn. NL Koude-isolerende handschoenen en hetzij gelaatsbescherming hetzij oogbescherming dragen. PL Nosić rękawice izolujące od zimna oraz albo maski na twarz albo ochronę oczu. PT Usar luvas de proteção contra o frio e escudo facial ou proteção ocular. RO Purtați mănuși izolante împotriva frigului și echipament de protecție a feței sau a ochilor. SK Používajte termostabilné rukavice a buď ochranný štít alebo ochranné okuliare. SL Nositi izolirne rokavice za zaščito pred mrazom in zaščito za obraz oziroma zaščito za oči. FI Käytä kylmäeristäviä suojakäsineitä ja joko kasvonsuojainta tai silmiensuojainta. SV Använd köldisolerande handskar och antingen visir eller ögonskydd. P283 Language BG Носете огнеупорно или огнезащитно облекло. ES Llevar ropa resistente al fuego o retardante de las llamas. CS Používejte ohnivzdorný oděv nebo oděv zpomalující hoření. DA Bær brandbestandig eller brandhæmmende beklædning. DE Schwer entflammbare oder flammhemmende Kleidung tragen. ET Kanda tulekindlat või tule levikut aeglustavat rõivastust. EL Να φοράτε αντιπυρικό ρουχισμό ή ρουχισμό με επιβραδυντικό φλόγας. EN Wear fire resistant or flame retardant clothing. FR Porter des vêtements résistant au feu ou à retard de flamme. GA Caith éadaí dódhíonacha nó lasairmhoillitheacha. HR Nositi odjeću otpornu na vatru ili nezapaljivu odjeću. IT Indossare indumenti completamente ignifughi o in tessuti ritardanti di fiamma. LV Izmantot aizsargapģērbu pret uguni/liesmām. LT Dėvėti ugniai/liepsnai atsparius/antipireninius drabužius. HU Tűz-/lángálló/-késleltető ruházat viselése kötelező. MT Ilbies ħwejjeġ reżistenti għan-nar/fjammi. NL Vuur/vlambestendige/brandwerende kleding dragen. PL Nosić odzież ognioodporną/płomienioodporną/opóźniającą zapalenie. PT Usar vestuário ignífugo/retardador de fogo/chamas. RO Purtați îmbrăcăminte rezistentă la foc/flacără/ignifugă. SK Noste ohňovzdorný odev/odev so zníženou horľavosťou. SL Nositi negorljiva oblačila in oblačila, odporna proti ognju. FI Käytä palosuojattua/paloturvallista vaatetusta. SV Använd brand-/flamsäkra eller brand-/flamhämmande kläder. LV Izmantot ugunsizturīgu vai liesmas aizturošu apģērbu. LT Dėvėti ugniai atsparius arba antipireninius drabužius. HU Tűzálló vagy lángkésleltető ruházat viselése kötelező. MT Ilbes ħwejjeġ reżistenti għan-nar u retardanti tal-fjammi. NL Vuurbestendige of vlamvertragende kleding dragen. PL Nosić odzież ognioodporną lub opóźniającą zapalenie. PT Usar vestuário ignífugo ou retardador de chamas. RO Purtați îmbrăcăminte rezistentă la foc sau ignifugă. SK Noste ohňovzdorný odev alebo odev so zníženou horľavosťou. SL Nositi negorljiva oblačila ali oblačila, odporna proti ognju. FI Käytä palosuojattua tai paloturvallista vaatetusta. SV Använd brandsäkra eller flamhämmande kläder. P284 Language BG [При недостатъчна вентилация] носете средства за защита на дихателните пътища. ES [En caso de ventilación insuficiente,] llevar equipo de protección respiratoria. CS [V případě nedostatečného větrání] používejte vybavení pro ochranu dýchacích cest. … 42 unchanged lines … SL Ob nezadostnem prezračevanju nositi opremo za zaščito dihal. FI Käytä hengityksensuojainta, jos ilmanvaihto on riittämätön. SV Använd andningsskydd vid otillräcklig ventilation. P231 + P232 Language BG Да се използва под инертен газ. Да се пази от влага. ES Manipular en gas inerte. Proteger de la humedad. CS Manipulace pod inertním plynem. Chraňte před vlhkem. DA Anvendes under inaktiv gas. Beskyttes mod fugt. DE Unter inertem Gas handhaben. Vor Feuchtigkeit schützen. ET Käidelda inertgaasis. Hoida niiskuse eest. EL Χειρισμός σε αδρανή ατμόσφαιρα. Προστατέψτε από την υγρασία. EN Handle under inert gas. Protect from moisture. FR Manipuler sous gaz inerte. Protéger de l’humidité. GA Láimhsigh faoi thriathghás. Cosain ó thaise. HR Rukovati u inertnom plinu. Zaštititi od vlage. IT Manipolare in atmosfera di gas inerte. Tenere al riparo dall’umidità. LV Izmantot tikai inertas gāzes apstākļos. Aizsargāt no mitruma. LT Tvarkyti inertinėse dujose. Saugoti nuo drėgmės. HU Inert gázban használandó. Nedvességtől védendő. MT Uża’ taħt gass inerti. Ipproteġi mill-umdità. NL Onder inert gas werken. Tegen vocht beschermen. PL Używać w atmosferze obojętnego gazu Chronić przed wilgocią. PT Manusear em atmosfera de gás inerte. Manter ao abrigo da humidade. RO A se manipula sub un gaz inert. A se proteja de umiditate. SK Manipulujte v prostredí s inertným plynom. Chráňte pred vlhkosťou. SL Hraniti v ustreznem inertnem plinu. Zaščititi pred vlago. FI Käsittele inertissä kaasussa. Suojaa kosteudelta. SV Hanteras under inert gas. Skyddas från fukt. P231 + P232 Language BG Да се използва и съхранява съдържанието под инертен газ/… Да се пази от влага. ES Manipular y almacenar el contenido en un medio de gas inerte/…. Proteger de la humedad. CS Manipulace a skladování pod inertním plynem /…. Chraňte před vlhkem. DA Håndteres og opbevares under inert gas/…. Beskyt mod fugt. DE Inhalt unter inertem Gas/… handhaben und aufbewahren. Vor Feuchtigkeit schützen. ET Sisu käidelda ja hoida inertgaasis/…. Hoida niiskuse eest. EL Ο χειρισμός και η αποθήκευση του υλικού να γίνεται υπό αδρανές αέριο/ …. Προστασία από την υγρασία. EN Handle and store contents under inert gas/…. Protect from moisture. FR Manipuler et stocker le contenu sous gaz inerte/… Protéger de l'humidité. GA Láimhsigh agus stóráil an t-ábhar faoi thriathghás/…. Cosain ó thaise. HR Rukovati i skladištiti u inertnom plinu / … Zaštititi od vlage. IT Manipolare e conservare in atmosfera di gas inerte/…. Tenere al riparo dall'umidità. LV Saturu izmantot un glabāt tikai inertas gāzes vidē/… Sargāt no mitruma. LT Turinį tvarkyti ir laikyti inertinėse dujose/…Saugoti nuo drėgmės. HU Tartalma inert gázban / … használandó és tárolandó. Nedvességtől védendő. MT Uża u aħżen il-kontenut taħt gass inerti /…. Ipproteġi mill-umdità. NL Inhoud onder inert gas/… gebruiken en bewaren. Tegen vocht beschermen. PL Używać i przechowywać zawartość w atmosferze obojętnego gazu /…. Chronić przed wilgocią. PT Manusear e armazenar o conteúdo em atmosfera de gás inerte/…. Manter ao abrigo da humidade. RO A se manipula și a se depozita conținutul sub un gaz inert/…. A se proteja de umiditate. SK Manipulujte s obsahom a skladujte ho v prostredí s inertným plynom/… Chráňte pred vlhkosťou. SL Ravnati z vsebino in jo hraniti v ustreznem inertnem plinu/…. Zaščititi pred vlago. FI Käsittele ja varastoi sisältö inertissä kaasussa /…. Suojaa kosteudelta. SV Hantera och förvara innehållet under inert gas/…. Skyddas från fukt. P235 + P410 Language BG Да се държи на хладно. Да се пази от пряка слънчева светлина. ES Conservar en un lugar fresco. Proteger de la luz del sol. CS Uchovávejte v chladu. Chraňte před slunečním zářením. … 284 unchanged lines … SL Pokličite CENTER ZA ZASTRUPITVE/zdravnika/… FI Ota yhteys MYRKYTYSTIETOKESKUKSEEN/lääkäriin/… SV Kontakta GIFTINFORMATIONSCENTRALEN/läkare/… P312 Language BG При неразположение се обадете в ЦЕНТЪР ПО ТОКСИКОЛОГИЯ/на лекар/…/. ES Llamar a un CENTRO DE TOXICOLOGĺA/médico/…/si la persona se encuentra mal. CS Necítíte-li se dobře, volejte TOXIKOLOGICKÉ INFORMAČNÍ STŘEDISKO/lékaře/… DA I tilfælde af ubehag, ring til en GIFTINFORMATION/læge/… DE Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/…/anrufen. ET Halva enesetunde korral võtta ühendust MÜRGISTUSTEABEKESKUSE/arstiga… EL Καλέστε το ΚΕΝΤΡΟ ΔΗΛΗΤΗΡΙΑΣΕΩΝ/γιατρό/…εάν αισθανθείτε αδιαθεσία. EN Call a POISON CENTER/doctor/…/if you feel unwell. FR Appeler un CENTRE ANTIPOISON/un médecin/…/en cas de malaise. GA Cuir glao ar IONAD NIMHE/ar dhoctúir/…mura mbraitheann tú go maith. HR U slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA/liječnika/… IT Contattare un CENTRO ANTIVELENI/un medico/…./in caso di malessere. LV Sazinieties ar SAINDĒŠANĀS INFORMĀCIJAS CENTRU/ārstu/.., ja jums ir slikta pašsajūta. LT Pasijutus blogai, skambinti į APSINUODIJIMŲ KONTROLĖS IR INFORMACIJOS BIURĄ/kreiptis į gydytoją/…. P312 Language BG При неразположение се обадете в ЦЕНТЪР ПО ТОКСИКОЛОГИЯ/на лекар/… ES Llamar a un CENTRO DE TOXICOLOGÍA / médico/… si la persona se encuentra mal. CS Necítíte-li se dobře, volejte TOXIKOLOGICKÉ INFORMAČNÍ STŘEDISKO / lékaře /… . DA Kontakt GIFTLINJEN/læge/… i tilfælde af ubehag. DE Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/… anrufen. ET Halva enesetunde korral võtta ühendust MÜRGISTUSTEABEKESKUSEGA/arstiga/…. EL Καλέστε το ΚΕΝΤΡΟ ΔΗΛΗΤΗΡΙΑΣΕΩΝ/γιατρό/…, αν αισθανθείτε αδιαθεσία. EN Call a POISON CENTRE/doctor/… if you feel unwell. FR Appeler un CENTRE ANTIPOISON/un médecin/… en cas de malaise. GA Cuir glao ar IONAD NIMHE/dochtúir/… má bhraitheann tú tinn. HR U slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA / liječnika / … IT In caso di malessere, contattare un CENTRO ANTIVELENI/un medico/… . LV Sazinieties ar SAINDĒŠANĀS INFORMĀCIJAS CENTRU/ārstu/…, ja jums ir slikta pašsajūta. LT Pasijutus blogai, skambinti į APSINUODIJIMŲ KONTROLĖS IR INFORMACIJOS BIURĄ / kreiptis į gydytoją / … HU Rosszullét esetén forduljon TOXIKOLÓGIAI KÖZPONTHOZ/orvoshoz/…. MT Sejjaħ ĊENTRU TAL-AVVELENAMENT/tabib/…/jekk ma tħossokx f’sikktek. MT Ikkuntattja ĊENTRU TAL-AVVELENAMENT / tabib / … jekk tħossok ma tiflaħx. NL Bij onwel voelen een ANTIGIFCENTRUM/arts/… raadplegen. PL W przypadku złego samopoczucia skontaktować się z OŚRODKIEM ZATRUĆ/lekarzem/… PT Caso sinta indisposição, contacte um CENTRO DE INFORMAÇÃO ANTIVENENOS/médico/… RO Sunați la un CENTRU DE INFORMARE TOXICOLOGICĂ/un medic/…/dacă nu vă simțiți bine. SK Pri zdravotných problémoch volajte TOXIKOLOGICKÉ INFORMAČNÉ CENTRUM/lekára/… SL Ob slabem počutju pokličite CENTER ZA ZASTRUPITVE/zdravnika/…/ FI Ota yhteys MYRKYTYSTIETOKESKUKSEEN/lääkäriin/…/jos ilmenee pahoinvointia. SV Vid obehag, kontakta GIFTINFORMATIONSCENTRALEN/läkare/… PL W przypadku złego samopoczucia skontaktować się z OŚRODKIEM ZATRUĆ/ lekarzem/…. PT Caso sinta indisposição, contacte um CENTRO DE INFORMAÇÃO ANTIVENENOS/médico/… . RO Sunați la un CENTRU DE INFORMARE TOXICOLOGICĂ/un medic/… dacă nu vă simțiți bine. SK Pri zdravotných problémoch volajte NÁRODNÉ TOXIKOLOGICKÉ INFORMAČNÉ CENTRUM/lekára/… . SL Ob slabem počutju pokličite CENTER ZA ZASTRUPITVE/ zdravnika/… . FI Ota yhteys MYRKYTYSTIETOKESKUKSEEN/lääkäriin/…, jos ilmenee pahoinvointia. SV Vid obehag, kontakta GIFTINFORMATIONSCENTRALEN/läkare… . P313 Language BG Потърсете медицински съвет/помощ. ES Consultar a un médico. CS Vyhledejte lékařskou pomoc/ošetření. … 234 unchanged lines … SL Če nastopi draženje kože ali se pojavi izpuščaj: FI Jos ilmenee ihoärsytystä tai ihottumaa: SV Vid hudirritation eller utslag: P334 Language BG Потопете в хладка вода/сложете мокри компреси. ES Sumergir en agua fresca/aplicar compresas húmedas. CS Ponořte do studené vody/zabalte do vlhkého obvazu. DA Skyl under koldt vand/anvend våde omslag. DE In kaltes Wasser tauchen/nassen Verband anlegen. ET Hoida jahedas vees/panna peale niiske kompress. EL Βυθίστε σε δροσερό νερό/τυλίξτε με βρεγμένους επιδέσμους. EN Immerse in cool water/wrap in wet bandages. FR Rincer à l’eau fraîche/poser une compresse humide. GA Tum in uisce fionnuar/cuir bréid fliuch air. HR Uroniti u hladnu vodu/omotati vlažnim zavojem. IT Immergere in acqua fredda/avvolgere con un bendaggio umido. LV Iegremdēt vēsā ūdenī/ietīt mitros apsējos. LT Įmerkti į vėsų vandenį/apvynioti šlapiais tvarsčiais. HU Hideg vízzel/nedves kötéssel kell hűteni. MT Daħħal fl-ilma kiesaħ/kebbeb f’faxex imxarrbin. NL In koud water onderdompelen/nat verband aanbrengen. PL Zanurzyć w zimnej wodzie/owinąć mokrym bandażem. PT Mergulhar em água fria/aplicar compressas húmidas. RO Introduceți în apă rece/acoperiți cu o compresă umedă. SK Ponorte do studenej vody/obviažte mokrými obväzmi. SL Potopiti v hladno vodo/zaviti v mokre povoje. FI Upota kylmään veteen/kääri märkiin siteisiin. SV Skölj under kallt vatten/använd våta omslag. P334 Language BG Потопете в хладка вода [или сложете мокри компреси]. ES Sumergir en agua fría [o envolver en vendas húmedas]. CS Ponořte do studené vody [nebo zabalte do vlhkého obvazu]. DA Hold under koldt vand [eller anvend våde omslag]. DE In kaltes Wasser tauchen [oder nassen Verband anlegen]. ET Hoida jahedas vees [või panna peale niiske kompress]. EL Βυθίστε σε δροσερό νερό [ή τυλίξτε με βρεγμένους επιδέσμους]. EN Immerse in cool water [or wrap in wet bandages]. FR Rincer à l'eau fraîche [ou poser une compresse humide]. GA Tum in uisce fionnuar [nó cuir bréid fliuch air]. HR Uroniti u hladnu vodu [ili omotati vlažnim zavojem]. IT Immergere in acqua fredda [o avvolgere con un bendaggio umido]. LV Iegremdēt vēsā ūdenī [vai ietīt mitros apsējos]. LT Įmerkti į vėsų vandenį [arba apvynioti šlapiais tvarsčiais]. HU Hideg vízzel [vagy nedves kötéssel] kell hűteni. MT Daħħal fl-ilma kiesaħ [jew kebbeb f'faxex imxarrbin]. NL In koud water onderdompelen [of nat verband aanbrengen]. PL Zanurzyć w zimnej wodzie [lub owinąć mokrym bandażem]. PT Mergulhar em água fria [ou aplicar compressas húmidas]. RO Introduceți în apă rece [sau acoperiți cu o compresă umedă]. SK Ponorte do studenej vody [alebo obviažte mokrými obväzmi]. SL Potopiti v hladno vodo [ali zaviti v mokre povoje]. FI Upota kylmään veteen [tai kääri märkiin siteisiin]. SV Skölj under kallt vatten [eller använd våta omslag]. P335 Language BG Отстранете от кожата посипаните частици. ES Sacudir las partículas que se hayan depositado en la piel. CS Volné částice odstraňte z kůže. … 234 unchanged lines … SL Umiti z veliko vode/… FI Pese runsaalla vedellä/… SV Tvätta med mycket vatten/… P353 Language BG Облейте кожата с вода/вземете душ. ES Aclararse la piel con agua/ducharse. CS Opláchněte kůži vodou/osprchujte. DA Skyl/brus huden med vand. DE Haut mit Wasser abwaschen/duschen. ET Loputada nahka veega/loputada duši all. EL Ξεπλύνετε την επιδερμίδα με νερό/στο ντους. EN Rinse skin with water/shower. FR Rincer la peau à l’eau/se doucher. GA Sruthlaítear an craiceann le huisce/glac cithfholcadh. HR Isprati kožu vodom/tuširanjem. IT Sciacquare la pelle/fare una doccia. LV Noskalot ādu ar ūdeni/dušā. LT Odą nuplauti vandeniu/čiurkšle. HU A bőrt le kell öblíteni vízzel/zuhanyozás. MT Laħlaħ il-ġilda bl-ilma/bix-xawer. NL Huid met water afspoelen/afdouchen. PL Spłukać skórę pod strumieniem wody/prysznicem. PT Enxaguar a pele com água/tomar um duche. RO Clătiți pielea cu apă/faceți duș. SK Pokožku opláchnite vodou/sprchou. SL Kožo izprati z vodo/prho. FI Huuhdo/suihkuta iho vedellä. SV Skölj huden med vatten/duscha. P353 Language BG Облейте кожата с вода [или вземете душ]. ES Enjuagar la piel con agua [o ducharse]. CS Opláchněte kůži vodou [nebo osprchujte]. DA Skyl [eller brus] huden med vand. DE Haut mit Wasser abwaschen [oder duschen]. ET Loputada nahka veega [või loputada duši all]. EL Ξεπλύνετε την επιδερμίδα με νερό [ή στο ντους]. EN Rinse skin with water [or shower]. FR Rincer la peau à l'eau [ou se doucher]. GA Sruthlaítear an craiceann le huisce [nó glac cithfholcadh]. HR Isprati kožu vodom [ili tuširanjem]. IT Sciacquare la pelle [o fare una doccia]. LV Noskalot ādu ar ūdeni [vai iet dušā]. LT Odą nuplauti vandeniu [arba čiurkšle]. HU A bőrt le kell öblíteni vízzel [vagy zuhanyozás]. MT Laħlaħ il-ġilda bl-ilma [jew bix-xawer]. NL Huid met water afspoelen [of afdouchen]. PL Spłukać skórę pod strumieniem wody [lub prysznicem]. PT Enxaguar a pele com água [ou tomar um duche]. RO Clătiți pielea cu apă [sau faceți duș]. SK Pokožku ihneď opláchnite vodou [alebo sprchou]. SL Kožo izprati z vodo [ali prho]. FI Huuhdo iho vedellä [tai suihkuta]. SV Skölj huden med vatten [eller duscha]. P360 Language BG Незабавно облейте замърсеното облекло и кожата обилно с вода, преди да свалите дрехите. ES Aclarar inmediatamente con agua abundante las prendas y la piel contaminadas antes de quitarse la ropa. CS Kontaminovaný oděv a kůži okamžitě omyjte velkým množstvím vody a potom oděv odložte. … 162 unchanged lines … SL Ob velikem požaru in velikih količinah: FI Jos tulipalo ja ainemäärät ovat suuret: SV Vid större brand och stora mängder: P372 Language BG Опасност от експлозия при пожар. ES Riesgo de explosión en caso de incendio. CS Nebezpečí výbuchu v případě požáru. DA Eksplosionsfare ved brand. DE Explosionsgefahr bei Brand. ET Tulekahju korral plahvatusoht. EL Κίνδυνος έκρηξης σε περίπτωση πυρκαγιάς. EN Explosion risk in case of fire. FR Risque d’explosion en cas d’incendie. GA Baol pléasctha i gcás dóiteáin. HR Opasnost od eksplozije u slučaju požara. IT Rischio di esplosione in caso di incendio. LV Eksplozijas risks ugunsgrēka gadījumā: LT Sprogimo pavojus gaisro atveju. HU Tűz esetén robbanásveszély. MT Riskju ta' splużjoni f’każ ta' nar. NL Ontploffingsgevaar in geval van brand. PL Ryzyko wybuchu w razie pożaru. PT Risco de explosão em caso de incêndio. RO Risc de explozie în caz de incendiu. SK V prípade požiaru hrozí riziko výbuchu. SL Nevarnost eksplozije ob požaru. FI Tulipalon sattuessa räjähdysvaara. SV Explosionsrisk vid brand. P372 Language BG Опасност от експлозия. ES Riesgo de explosión. CS Nebezpečí výbuchu. DA Eksplosionsfare. DE Explosionsgefahr. ET Plahvatusoht. EL Κίνδυνος έκρηξης. EN Explosion risk. FR Risque d'explosion. GA Baol pléasctha. HR Opasnost od eksplozije. IT Rischio di esplosione. LV Eksplozijas risks. LT Sprogimo pavojus. HU Robbanásveszély. MT Riskju ta' splużjoni. NL Ontploffingsgevaar. PL Zagrożenie wybuchem. PT Risco de explosão. RO Risc de explozie. SK Riziko výbuchu. SL Nevarnost eksplozije. FI Räjähdysvaara. SV Explosionsrisk. P373 Language BG НЕ се опитвайте да гасите пожара, ако огънят наближи експлозиви. ES NO luchar contra el incendio cuando el fuego llega a los explosivos. CS Požár NEHASTE, dostane-li se k výbušninám. … 181 unchanged lines … SL Izprazniti območje. FI Evakuoi alue. SV Utrym området. P381 Language BG Премахнете всички източници на запалване, ако е безопасно. ES Eliminar todas las fuentes de ignición si no hay peligro en hacerlo. CS Odstraňte všechny zdroje zapálení, můžete-li tak učinit bez rizika. DA Fjern alle antændelseskilder, hvis dette kan gøres sikkert. DE Alle Zündquellen entfernen, wenn gefahrlos möglich. ET Eemaldada kõik süüteallikad, kui seda on võimalik teha ohutult. EL Απομακρύνετε τις πηγές ανάφλεξης, εάν αυτό μπορεί να γίνει χωρίς κίνδυνο. EN Eliminate all ignition sources if safe to do so. FR Éliminer toutes les sources d’ignition si cela est faisable sans danger. GA Díothaigh gach foinse adhainte, má tá sé sábháilte é sin a dhéanamh. HR Ukloniti sve izvore paljenja ukoliko je to moguće sigurno učiniti. IT Eliminare ogni fonte di accensione se non c’è pericolo. LV Novērst visus uzliesmošanas avotus, ja to var izdarīt droši. LT Pašalinti visus uždegimo šaltinius, jeigu galima saugiai tai padaryti. HU Meg kell szüntetni az összes gyújtóforrást, ha ez biztonságosan megtehető. MT Elimina s-sorsi kollha li jqabbdu sakemm ma jkunx perikoluż li tagħmel dan. NL Alle ontstekingsbronnen wegnemen als dat veilig gedaan kan worden. PL Wyeliminować wszystkie źródła zapłonu, jeżeli jest to bezpieczne. PT Eliminar todas as fontes de ignição se tal puder ser feito em segurança. RO Eliminați toate sursele de aprindere, dacă acest lucru se poate face în siguranță. SK Ak je to bezpečné, odstráňte všetky zdroje zapálenia. SL Odstraniti vse vire vžiga, če je varno. FI Poista kaikki sytytyslähteet, jos sen voi tehdä turvallisesti. SV Avlägsna alla antändningskällor om det kan göras på ett säkert sätt. P381 Language BG В случай на изтичане премахнете всички източници на запалване. ES En caso de fuga, eliminar todas las fuentes de ignición. CS V případě úniku odstraňte všechny zdroje zapálení. DA I tilfælde af lækage fjernes alle antændelseskilder. DE Bei Undichtigkeit alle Zündquellen entfernen. ET Lekke korral eemaldada kõik süüteallikad. EL Σε περίπτωση διαρροής, εξαλείψτε όλες τις πηγές ανάφλεξης. EN In case of leakage, eliminate all ignition sources. FR En cas de fuite, éliminer toutes les sources d'ignition. GA I gcás sceite, díothaigh gach foinse adhainte. HR U slučaju istjecanja ukloniti sve izvore paljenja. IT In caso di perdita, eliminare ogni fonte di accensione. LV Noplūdes gadījumā novērst visus uzliesmošanas avotus. LT Nuotėkio atveju, pašalinti visus uždegimo šaltinius. HU Szivárgás esetén meg kell szüntetni az összes gyújtóforrást. MT F'każ ta' tnixxija, elimina s-sorsi kollha li jqabbdu. NL In geval van lekkage alle ontstekingsbronnen wegnemen. PL W przypadku wycieku wyeliminować wszystkie źródła zapłonu. PT Em caso de fuga, eliminar todas as fontes de ignição. RO În caz de scurgeri, eliminați toate sursele de aprindere. SK V prípade úniku odstráňte všetky zdroje zapálenia. SL V primeru uhajanja odstraniti vse vire vžiga. FI Vuototapauksessa poista kaikki sytytyslähteet. SV Vid läckage, avlägsna alla antändningskällor. P390 Language BG Попийте разлятото, за да се предотвратят материални вреди. ES Absorber el vertido para que no dañe otros materiales. CS Uniklý produkt absorbujte, aby se zabránilo materiálním škodám. … 66 unchanged lines … SL PRI ZAUŽITJU: Takoj pokličite CENTER ZA ZASTRUPITVE/zdravnika/… FI JOS KEMIKAALIA ON NIELTY: Ota välittömästi yhteys MYRKYTYSTIETOKESKUKSEEN/lääkäriin/… SV VID FÖRTÄRING: Kontakta genast GIFTINFORMATIONSCENTRALEN/läkare/… P301 + P312 Language BG ПРИ ПОГЛЪЩАНЕ: При неразположение се обадете в ЦЕНТЪР ПО ТОКСИКОЛОГИЯ/на лекар/… ES EN CASO DE INGESTIÓN: Llamar a un CENTRO DE TOXICOLOGĺA/médico/…/si la persona se encuentra mal. CS PŘI POŽITÍ: Necítíte-li se dobře, volejte TOXIKOLOGICKÉ INFORMAČNÍ STŘEDISKO/lékaře/… DA I TILFÆLDE AF INDTAGELSE: I tilfælde af ubehag, ring til en GIFTINFORMATION/læge/…/ DE BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/…/anrufen. ET ALLANEELAMISE KORRAL: halva enesetunde korral võtta ühendust MÜRGISTUSTEABEKESKUSE/arstiga… EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΚΑΤΑΠΟΣΗΣ: Καλέστε το ΚΕΝΤΡΟ ΔΗΛΗΤΗΡΙΑΣΕΩΝ/γιατρό/…/εάν αισθανθείτε αδιαθεσία. EN IF SWALLOWED: Call a POISON CENTER/doctor/…/if you feel unwell. FR EN CAS D’INGESTION: Appeler un CENTRE ANTIPOISON/un médecin/…/en cas de malaise. GA MÁ SHLOGTAR: Cuir glao ar IONAD NIMHE/ar dhoctúir/… mura mbraitheann tú go maith. HR AKO SE PROGUTA: u slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA/liječnika/… IT IN CASO DI INGESTIONE: contattare un CENTRO ANTIVELENI/un medico/…/in caso di malessere. LV NORĪŠANAS GADĪJUMĀ: Sazinieties ar SAINDĒŠANĀS INFORMĀCIJAS CENTRU/ārstu/.., ja jums ir slikta pašsajūta. LT PRARIJUS: pasijutus blogai, skambinti į APSINUODIJIMŲ KONTROLĖS IR INFORMACIJOS BIURĄ/kreiptis į gydytoją/… P301 + P312 Language BG ПРИ ПОГЛЪЩАНЕ: при неразположение се обадете в ЦЕНТЪР ПО ТОКСИКОЛОГИЯ/на лекар/… ES EN CASO DE INGESTIÓN: Llamar a un CENTRO DE TOXICOLOGÍA / médico /… si la persona se encuentra mal. CS PŘI POŽITÍ: Necítíte-li se dobře, volejte TOXIKOLOGICKÉ INFORMAČNÍ STŘEDISKO / lékaře / … . DA I TILFÆLDE AF INDTAGELSE: Kontakt GIFTLINJEN/læge/… i tilfælde af ubehag. DE BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/… anrufen. ET ALLANEELAMISE KORRAL: halva enesetunde korral võtta ühendust MÜRGISTUSTEABEKESKUSEGA/arstiga/…/. EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΚΑΤΑΠΟΣΗΣ: Καλέστε το ΚΕΝΤΡΟ ΔΗΛΗΤΗΡΙΑΣΕΩΝ/γιατρό/…, αν αισθανθείτε αδιαθεσία. EN IF SWALLOWED: Call a POISON CENTRE/doctor/… if you feel unwell. FR EN CAS D'INGESTION: Appeler un CENTRE ANTIPOISON/un médecin/…/ en cas de malaise. GA MÁ SHLOGTAR: Cuir glao ar IONAD NIMHE/dochtúir/… má bhraitheann tú tinn. HR AKO SE PROGUTA: u slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA / liječnika / … IT IN CASO DI INGESTIONE: in presenza di malessere, contattare un CENTRO ANTIVELENI/un medico/… . LV NORĪŠANAS GADĪJUMĀ: Sazinieties ar SAINDĒŠANĀS INFORMĀCIJAS CENTRU/ ārstu/…, ja jums ir slikta pašsajūta. LT PRARIJUS: pasijutus blogai, skambinti į APSINUODIJIMŲ KONTROLĖS IR INFORMACIJOS BIURĄ / kreiptis į gydytoją / … HU LENYELÉS ESETÉN: Rosszullét esetén forduljon TOXIKOLÓGIAI KÖZPONTHOZ/orvoshoz/…. MT JEKK JINBELA’: Sejjaħ ĊENTRU TAL-AVVELENAMENT/tabib/…/jekk ma tħossokx f’sikktek. MT JEKK JINBELA': Ikkuntattja ĊENTRU TAL-AVVELENAMENT / tabib /… jekk tħossok ma tiflaħx. NL NA INSLIKKEN: bij onwel voelen een ANTIGIFCENTRUM/arts/… raadplegen. PL W PRZYPADKU POŁKNIĘCIA: W przypadku złego samopoczucia skontaktować się z OŚRODKIEM ZATRUĆ/lekarzem/… PT EM CASO DE INGESTÃO: caso sinta indisposição, contacte um CENTRO DE INFORMAÇÃO ANTIVENENOS/médico/… RO ÎN CAZ DE ÎNGHIȚIRE: sunați la un CENTRU DE INFORMARE TOXICOLOGICĂ/un medic/…/dacă nu vă simțiți bine. SK PO POŽITÍ: Pri zdravotných problémoch volajte TOXIKOLOGICKÉ INFORMAČNÉ CENTRUM/lekára/… SL PRI ZAUŽITJU: Ob slabem počutju pokličite CENTER ZA ZASTRUPITVE/zdravnika/…/. FI JOS KEMIKAALIA ON NIELTY: Ota yhteys MYRKYTYSTIETOKESKUKSEEN/lääkäriin/…/jos ilmenee pahoinvointia. SV VID FÖRTÄRING: Vid obehag, kontakta GIFTINFORMATIONSCENTRALEN/läkare/… PL W PRZYPADKU POŁKNIĘCIA: W przypadku złego samopoczucia skontaktować się z OŚRODKIEM ZATRUĆ/ lekarzem/…. PT EM CASO DE INGESTÃO: Caso sinta indisposição, contacte um CENTRO DE INFORMAÇÃO ANTIVENENOS/médico/… . RO ÎN CAZ DE ÎNGHIȚIRE: Sunați la un CENTRU DE INFORMARE TOXICOLOGICĂ/un medic/… dacă nu vă simțiți bine. SK PO POŽITÍ: Pri zdravotných problémoch volajte NÁRODNÉ TOXIKOLOGICKÉ INFORMAČNÉ CENTRUM/lekára/… . SL PRI ZAUŽITJU: Ob slabem počutju pokličite CENTER ZA ZASTRUPITVE/zdravnika/… . FI JOS KEMIKAALIA ON NIELTY: Ota yhteys MYRKYTYSTIETOKESKUKSEEN/lääkäriin/…, jos ilmenee pahoinvointia. SV VID FÖRTÄRING: Vid obehag, kontakta GIFTINFORMATIONSCENTRALEN/läkare… . P301 + P330 + P331 Language BG ПРИ ПОГЛЪЩАНЕ: изплакнете устата. НЕ предизвиквайте повръщане. ES EN CASO DE INGESTIÓN: Enjuagarse la boca. NO provocar el vómito. CS PŘI POŽITÍ: Vypláchněte ústa. NEVYVOLÁVEJTE zvracení. … 18 unchanged lines … SL PRI ZAUŽITJU: izprati usta. NE izzvati bruhanja. FI JOS KEMIKAALIA ON NIELTY: Huuhdo suu. EI saa oksennuttaa. SV VID FÖRTÄRING: Skölj munnen. Framkalla INTE kräkning. P302 + P334 Language BG ПРИ КОНТАКТ С КОЖАТА: Потопете в студена вода/сложете мокри компреси. ES EN CASO DE CONTACTO CON LA PIEL: Sumergir en agua fresca/aplicar compresas húmedas. CS PŘI STYKU S KŮŽÍ: Ponořte do studené vody/zabalte do vlhkého obvazu. DA VED KONTAKT MED HUDEN: Skyl under koldt vand/anvend våde omslag. DE BEI BERÜHRUNG MIT DER HAUT: In kaltes Wasser tauchen/nassen Verband anlegen. ET NAHALE SATTUMISE KORRAL: hoida jahedas vees/panna peale niiske kompress. EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΠΑΦΗΣ ΜΕ ΤΟ ΔΕΡΜΑ: Πλύντε με άφθονο δροσερό νερό/τυλίξτε με βρεγμένους επιδέσμους. EN IF ON SKIN: Immerse in cool water/wrap in wet bandages. FR EN CAS DE CONTACT AVEC LA PEAU: rincer à l’eau fraîche/poser une compresse humide. GA I gCÁS TEAGMHÁLA LEIS AN gCRAICEANN: Tum in uisce fionnuar/cuir bréid fliuch air. HR U SLUČAJU DODIRA S KOŽOM: uroniti u hladnu vodu/omotati vlažnim zavojem. IT IN CASO DI CONTATTO CON LA PELLE: immergere in acqua fredda/avvolgere con un bendaggio umido. LV SASKARĒ AR ĀDU: iegremdēt vēsā ūdenī/ietīt mitros apsējos. LT PATEKUS ANT ODOS: Įmerkti į vėsų vandenį/apvynioti šlapiais tvarsčiais. HU HA BŐRRE KERÜL: Hideg vízzel/nedves kötéssel kell hűteni. MT JEKK FUQ IL-ĠILDA: Daħħal fl-ilma frisk/kebbeb f’faxex imxarrbin. NL BIJ CONTACT MET DE HUID: in koud water onderdompelen/nat verband aanbrengen. PL W PRZYPADKU KONTAKTU ZE SKÓRĄ: Zanurzyć w zimnej wodzie/owinąć mokrym bandażem. PT SE ENTRAR EM CONTACTO COM A PELE: mergulhar em água fria/aplicar compressas húmidas. RO ÎN CAZ DE CONTACT CU PIELEA: introduceți în apă rece/acoperiți cu o compresă umedă. SK PRI KONTAKTE S POKOŽKOU: Ponorte do studenej vody/obviažte mokrými obväzmi. SL PRI STIKU S KOŽO: potopiti v hladno vodo/zaviti v mokre povoje. FI JOS KEMIKAALIA JOUTUU IHOLLE: Upota kylmään veteen/kääri märkiin siteisiin. SV VID HUDKONTAKT: Skölj under kallt vatten/använd våta omslag. P302 + P334 Language BG ПРИ КОНТАКТ С КОЖАТА: потопете в хладка вода или сложете мокри компреси. ES EN CASO DE CONTACTO CON LA PIEL: Sumergir en agua fría o envolver en vendas húmedas. CS PŘI STYKU S KŮŽÍ: Ponořte do studené vody nebo zabalte do vlhkého obvazu. DA VED KONTAKT MED HUDEN: Hold under koldt vand eller anvend våde omslag. DE BEI BERÜHRUNG MIT DER HAUT: In kaltes Wasser tauchen oder nassen Verband anlegen. ET NAHALE SATTUMISE KORRAL: hoida jahedas vees või panna peale niiske kompress. EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΠΑΦΗΣ ΜΕ ΤΟ ΔΕΡΜΑ: Βυθίστε σε δροσερό νερό ή τυλίξτε με βρεγμένους επιδέσμους. EN IF ON SKIN: Immerse in cool water or wrap in wet bandages. FR EN CAS DE CONTACT AVEC LA PEAU: Rincer à l'eau fraîche ou poser une compresse humide. GA I gCÁS TEAGMHÁLA LEIS AN gCRAICEANN: Tum in uisce fionnuar nó cuir bréid fliuch air. HR U SLUČAJU DODIRA S KOŽOM: uroniti u hladnu vodu ili omotati vlažnim zavojem. IT IN CASO DI CONTATTO CON LA PELLE: immergere in acqua fredda o avvolgere con un bendaggio umido. LV SASKARĒ AR ĀDU: Iegremdēt vēsā ūdenī vai ietīt mitros apsējos. LT PATEKUS ANT ODOS: įmerkti į vėsų vandenį arba apvynioti šlapiais tvarsčiais. HU HA BŐRRE KERÜL: Hideg vízzel vagy nedves kötéssel kell hűteni. MT JEKK FUQ IL-ĠILDA: Daħħal fl-ilma frisk jew kebbeb f'faxex imxarrbin. NL BIJ CONTACT MET DE HUID: in koud water onderdompelen of nat verband aanbrengen. PL W PRZYPADKU KONTAKTU ZE SKÓRĄ: Zanurzyć w zimnej wodzie lub owinąć mokrym bandażem. PT SE ENTRAR EM CONTACTO COM A PELE: Mergulhar em água fria ou aplicar compressas húmidas. RO ÎN CAZ DE CONTACT CU PIELEA: Introduceți în apă rece sau acoperiți cu o compresă umedă. SK PRI KONTAKTE S POKOŽKOU: Ponorte do studenej vody alebo obviažte mokrými obväzmi. SL PRI STIKU S KOŽO: Potopiti v hladno vodo ali zaviti v mokre povoje. FI JOS KEMIKAALIA JOUTUU IHOLLE: Upota kylmään veteen tai kääri märkiin siteisiin. SV VID HUDKONTAKT: Skölj under kallt vatten eller använd våta omslag. P302 + P350 Language BG ПРИ КОНТАКТ С КОЖАТА: Измийте внимателно и обилно със сапун и вода. ES EN CASO DE CONTACTO CON LA PIEL: Lavar suavemente con agua y jabón abundantes. CS PŘI STYKU S KŮŽÍ: Jemně omyjte velkým množstvím vody a mýdla. … 282 unchanged lines … SL Če nastopi draženje kože ali se pojavi izpuščaj: poiščite zdravniško pomoč/oskrbo. FI Jos ilmenee ihoärsytystä tai ihottumaa: Hakeudu lääkäriin. SV Vid hudirritation eller utslag: Sök läkarhjälp. P336 + P315 Language BG Размразете замръзналите части в хладка вода. Не разтривайте засегнатото място. Незабавно потърсете медицински съвет/помощ. ES Descongelar las partes congeladas con agua tibia. No frotar la parte afectada. Buscar asistencia médica inmediata. CS Omrzlá místa ošetřete vlažnou vodou. Postižené místo netřete. Okamžitě vyhledejte lékařskou pomoc/ošetření. DA Opvarm forsigtigt af frostskadede legemsdele i lunkent vand. Gnid ikke det angrebne område. Søg omgående lægehjælp. DE Vereiste Bereiche mit lauwarmem Wasser auftauen. Betroffenen Bereich nicht reiben. Sofort ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen. ET Sulatada külmunud piirkonnad leige veega. Kannatada saanud piirkonda mitte hõõruda. Pöörduda viivitamata arsti poole. EL Ξεπαγώστε τα παγωμένα μέρη με χλιαρό νερό. Μην τρίβετε την περιοχή που πάγωσε. Συμβουλευθείτε/Επισκεφθείτε αμέσως γιατρό. EN Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention. FR Dégeler les parties gelées avec de l'eau tiède. Ne pas frotter les zones touchées. Consulter immédiatement un médecin. GA Leáigh codanna sioctha le huisce alabhog. Ná cuimil an réimse lena mbaineann. Faigh comhairle/cúram liachta láithreach. HR Zamrznute dijelove odmrznuti mlakom vodom. Ne trljati oštećeno mjesto. Hitno zatražiti savjet/pomoć liječnika. IT Sgelare le parti congelate usando acqua tiepida. Non sfregare la parte interessata. Consultare immediatamente un medico. LV Atkausēt sasalušās daļas ar remdenu ūdeni. Skarto zonu neberzt. Nekavējoties lūgt palīdzību mediķiem. LT Prišalusias daleles atitirpinti drungnu vandeniu. Netrinti paveiktos zonos. Nedelsiant kreiptis į gydytoją. HU A fagyott részeket langyos vízzel fel kell melegíteni. Tilos az érintett terület dörzsölése. Azonnal orvosi ellátást kell kérni. MT Ħoll il-partijiet kiesħa bl-ilma fietel. Togħrokx il-parti affettwata. Ikkonsulta tabib minnufih. NL Bevroren lichaamsdelen met lauw water ontdooien. Niet wrijven. Onmiddellijk een arts raadplegen. PL Rozmrozić oszronione obszary letnią wodą. Nie trzeć oszronionego obszaru. Natychmiast zasięgnąć porady/zgłosić się pod opiekę lekarza. PT Derreter as zonas congeladas com água morna. Não friccionar a zona afetada. Consulte imediatamente um médico. RO Dezghețați părțile degerate cu apă călduță. Nu frecați zona afectată. Consultați imediat medicul. SK Zmrznuté časti ošetrite vlažnou vodou. Postihnuté miesto netrite. Okamžite vyhľadajte lekársku pomoc/starostlivosť. SL Zamrznjene dele odtaliti z mlačno vodo. Ne drgniti prizadetega mesta. Takoj poiščite zdravniško pomoč/oskrbo. FI Sulata jäätyneet alueet haalealla vedellä. Vahingoittunutta aluetta ei saa hangata. Hakeudu välittömästi lääkäriin. SV Värm det köldskadade området med ljummet vatten. Gnid inte det skadade området. Sök omedelbart läkarhjälp. P335 + P334 Language BG Отстранете посипаните частици от кожата. Потопете в хладка вода/сложете мокри компреси. ES Sacudir las partículas que se hayan depositado en la piel. Sumergir en agua fresca/aplicar compresas húmedas. CS Volné částice odstraňte z kůže. Ponořte do studené vody/zabalte do vlhkého obvazu. … 162 unchanged lines … SL Ob požaru: Za gašenje se uporabi … FI Tulipalon sattuessa: Käytä palon sammuttamiseen… SV Vid brand: Släck med… P301 + P330 + P331 Language BG ПРИ ПОГЛЪЩАНЕ: изплакнете устата. НЕ предизвиквайте повръщане. ES EN CASO DE INGESTIÓN: Enjuagar la boca. NO provocar el vómito. CS PŘI POŽITÍ: Vypláchněte ústa. NEVYVOLÁVEJTE zvracení. DA I TILFÆLDE AF INDTAGELSE: Skyl munden. Fremkald IKKE opkastning. DE BEI VERSCHLUCKEN: Mund ausspülen. KEIN Erbrechen herbeiführen. ET ALLANEELAMISE KORRAL: loputada suud. MITTE kutsuda esile oksendamist. EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΚΑΤΑΠΟΣΗΣ: Ξεπλύνετε το στόμα. ΜΗΝ προκαλέσετε εμετό. EN IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. FR EN CAS D'INGESTION: Rincer la bouche. NE PAS faire vomir. GA MÁ SHLOGTAR: Sruthlaítear an béal. NÁ spreagtar urlacan. HR AKO SE PROGUTA: isprati usta. NE izazivati povraćanje. IT IN CASO DI INGESTIONE: sciacquare la bocca. NON provocare il vomito. LV NORĪŠANAS GADĪJUMĀ: Izskalot muti. NEIZRAISĪT vemšanu. LT PRARIJUS: išskalauti burną. NESKATINTI vėmimo. HU LENYELÉS ESETÉN: A szájat ki kell öblíteni. TILOS hánytatni. MT JEKK JINBELA': Laħlaħ il-ħalq. TIPPROVOKAX ir-remettar. NL NA INSLIKKEN: de mond spoelen. GEEN braken opwekken. PL W PRZYPADKU POŁKNIĘCIA: wypłukać usta. NIE wywoływać wymiotów. PT EM CASO DE INGESTÃO: Enxaguar a boca. NÃO provocar o vómito. RO ÎN CAZ DE ÎNGHIȚIRE: Clătiți gura. NU provocați voma. SK PO POŽITÍ: vypláchnite ústa. NEVYVOLÁVAJTE zvracanie. SL PRI ZAUŽITJU: Izprati usta. Ne izzivati bruhanja. FI JOS KEMIKAALIA ON NIELTY: Huuhdo suu. EI saa oksennuttaa. SV VID FÖRTÄRING: Skölj munnen. Framkalla INTE kräkning. P302 + P335 + P334 Language BG ПРИ КОНТАКТ С КОЖАТА: отстранете от кожата посипаните частици. Потопете в хладка вода [или сложете мокри компреси]. ES EN CASO DE CONTACTO CON LA PIEL: Cepillar las partículas sueltas depositadas en la piel; sumergir en agua fría [o envolver en vendas húmedas]. CS PŘI STYKU S KŮŽÍ: Volné částečky odstraňte z kůže. Ponořte do studené vody [nebo zabalte do vlhkého obvazu]. DA VED KONTAKT MED HUDEN: Børst løse partikler bort fra huden. Hold under koldt vand [eller anvend våde omslag]. DE BEI BERÜHRUNG MIT DER HAUT: Lose Partikel von der Haut abbürsten. In kaltes Wasser tauchen [oder nassen Verband anlegen]. ET NAHALE SATTUMISE KORRAL: pühkida lahtised osakesed nahalt maha. Hoida jahedas vees [või panna peale niiske kompress]. EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΠΑΦΗΣ ΜΕ ΤΟ ΔΕΡΜΑ: Αφαιρέστε προσεκτικά τα σωματίδια που έχουν μείνει στο δέρμα με μια βούρτσα. Βυθίστε σε δροσερό νερό [ή τυλίξτε με βρεγμένους επιδέσμους]. EN IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. FR EN CAS DE CONTACT AVEC LA PEAU: Enlever avec précaution les particules déposées sur la peau. Rincer à l'eau fraîche [ou poser une compresse humide]. GA I gCÁS TEAGMHÁLA LEIS AN gCRAICEANN: Glan cáithníní scaoilte den chraiceann. Tum in uisce fionnuar [nó cuir bréid fliuch air]. HR U SLUČAJU DODIRA S KOŽOM: izmesti zaostale čestice s kože. Uroniti u hladnu vodu [ili omotati vlažnim zavojem]. IT IN CASO DI CONTATTO CON LA PELLE: rimuovere le particelle depositate sulla pelle. Immergere in acqua fredda [o avvolgere con un bendaggio umido]. LV SASKARĒ AR ĀDU: Noslaucīt brīvās daļiņas no ādas. Iegremdēt vēsā ūdenī [vai ietīt mitros apsējos]. LT PATEKUS ANT ODOS: neprilipusias daleles nuvalyti nuo odos. Įmerkti į vėsų vandenį [arba apvynioti šlapiais tvarsčiais]. HU HA BŐRRE KERÜL: A bőrre lazán tapadó szemcséket óvatosan le kell kefélni. Hideg vízzel [vagy nedves kötéssel] kell hűteni. MT JEKK FUQ IL-ĠILDA: Farfar il-frak mhux imwaħħal minn mal-ġilda. Daħħal fl-ilma frisk [jew kebbeb f'faxex imxarrbin]. NL BIJ CONTACT MET DE HUID: losse deeltjes van de huid afvegen. In koud water onderdompelen [of nat verband aanbrengen]. PL W PRZYPADKU KONTAKTU ZE SKÓRĄ: Niezwiązaną pozostałość strzepnąć ze skóry. Zanurzyć w zimnej wodzie [lub owinąć mokrym bandażem]. PT SE ENTRAR EM CONTACTO COM A PELE: Sacudir da pele as partículas soltas. Mergulhar em água fria [ou aplicar compressas húmidas]. RO ÎN CAZ DE CONTACT CU PIELEA: Îndepărtați particulele depuse pe piele. Introduceți în apă rece [sau acoperiți cu o compresă umedă]. SK PRI KONTAKTE S POKOŽKOU: Z pokožky oprášte sypké čiastočky. Ponorte do studenej vody [alebo obviažte mokrými obväzmi]. SL PRI STIKU S KOŽO: S krtačo odstraniti razsute delce s kože. Potopiti v hladno vodo [ali zaviti v mokre povoje]. FI JOS KEMIKAALIA JOUTUU IHOLLE: Poista irtohiukkaset iholta. Upota kylmään veteen [tai kääri märkiin siteisiin]. SV VID HUDKONTAKT: Borsta bort lösa partiklar från huden. Skölj under kallt vatten [eller använd våta omslag]. P303 + P361 + P353 Language BG ПРИ КОНТАКТ С КОЖАТА (или косата): незабавно свалете цялото замърсено облекло. Облейте кожата с вода [или вземете душ]. ES EN CASO DE CONTACTO CON LA PIEL (o el pelo): Quitar inmediatamente toda la ropa contaminada. Enjuagar la piel con agua [o ducharse]. CS PŘI STYKU S KŮŽÍ (nebo s vlasy): Veškeré kontaminované části oděvu okamžitě svlékněte. Opláchněte kůži vodou [nebo osprchujte]. DA VED KONTAKT MED HUDEN (eller håret): Tilsmudset tøj tages straks af/fjernes. Skyl [eller brus] huden med vand. DE BEI BERÜHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen [oder duschen]. ET NAHALE (või juustele) SATTUMISE KORRAL: kõik saastunud rõivad viivitamata seljast võtta. Loputada nahka veega [või loputada duši all]. EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΠΑΦΗΣ ΜΕ ΤΟ ΔΕΡΜΑ (ή με τα μαλλιά): Βγάλτε αμέσως όλα τα μολυσμένα ρούχα. Ξεπλύνετε την επιδερμίδα με νερό [ή στο ντους]. EN IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. FR EN CAS DE CONTACT AVEC LA PEAU (ou les cheveux): Enlever immédiatement tous les vêtements contaminés. Rincer la peau à l'eau [ou se doucher]. GA I gCÁS TEAGMHÁLA LEIS AN gCRAICEANN (nó le gruaig): Bain díot láithreach na héadaí éillithe go léir. Sruthlaítear an craiceann le huisce [nó glac cithfholcadh]. HR U SLUČAJU DODIRA S KOŽOM (ili kosom): odmah skinuti svu zagađenu odjeću. Isprati kožu vodom [ili tuširanjem]. IT IN CASO DI CONTATTO CON LA PELLE (o con i capelli): togliersi di dosso immediatamente tutti gli indumenti contaminati. Sciacquare la pelle [o fare una doccia]. LV SASKARĒ AR ĀDU (vai matiem): Nekavējoties novilkt visu piesārņoto apģērbu. Noskalot ādu ar ūdeni [vai iet dušā]. LT PATEKUS ANT ODOS (arba plaukų): nedelsiant nuvilkti visus užterštus drabužius. Odą nuplauti vandeniu [arba čiurkšle]. HU HA BŐRRE (vagy hajra) KERÜL: Az összes szennyezett ruhadarabot azonnal le kell vetni. A bőrt le kell öblíteni vízzel [vagy zuhanyozás]. MT JEKK FUQ IL-ĠILDA (jew ix-xagħar): Inża' minnufih l-ilbies kontaminat. Laħlaħ il-ġilda bl-ilma [jew bix-xawer]. NL BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen [of afdouchen]. PL W PRZYPADKU KONTAKTU ZE SKÓRĄ (lub z włosami): Natychmiast zdjąć całą zanieczyszczoną odzież. Spłukać skórę pod strumieniem wody [lub prysznicem]. PT SE ENTRAR EM CONTACTO COM A PELE (ou o cabelo): Retirar imediatamente toda a roupa contaminada. Enxaguar a pele com água [ou tomar um duche]. RO ÎN CAZ DE CONTACT CU PIELEA (sau cu părul): Scoateți imediat toată îmbrăcămintea contaminată. Clătiți pielea cu apă [sau faceți duș]. SK PRI KONTAKTE S POKOŽKOU (alebo vlasmi): Vyzlečte všetky kontaminované časti odevu. Pokožku ihneď opláchnite vodou [alebo sprchou]. SL PRI STIKU S KOŽO (ali lasmi): Takoj sleči vsa kontaminirana oblačila. Kožo izprati z vodo [ali prho]. FI JOS KEMIKAALIA JOUTUU IHOLLE (tai hiuksiin): Riisu saastunut vaatetus välittömästi. Huuhdo iho vedellä [tai suihkuta]. SV VID HUDKONTAKT (även håret): Ta omedelbart av alla nedstänkta kläder. Skölj huden med vatten [eller duscha]. P305 + P351 + P338 Language BG ПРИ КОНТАКТ С ОЧИТЕ: промивайте внимателно с вода в продължение на няколко минути. Свалете контактните лещи, ако има такива и доколкото това е възможно. Продължете с изплакването. ES EN CASO DE CONTACTO CON LOS OJOS: Enjuagar con agua cuidadosamente durante varios minutos. Quitar las lentes de contacto cuando estén presentes y pueda hacerse con facilidad. Proseguir con el lavado. CS PŘI ZASAŽENÍ OČÍ: Několik minut opatrně vyplachujte vodou. Vyjměte kontaktní čočky, jsou-li nasazeny a pokud je lze vyjmout snadno. Pokračujte ve vyplachování. DA VED KONTAKT MED ØJNENE: Skyl forsigtigt med vand i flere minutter. Fjern eventuelle kontaktlinser, hvis dette kan gøres let. Fortsæt skylning. DE BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. ET SILMA SATTUMISE KORRAL: loputada mitme minuti jooksul ettevaatlikult veega. Eemaldada kontaktläätsed, kui neid kasutatakse ja kui neid on kerge eemaldada. Loputada veel kord. EL ΣΕ ΠΕΡΙΠΤΩΣΗ ΕΠΑΦΗΣ ΜΕ ΤΑ ΜΑΤΙΑ: Ξεπλύνετε προσεκτικά με νερό για αρκετά λεπτά. Αν υπάρχουν φακοί επαφής, αφαιρέστε τους, αν είναι εύκολο. Συνεχίστε να ξεπλένετε. EN IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. FR EN CAS DE CONTACT AVEC LES YEUX: Rincer avec précaution à l'eau pendant plusieurs minutes. Enlever les lentilles de contact si la victime en porte et si elles peuvent être facilement enlevées. Continuer à rincer. GA I gCÁS TEAGMHÁLA LEIS NA SÚILE: Sruthlaítear go cúramach le huisce ar feadh roinnt nóiméad. Tóg amach na tadhall-lionsaí, más ann dóibh agus más furasta é sin a dhéanamh. Lean den sruthlú. HR U SLUČAJU DODIRA S OČIMA: oprezno ispirati vodom nekoliko minuta. Ukloniti kontaktne leće ako ih nosite i ako se one lako uklanjaju. Nastaviti ispirati. IT IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti. Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare. LV SASKARĒ AR ACĪM: Uzmanīgi izskalot ar ūdeni vairākas minūtes. Izņemt kontaktlēcas, ja tās ir ievietotas un ja to var vienkārši izdarīt. Turpināt skalot. LT PATEKUS Į AKIS: atsargiai plauti vandeniu kelias minutes. Išimti kontaktinius lęšius, jeigu jie yra ir jeigu lengvai galima tai padaryti. Toliau plauti akis. HU SZEMBE KERÜLÉS ESETÉN: Több percig tartó óvatos öblítés vízzel. Adott esetben a kontaktlencsék eltávolítása, ha könnyen megoldható. Az öblítés folytatása. MT JEKK JIDĦOL FL-GĦAJNEJN: Laħlaħ b'attenzjoni bl-ilma għal diversi minuti. Neħħi l-lentijiet tal-kuntatt, jekk ikun hemm u jkunu faċli biex tneħħihom. Kompli laħlaħ. NL BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen. PL W PRZYPADKU DOSTANIA SIĘ DO OCZU: Ostrożnie płukać wodą przez kilka minut. Wyjąć soczewki kontaktowe, jeżeli są i można je łatwo usunąć. Nadal płukać. PT SE ENTRAR EM CONTACTO COM OS OLHOS: Enxaguar cuidadosamente com água durante vários minutos. Se usar lentes de contacto, retire-as, se tal lhe for possível. Continue a enxaguar. RO ÎN CAZ DE CONTACT CU OCHII: Clătiți cu atenție cu apă timp de mai multe minute. Scoateți lentilele de contact, dacă este cazul și dacă acest lucru se poate face cu ușurință. Continuați să clătiți. SK PO ZASIAHNUTÍ OČÍ: Niekoľko minút ich opatrne vyplachujte vodou. Ak používate kontaktné šošovky a je to možné, odstráňte ich. Pokračujte vo vyplachovaní. SL PRI STIKU Z OČMI: Previdno izpirati z vodo nekaj minut. Odstranite kontaktne leče, če jih imate in če to lahko storite brez težav. Nadaljujte z izpiranjem. FI JOS KEMIKAALIA JOUTUU SILMIIN: Huuhdo huolellisesti vedellä usean minuutin ajan. Poista mahdolliset piilolinssit, jos sen voi tehdä helposti. Jatka huuhtomista. SV VID KONTAKT MED ÖGONEN: Skölj försiktigt med vatten i flera minuter. Ta ur eventuella kontaktlinser om det går lätt. Fortsätt att skölja. P370 + P380 Language BG При пожар: Евакуирайте зоната. ES En caso de incendio: Evacuar la zona. CS V případě požáru: Vykliďte prostor. … 66 unchanged lines … SL Ob velikem požaru in velikih količinah: izprazniti območje. Gasiti z večje razdalje zaradi nevarnosti eksplozije. FI Jos tulipalo ja ainemäärät ovat suuret: Evakuoi alue. Sammuta palo etäältä räjähdysvaaran takia. SV Vid större brand och stora mängder: Utrym området. Bekämpa branden på avstånd på grund av explosionsrisken. P370 + P372 + P380 + P373 Language BG При пожар: опасност от експлозия. Евакуирайте зоната. НЕ се опитвайте да гасите пожара, ако огънят наближи експлозиви. ES En caso de incendio: Riesgo de explosión. Evacuar la zona. NO combatir el incendio cuando este afecte a la carga. CS V případě požáru: Nebezpečí výbuchu. Vykliďte prostor. Požár NEHASTE, dostane-li se k výbušninám. DA Ved brand: Eksplosionsfare. Evakuer området. BEKÆMP IKKE branden, hvis denne når eksplosiverne. DE Bei Brand: Explosionsgefahr. Umgebung räumen. KEINE Brandbekämpfung, wenn das Feuer explosive Stoffe/Gemische/Erzeugnisse erreicht. ET Tulekahju korral: plahvatusoht. Ala evakueerida. Kui tuli jõuab lõhkeaineteni, MITTE teha kustutustöid. EL Σε περίπτωση πυρκαγιάς: Κίνδυνος έκρηξης. Εκκενώστε την περιοχή. ΜΗΝ προσπαθείτε να σβήσετε την πυρκαγιά, όταν η φωτιά πλησιάζει σε εκρηκτικά. EN In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives. FR En cas d'incendie: Risque d'explosion. Évacuer la zone. NE PAS combattre l'incendie lorsque le feu atteint les explosifs. GA I gcás dóiteáin: Baol pléasctha. Aslonnaigh gach duine as an limistéar. NÁ DÉAN an dóiteán a chomhrac má shroicheann sé pléascáin. HR U slučaju požara: opasnost od eksplozije. Evakuirati područje. NE gasiti vatru kada plamen zahvati eksplozive. IT Rischio di esplosione in caso di incendio. Evacuare la zona. NON utilizzare mezzi estinguenti se l'incendio raggiunge materiali esplosivi. LV Ugunsgrēka gadījumā: Eksplozijas risks. Evakuēt zonu. NECENSTIES dzēst ugunsgrēku, ja uguns piekļūst sprādzienbīstamām vielām. LT Gaisro atveju: sprogimo pavojus. Evakuoti zoną. NEGESINTI gaisro, jeigu ugnis pasiekia sprogmenis. HU Tűz esetén: Robbanásveszély. A területet ki kell üríteni. TILOS a tűz oltása, ha az robbanóanyagra átterjedt. MT F'każ ta' nar: Riskju ta' splużjoni. Evakwa ż-żona. TIPPRUVAX TITFI n-nar meta n-nar jilħaq l-isplussivi. NL In geval van brand: ontploffingsgevaar. Evacueren. NIET blussen wanneer het vuur de ontplofbare stoffen bereikt. PL W przypadku pożaru: Zagrożenie wybuchem. Ewakuować teren. NIE gasić pożaru, jeżeli ogień dosięgnie materiały wybuchowe. PT Em caso de incêndio: Risco de explosão. Evacuar a zona. Se o fogo atingir os explosivos, NÃO tentar combatê-lo. RO În caz de incendiu: Risc de explozie. Evacuați zona. NU încercați să stingeți incendiul atunci când focul a ajuns la explozivi. SK V prípade požiaru: Riziko výbuchu. Priestory evakuujte. Požiar NEHASTE, ak sa oheň priblížil k výbušninám. SL Ob požaru: Nevarnost eksplozije. Izprazniti območje. NE gasiti, ko ogenj doseže eksploziv. FI Tulipalon sattuessa: Räjähdysvaara. Evakuoi alue. Tulta EI SAA yrittää sammuttaa sen saavutettua räjähteet. SV Vid brand: Explosionsrisk. Utrym området. Försök INTE bekämpa branden när den når explosiva varor. P370 + P380 + P375[+ P378] Language BG При пожар: евакуирайте зоната. Гасете пожара от разстояние поради опасност от експлозия. [Използвайте…, за да загасите]. ES En caso de incendio: Evacuar la zona. Combatir el incendio a distancia, debido al riesgo de explosión. [Utilizar … en la extinción]. CS V případě požáru: Vykliďte prostor. Kvůli nebezpečí výbuchu haste z dostatečné vzdálenosti. [K uhašení použijte …]. DA Ved brand: Evakuer området. Bekæmp branden på afstand på grund af eksplosionsfare. [Anvend … til brandslukning]. DE Bei Brand: Umgebung räumen. Wegen Explosionsgefahr Brand aus der Entfernung bekämpfen. [… zum Löschen verwenden.] ET Tulekahju korral: ala evakueerida. Plahvatusohu tõttu teha kustutustöid eemalt. [Kustutamiseks kasutada ….]. EL Σε περίπτωση πυρκαγιάς: Εκκενώστε την περιοχή. Προσπαθήστε να σβήσετε την πυρκαγιά από απόσταση, επειδή υπάρχει κίνδυνος έκρηξης [Χρησιμοποιήστε … για την κατάσβεση]. EN In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish]. FR En cas d'incendie: Évacuer la zone. Combattre l'incendie à distance à cause du risque d'explosion. [Utiliser … pour l'extinction]. GA I gcás dóiteáin: Aslonnaigh gach duine as an limistéar. Téigh i gcianghleic leis an dóiteán mar gheall ar an mbaol pléasctha. [Úsáid … le haghaidh múchta]. HR U slučaju požara: evakuirati područje. Gasiti s veće udaljenosti zbog opasnosti od eksplozije. [Za gašenje rabiti…]. IT In caso di incendio: evacuare la zona. Rischio di esplosione. Utilizzare i mezzi estinguenti a grande distanza. [Estinguere con…]. LV Ugunsgrēka gadījumā: Evakuēt zonu. Dzēst uguni no attāluma eksplozijas riska dēļ. [Dzēšanai lietot …]. LT Gaisro atveju: evakuoti zoną. Gaisrą gesinti iš toli dėl sprogimo pavojaus. [Gesinimui naudoti …]. HU Tűz esetén: A területet ki kell üríteni. A tűz oltását robbanásveszély miatt távolból kell végezni. [Az oltáshoz … használandó]. MT F'każ ta' nar: Evakwa ż-żona. Itfi n-nar mill-bogħod minħabba r-riskju ta' splużjoni. [Uża … biex titfi]. NL In geval van brand: evacueren. Op afstand blussen in verband met ontploffingsgevaar. [Blussen met …]. PL W przypadku pożaru: Ewakuować teren. Z powodu ryzyka wybuchu gasić pożar z odległości. [Użyć … do gaszenia]. PT Em caso de incêndio: Evacuar a zona. Combater o incêndio à distância, devido ao risco de explosão. [Para extinguir utilizar…]. RO În caz de incendiu: Evacuați zona. Stingeți incendiul de la distanță din cauza pericolului de explozie. [Utilizați … pentru stingere]. SK V prípade požiaru: Priestory evakuujte. Z dôvodu nebezpečenstva výbuchu požiar haste z diaľky. [Na hasenie použite…]. SL Ob požaru: Izprazniti območje. Gasiti z večje razdalje zaradi nevarnosti eksplozije. [Za gašenje uporabiti …]. FI Tulipalon sattuessa: Evakuoi alue. Sammuta palo etäältä räjähdysvaaran takia. [Käytä palon sammuttamiseen …]. SV Vid brand: Utrym området. Bekämpa branden på avstånd på grund av explosionsrisken. [Släck med …]. Table 1.4 Precautionary statements — Storage P401 Language BG Да се съхранява… ES Almacenar … CS Skladujte … DA Opbevares … DE … aufbewahren. ET Hoida … EL Αποθηκεύεται … EN Store … FR Stocker … GA Stóráil … HR Skladištiti … IT Conservare… LV Glabāt… LT Laikyti… HU Tárolás: …. MT Aħżen … NL … bewaren. PL Przechowywać … PT Armazenar … RO A se depozita… SK Uchovávajte … SL Hraniti … FI Varastoi … SV Förvaras … P401 Language BG Да се съхранява съгласно… ES Almacenar conforme a … . CS Skladujte v souladu s … . DA Opbevares i overensstemmelse med … . DE Aufbewahren gemäß … . ET Hoida kooskõlas … . EL Αποθηκεύεται σύμφωνα με… . EN Store in accordance with… . FR Stocker conformément à… . GA Stóráil i gcomhréir le… . HR Skladištiti u skladu s… IT Conservare secondo… . LV Glabāt saskaņā ar … . LT Laikyti, vadovaujantis… HU A … -nak/-nek megfelelően tárolandó. MT Aħżen skont… . NL Overeenkomstig … bewaren. PL Przechowywać zgodnie z … . PT Armazenar em conformidade com… . RO A se depozita în conformitate cu… . SK Skladujte v súlade s… . SL Hraniti v skladu s/z… . FI Varastoi … mukaisesti. SV Förvaras enligt … . P402 Language BG Да се съхранява на сухо място. ES Almacenar en un lugar seco. CS Skladujte na suchém místě. … 91 unchanged lines … FI Varastoi lukitussa tilassa. SV Förvaras inlåst. P406 Language BG Да се съхранява в устойчив на разяждане съд/… съд с устойчива вътрешна облицовка. ES Almacenar en un recipiente resistente a la corrosión/… con revestimiento interior resistente. CS Skladujte v obalu odolném proti korozi/… obalu s odolnou vnitřní vrstvou. DA Opbevares i ætsningsbestandig/…beholder med modstandsdygtig indvendig belægning. DE In korrosionsbeständigem/… Behälter mit widerstandsfähiger Innenauskleidung aufbewahren. ES Almacenar en un recipiente resistente a la corrosión /… en un recipiente con revestimiento interior resistente. CS Skladujte v obalu odolném proti korozi/… s odolnou vnitřní vrstvou. DA Opbevares i ætsningsbestandig/… beholder med modstandsdygtig foring. DE In korrosionsbeständigem/… Behälter mit korrosionsbeständiger Innenauskleidung aufbewahren. ET Hoida sööbekindlas/…sööbekindla sisevooderdisega mahutis. EL Αποθηκεύεται σε ανθεκτικό στη διάβρωση/… περιέκτη με ανθεκτική εσωτερική επένδυση. EN Store in corrosive resistant/… container with a resistant inner liner. FR Stocker dans un récipient résistant à la corrosion/récipient en … avec doublure intérieure résistant à la corrosion. GA Stóráil i gcoimeádán … frithchreimneach/… le líneáil frithchreimneach laistigh. HR Skladištiti u spremniku otpornom na nagrizanje/… spremniku s otpornom unutarnjom oblogom. EN Store in a corrosion-resistant/… container with a resistant inner liner. FR Stocker dans un récipient résistant à la corrosion/… avec doublure intérieure. GA Stóráil i gcoimeádán/ … frithchreimneach le líneáil fhrithchreimneach laistigh. HR Skladištiti u spremniku otpornom na nagrizanje/ … s otpornom unutarnjom oblogom. IT Conservare in recipiente resistente alla corrosione/… provvisto di rivestimento interno resistente. LV Glabāt tvertnē, kas aizsargā pret koroziju/… tvertnes ar iekšējo pretkorozijas izolāciju. LV Glabāt korozijizturīgā/… tvertnē ar iekšējo pretkorozijas izolāciju. LT Laikyti korozijai atsparioje talpykloje/…, turinčioje atsparią vidinę dangą. HU Saválló/saválló bélésű … edényben tárolandó. MT Aħżen f'post reżistenti għall-korrużjoni/… kontenitur li huwa infurrat minn ġewwa b'materjal reżistenti. MT Aħżen f'post reżistenti għall-korrużjoni /… kontenitur li huwa infurrat minn ġewwa b'materjal reżistenti. NL In corrosiebestendige/… houder met corrosiebestendige binnenbekleding bewaren. PL Przechowywać w pojemniku odpornym na korozję / … o odpornej powłoce wewnętrznej. PL Przechowywać w pojemniku odpornym na korozję /… o odpornej powłoce wewnętrznej. PT Armazenar num recipiente resistente à corrosão/… com um revestimento interior resistente. RO Depozitați într-un recipient rezistent la coroziune/recipient din… cu dublură interioară rezistentă la coroziune. SK Uchovávajte v nádobe odolnej proti korózii/… nádobe s odolnou vnútornou vrstvou. RO A se depozita într-un recipient rezistent la coroziune/recipient din… cu dublură interioară rezistentă la coroziune. SK Uchovávajte v nádobe odolnej proti korózii/… nádobe s odolnou vnútornou vrstvou. SL Hraniti v posodi, odporni proti koroziji/…, z odporno notranjo oblogo. FI Varastoi syöpymättömässä/… säiliössä, jossa on kestävä sisävuoraus. SV Förvaras i korrosionsbeständig/… behållare med beständigt innerhölje. P407 Language BG Да се остави въздушно пространство между купчините/палетите. ES Dejar una separación entre los bloques/los palés de carga. CS Mezi stohy/paletami ponechte vzduchovou mezeru. DA Obevares med luftmellemrum mellem stakkene/pallerne. DE Luftspalt zwischen Stapeln/Paletten lassen. ET Jätta virnade/kaubaaluste vahele õhuvahe. EL Να υπάρχει κενό αέρος μεταξύ των σωρών/παλετών. EN Maintain air gap between stacks/pallets. FR Maintenir un intervalle d’air entre les piles/palettes. GA Coimeád bearna aeir idir chruacha/phailléid. HR Osigurati razmak između polica/paleta. IT Mantenere uno spazio libero tra gli scaffali/i pallet. LV Saglabāt gaisa spraugu starp krāvumiem/paletēm. LT Palikti oro tarpą tarp eilių/palečių. HU A rakatok/raklapok között térközt kell hagyni. MT Ħalli l-arja tgħaddi bejn l-imniezel/il-palits. NL Ruimte laten tussen stapels/pallets. PL Zachować szczelinę powietrzną pomiędzy stosami/paletami. PT Respeitar as distâncias mínimas entre pilhas/paletes. RO Păstrați un spațiu gol între stive/paleți. SK Medzi regálmi/paletami ponechajte vzduchovú medzeru. SL Ohraniti zračno režo med skladi/paletami. FI Jätä pinojen/kuormalavojen väliin ilmarako. SV Se till att det finns luft mellan staplar/pallar. P407 Language BG Да се остави въздушно пространство между купчините или палетите. ES Dejar un espacio de aire entre las pilas o bandejas. CS Mezi stohy nebo paletami ponechte vzduchovou mezeru. DA Opbevares med luftmellemrum mellem stakkene/pallerne. DE Luftspalt zwischen Stapeln oder Paletten lassen. ET Jätta virnade või kaubaaluste vahele õhuvahe. EL Να υπάρχει κενό αέρος μεταξύ των σωρών ή παλετών. EN Maintain air gap between stacks or pallets. FR Maintenir un intervalle d'air entre les piles ou les palettes. GA Coimeád bearna aeir idir cruacha nó idir pailléid. HR Osigurati razmak između polica ili paleta. IT Mantenere uno spazio libero tra gli scaffali o i pallet. LV Saglabāt gaisa spraugu starp krāvumiem vai paletēm. LT Palikti oro tarpą tarp eilių arba palečių. HU A rakatok vagy raklapok között térközt kell hagyni. MT Ħalli l-arja tgħaddi bejn l-imniezel jew il-palits. NL Ruimte laten tussen stapels of pallets. PL Zachować szczelinę powietrzną pomiędzy stosami lub paletami. PT Respeitar as distâncias mínimas entre pilhas ou paletes. RO Păstrați un spațiu gol între stive sau paleți. SK Medzi regálmi alebo paletami ponechajte vzduchovú medzeru. SL Ohraniti zračno režo med skladi ali paletami. FI Jätä pinojen tai kuormalavojen väliin ilmarako. SV Se till att det finns luft mellan staplar eller pallar. P410 Language BG Да се пази от пряка слънчева светлина. ES Proteger de la luz del sol. CS Chraňte před slunečním zářením. … 90 unchanged lines … SL Razsute količine, večje od … kg/… lbs, hraniti pri temperaturi do … oC/… oF. FI Säilytä yli … kg/…lbs painoinen irtotavara enintään … oC/…oF lämpötilassa. SV Bulkprodukter som väger mer än … kg/… lbs förvaras vid högst … oC/…oF. P420 Language BG Да се съхранява на разстояние от други материали. ES Almacenar alejado de otros materiales. CS Skladujte odděleně od ostatních materiálů. DA Må ikke opbevares i nærheden af andre materialer. DE Von anderen Materialien entfernt aufbewahren. ET Hoida eemal teistest materjalidest. EL Αποθηκεύεται μακριά από άλλα υλικά. EN Store away from other materials. FR Stocker à l’écart des autres matières. GA Stóráil glan ar ábhair eile. HR Skladištiti odvojeno od drugih materijala. IT Conservare lontano da altri materiali. LV Glabāt atsevišķi no citiem materiāliem. LT Laikyti atokiau nuo kitų medžiagų. HU Más anyagoktól távol tárolandó. MT Aħżen ‘l bogħod minn materjal ieħor. NL Gescheiden van ander materiaal bewaren. PL Przechowywać z dala od innych materiałów. PT Armazenar afastado de outros materiais. RO Depozitați departe de alte materiale. SK Uchovávajte oddelene od iných materiálov. SL Hraniti ločeno od drugih materialov. FI Varastoi erillään muista materiaaleista. SV Förvaras åtskilt från andra material. P420 Language BG Да се съхранява отделно. ES Almacenar separadamente. CS Skladujte odděleně. DA Opbevares separat. DE Getrennt aufbewahren. ET Hoida eraldi. EL Αποθηκεύεται χωριστά. EN Store separately. FR Stocker séparément. GA Stóráil as féin. HR Skladištiti odvojeno. IT Conservare separatamente. LV Glabāt atsevišķi. LT Laikyti atskirai. HU Elkülönítve tárolandó. MT Aħżen separatament. NL Gescheiden bewaren. PL Przechowywać oddzielnie. PT Armazenar separadamente. RO A se depozita separat. SK Skladujte jednotlivo. SL Hraniti ločeno. FI Varastoi erillään. SV Förvaras separat. P422 Language BG Съдържанието да се съхранява при… ES Almacenar el contenido en … CS Skladujte pod … … 188 unchanged lines … SL Odstraniti vsebino/posodo … FI Hävitä sisältö/pakkaus … SV Innehållet/behållaren lämnas till… P502 Language BG Обърнете се към производителя/доставчика за информация относно възстановяването/рециклирането ES Pedir información al fabricante o proveedor sobre su recuperación o reciclado CS Informujte se u výrobce nebo dodavatele o regeneraci nebo recyklaci DA Indhent oplysninger om genvinding/genanvendelse hos producenten/leverandøren DE Informationen zur Wiederverwendung/Wiederverwertung beim Hersteller/Lieferanten erfragen ET Hankida valmistajalt/tarnijalt teavet kemikaali taaskasutamise/ringlussevõtu kohta EL Απευθυνθείτε στον παραγωγό/προμηθευτή για την ανάκτηση/ανακύκλωση EN Refer to manufacturer/supplier for information on recovery/recycling FR Se reporter au fabricant/fournisseur pour des informations concernant la récupération/le recyclage GA Féach an fhaisnéis ón monaróir/soláthróir maidir le haisghabháil/athchúrsáil HR Pogledajte proizvođača/dobavljača zatražiti podatke o recikliranju/preradi IT Chiedere informazioni al produttore o fornitore per il recupero/riciclaggio LV Informācija par rekuperāciju/pārstrādi saņemama pie ražotāja/piegādātāja LT Kreiptis į gamintoją (tiekėją) informacijai apie šių medžiagų ar preparatų panaudojimą arba perdirbimą gauti HU A gyártó/szállító határozza meg a hasznosításra és újrafeldolgozásra vonatkozó információkat MT Irreferi għall-manifattur/fornitur rigward informazzjoni dwar l-irkupru/riċiklaġġ NL Raadpleeg fabrikant/leverancier voor informatie over terugwinning/recycling PL Przestrzegać wskazówek producenta lub dostawcy dotyczących odzysku lub wtórnego wykorzystania PT Solicitar ao fabricante/fornecedor informações relativas à recuperação/reciclagem RO Adresați-vă producătorului pentru informații privind recuperarea/reciclarea SK Informujte sa u výrobcu alebo dodávateľa o regenerácii alebo recyklácii SL Za podatke glede obnovitve/reciklaže se obrnite na proizvajalca/dobavitelja FI Hanki valmistajalta/toimittajalta tietoja uudelleenkäytöstä/kierrätyksestä SV Rådfråga tillverkare/leverantör om återvinning/återanvändning P502 Language BG Обърнете се към производителя или доставчика за информация относно оползотворяването или рециклирането. ES Pedir información al fabricante o proveedor sobre la recuperación o el reciclado. CS Informujte se u výrobce nebo dodavatele o regeneraci nebo recyklaci. DA Indhent oplysninger om genindvinding/genanvendelse hos fabrikanten/leverandøren. DE Informationen zur Wiederverwendung oder Wiederverwertung beim Hersteller oder Lieferanten erfragen. ET Hankida valmistajalt või tarnijalt teavet kemikaali taaskasutamise või ringlussevõtu kohta. EL Ανατρέξτε στον παρασκευαστή ή τον προμηθευτή για πληροφορίες όσον αφορά την ανάκτηση ή την ανακύκλωση. EN Refer to manufacturer or supplier for information on recovery or recycling. FR Consulter le fabricant ou le fournisseur pour des informations relatives à la récupération ou au recyclage. GA Téigh i dteagmháil leis an monaróir nó leis an soláthróir chun faisnéis a fháil faoi aisghabháil nó athchúrsáil. HR Za informacije o oporabi ili recikliranju obratiti se proizvođaču ili dobavljaču. IT Chiedere informazioni al produttore o fornitore per il recupero o il riciclaggio. LV Informācija par rekuperāciju vai pārstrādi saņemama pie ražotāja vai piegādātāja. LT Kreiptis į gamintoją arba tiekėją dėl informacijos apie surinkimą arba recirkuliavimą. HU A gyártó vagy a szállító határozza meg a hasznosításra vagy az újrafeldolgozásra vonatkozó információkat. MT Irreferi għall-manifattur jew il-fornitur għal informazzjoni dwar l-irkupru jew ir-riċiklaġġ. NL Raadpleeg fabrikant of leverancier voor informatie over terugwinning of recycling. PL Przestrzegać wskazówek producenta lub dostawcy dotyczących odzysku lub wtórnego wykorzystania. PT Solicitar ao fabricante ou fornecedor informações relativas à recuperação ou reciclagem. RO Adresați-vă producătorului sau furnizorului pentru informații privind recuperarea/reciclarea. SK Obráťte sa na výrobcu alebo dodávateľa s požiadavkou o informácie týkajúce sa obnovenia alebo recyklácie. SL Za podatke glede predelave ali reciklaže se obrnite na proizvajalca ali dobavitelja. FI Hanki valmistajalta tai toimittajalta tietoja uudelleenkäytöstä tai kierrätyksestä. SV Rådfråga tillverkare eller leverantör om återvinning eller återanvändning.

MODIFIED +29 −10 Annex V HAZARD PICTOGRAMS

applies from: unchanged

In section 2.2, the description under GHS05 for skin corrosion was changed from listing hazard categories 1A, 1B, 1C to describing hazard category 1 with sub-categories 1A, 1B, 1C.

Cited: Annex V, v2

text before / after

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ANNEX V HAZARD PICTOGRAMS INTRODUCTION The hazard pictograms for each hazard class, differentiation of a hazard class and hazard category shall satisfy the provisions of this Annex and Annex I, section 1.2 and conform in terms of symbols and general format, to the specimens shown. 1. PART 1: PHYSICAL HAZARDS 1.1. Symbol: exploding bomb Pictogram (1) Hazard class and hazard category (2) GHS01 Section 2.1 Unstable explosives Explosives of Divisions 1.1, 1.2, 1.3, 1.4 Section 2.8 Self reactive substances and mixtures, Types A, B Section 2.15 Organic peroxides, Types A, B 1.2. Symbol: flame Pictogram (1) Hazard class and hazard category (2) GHS02 Section 2.2 Flammable gases, hazard category 1 Section 2.3 Aerosols, hazard categories 1, 2 Section 2.6 Flammable liquids, hazard categories 1, 2, 3 Section 2.7 Flammable solids, hazard categories 1, 2 Section 2.8 Self-reactive substances and mixtures, Types B, C, D, E, F Section 2.9 Pyrophoric liquids, hazard category 1 Section 2.10 Pyrophoric solids, hazard category 1 Section 2.11 Self-heating substances and mixtures, hazard categories 1, 2 Section 2.12 Substances and mixtures, which in contact with water, emit flammable gases, hazard categories 1, 2, 3 Section 2.15 Organic peroxides, Types B, C, D, E, F 1.3. Symbol: flame over circle Pictogram (1) Hazard class and hazard category (2) GHS03 Section 2.4 Oxidising gases, hazard category 1 Section 2.13 Oxidising liquids, hazard categories 1, 2, 3 Section 2.14 Oxidising solids, hazard categories 1, 2, 3 1.4. Symbol: gas cylinder Pictogram (1) Hazard class and hazard category (2) GHS04 Section 2.5 Gases under pressure: Compressed gases; Liquefied gases; Refrigerated liquefied gases; Dissolved gases 1.5. Symbol: corrosion Pictogram (1) Hazard class and hazard category (2) GHS05 Section 2.16 Corrosive to metals, hazard category 1 1.6. A pictogram is not required for the following physical hazard classes and hazard categories: Section 2.1: Explosives of Division 1.5 Section 2.1: Explosives of Division 1.6 Section 2.2: Flammable gases, hazard Category 2 Section 2.3: Aerosols, hazard Category 3 Section 2.8: Self-reactive substances and mixtures, Type G Section 2.15: Organic peroxides, Type G 2. PART 2: HEALTH HAZARDS 2.1. Symbol: skull and crossbones Pictogram (1) Hazard class and hazard category (2) GHS06 Section 3.1 Acute toxicity (oral, dermal, inhalation), hazard categories 1, 2, 3 2.2. Symbol: corrosion Pictogram (1) Hazard class and hazard category (2) GHS05 Section 3.2 Skin corrosion, hazard categories category 1 and sub-categories 1A, 1B, 1C Section 3.3 Serious eye damage, hazard category 1 2.3. Symbol: exclamation mark Pictogram (1) Hazard class and hazard category (2) GHS07 Section 3.1 Acute toxicity (oral, dermal, inhalation), hazard category 4 Section 3.2 Skin irritation, hazard category 2 Section 3.3 Eye irritation, hazard category 2 Section 3.4 Skin sensitisation, hazard categories 1, 1A, 1B Section 3.8 Specific Target Organ Toxicity — Single exposure, hazard category 3 Respiratory tract irritation Narcotic effects 2.4. Symbol: health hazard Pictogram (1) Hazard class and hazard category (2) GHS08 Section 3.4 Respiratory sensitisation, hazard categories 1, 1A, 1B Section 3.5 Germ cell mutagenicity, hazard categories 1A, 1B, 2 Section 3.6 Carcinogenicity, hazard categories 1A, 1B, 2 Section 3.7 Reproductive toxicity, hazard categories 1A, 1B, 2 Section 3.8 Specific Target Organ Toxicity — Single exposure, hazard categories 1, 2 Section 3.9 Specific Target Organ Toxicity — Repeated exposure, hazard categories 1, 2 Section 3.10 Aspiration hazard, hazard category 1 2.5. A pictogram is not required for the following health hazard categories: Section 3.7: Reproductive toxicity, Effects on or via lactation, additional hazard category 3. PART 3: ENVIRONMENTAL HAZARDS 3.1. Symbol: environment Pictogram (1) Hazard class and hazard category (2) GHS09 Section 4.1 Hazardous to the aquatic environment Acute hazard category: Acute 1 Long-term hazard categories: Chronic 1, Chronic 2 A pictogram is not required for the following environmental hazard classes and hazard categories: Section 4.1: Hazardous to the aquatic environment — Long-term hazard categories: Chronic 3, Chronic 4. 4. PART 4: ADDITIONAL HAZARDS 4.1. Symbol: exclamation mark Pictogram Hazard class and hazard category (1) (2) GHS07 Section 5.1 Hazardous to the ozone layer, hazard category 1

MODIFIED +14,467 −6,422 Annex VI Harmonised classification and labelling for certain hazardous substances

applies from: unchanged

In the Hazard Class and Category Code table, a new entry "Skin Corr. 1" has been added ahead of the existing "Skin Corr. 1A" line under skin corrosion/irritation.

Note U has been expanded to list the specific codes Press. Gas (Comp.), Press. Gas (Liq.), Press. Gas (Ref. Liq.) and Press. Gas (Diss.), and to add a statement that aerosols are not to be classified as gases under pressure, with a cross-reference to Annex I, Part 2, Section 2.3.2.1, Note 2.

The text of Part 3 in both versions is cut off before the comparison could be completed, so only the changes visible within the shown portion, and not any further differences that may exist later in Part 3, can be described here.

Cited: Annex VI, v2 · Annex VI, v1

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02008R1272-2017060102008R1272-20180301

compared line by line: this provision is too large to compare word by word, so a marked line is a line that changed somewhere

ANNEX VI Harmonised classification and labelling for certain hazardous substances Part 1 of this Annex provides an introduction to the list of harmonised classification and labelling, including information listed for each entry and related classifications and hazard statements in Table 3. … 78 unchanged lines … Acute Tox. 2 Acute Tox. 3 Acute Tox. 4 Skin corrosion/irritation Skin Corr. 1A Skin corrosion/irritation Skin Corr. 1 Skin Corr. 1A Skin Corr. 1B Skin Corr. 1C Skin Irrit. 2 … 99 unchanged lines … Note T: This substance may be marketed in a form which does not have the physical hazards as indicated by the classification in the entry in Part 3. If the results of the relevant method or methods in accordance with Part 2 of Annex I of this Regulation show that the specific form of substance marketed does not exhibit this physical property or these physical hazards, the substance shall be classified in accordance with the result or results of this test or these tests. Relevant information, including reference to the relevant test method(s) shall be included in the safety data sheet. Note U (Table 3.1): When put on the market gases have to be classified as Gases under pressure, in one of the groups compressed gas, liquefied gas, refrigerated liquefied gas or dissolved gas. The group depends on the physical state in which the gas is packaged and therefore has to be assigned case by case. When put on the market gases have to be classified as Gases under pressure, in one of the groups compressed gas, liquefied gas, refrigerated liquefied gas or dissolved gas. The group depends on the physical state in which the gas is packaged and therefore has to be assigned case by case. The following codes are assigned: Press. Gas (Comp.) Press. Gas (Liq.) Press. Gas (Ref. Liq.) Press. Gas (Diss.) Aerosols shall not be classified as gases under pressure (See Annex I, Part 2, Section 2.3.2.1, Note 2). 1.1.3.2. Notes relating to the classification and labelling of mixtures Note 1: The concentration stated or, in the absence of such concentrations, the generic concentrations set out in this Regulation are the percentages by weight of the metallic element calculated with reference to the total weight of the mixture. … 497 unchanged lines … H318 Repr. 1B; H360Df: C ≥ 9 % Repr. 1B; H360D: 6,5 % ≤ C < 9 % Eye Dam. 1; H318: C ≥ 22 % Eye Irrit. 2; H319: 14 % ≤ C < 22 % 006-001-00-2 carbon monoxide 211-128-3 630-08-0 Flam. Gas 1 Eye Irrit. 2; H319: 14 % ≤ C < 22 % 005-020-00-3 disodium octaborate anhydrous; [1] disodium octaborate tetrahydrate [2] 234-541-0 [1] 234-541-0 [2] 12008-41-2 [1] 12280-03-4 [2] Repr. 1B H360FD GHS08 Dgr H360FD 006-001-00-2 carbon monoxide 211-128-3 630-08-0 Flam. Gas 1 Press. Gas Repr. 1A Acute Tox. 3 * … 380 unchanged lines … H411 GHS07 GHS09 Wng H302 H411 006-035-00-8 pirimicarb (ISO); 5,6-dimethyl-2-dimethylamino-pyrimidin-4-yl N,N-dimethylcarbamate 245-430-1 23103-98-2 Acute Tox. 3 * Aquatic Acute 1 Aquatic Chronic 1 H301 H411 006-035-00-8 pirimicarb (ISO); 2-(dimethylamino)-5,6-dimethylpyrimidin-4-yl dimethylcarbamate 245-430-1 23103-98-2 Carc. 2 Acute Tox. 3 Acute Tox. 3 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 H351 H331 H301 H317 H400 H410 GHS06 H410 GHS08 GHS06 GHS09 Dgr H301 H410 006-036-00-3 benzthiazuron (ISO); Dgr H351 H331 H301 H317 H410 M = 10 M = 100 006-036-00-3 benzthiazuron (ISO); 1-benzothiazol-2-yl-3-methylurea 217-685-9 1929-88-0 Acute Tox. 4 * H302 GHS07 Wng H302 006-037-00-9 promecarb (ISO); 3-isopropyl-5-methylphenyl N-methylcarbamate 220-113-0 2631-37-0 Acute Tox. 3 * … 1,602 unchanged lines … H315 H318 H412 014-044-00-3 3-[(4'-acetoxy-3'-methoxyphenyl) propyl]trimethoxysilane 433-050-0 — Aquatic Chronic 2 H411 GHS09 H411 014-045-00-9 magnesium sodium fluoride silicate 442-650-1 — STOT RE 2 * H373** GHS08 Wng H373** 015-001-00-1 white phosphorus 231-768-7 12185-10-3 Pyr. Sol. 1 Wng H373** 014-046-00-4 e-glass microfibres of representative composition; [Calcium-aluminium-silicate fibres with random orientation with the following representative composition (% given by weight): SiO2 50,0-56,0 %, Al2O3 13,0-16,0 %, B2O3 5,8-10,0 %, Na2O < 0,6 %, K2O < 0,4 %, CaO 15,0-24,0 %, MgO < 5,5 %, Fe2O3 < 0,5 %, F2 < 1,0 %. Process: typically produced by flame attenuationand rotary process. (Additional individual elements may be present at low levels; the process list does not preclude innovation).] — — Carc. 1B H350i GHS08 Dgr H350i A 014-047-00-X glass microfibres of representative composition; [Calcium-aluminium-silicate fibres with random orientation with the following composition (% given by weight): SiO2 55,0-60,0 %, Al2O3 4,0-7,0 %, B2O3 8,0-11,0 %, ZrO2 0,0-4,0 %, Na2O 9,5-13,5 %, K2O 0,0-4,0 %, CaO 1,0-5,0 %, MgO 0,0-2,0 %, Fe2O3 < 0,2 %, ZnO 2,0-5,0 %, BaO 3,0-6,0 %, F2 < 1,0 %. Process: typically produced by flame attenuation and rotary process. (Additional individual elements may be present at low levels; the process list does not preclude innovation).] — — Carc. 2 H351 (inhalation) GHS08 Wng H351 (inhalation) A 015-001-00-1 white phosphorus 231-768-7 12185-10-3 Pyr. Sol. 1 Acute Tox. 2 * Acute Tox. 2 * Skin Corr. 1A … 4,832 unchanged lines … Wng H302 H400 H410 029-002-00-X dicopper oxide; copper (I) oxide 215-270-7 1317-39-1 Acute Tox. 4 * copper (I) oxide 215-270-7 1317-39-1 Acute Tox. 4 Acute Tox. 4 Eye Dam. 1 Aquatic Acute 1 Aquatic Chronic 1 H302 Aquatic Chronic 1 H332 H302 H318 H400 H410 GHS07 GHS05 GHS09 Wng H302 H410 029-003-00-5 Naphthenic acids, copper salts; Dgr H332 H302 H318 H410 M = 100 029-003-00-5 Naphthenic acids, copper salts; copper naphthenate 215-657-0 1338-02-9 Flam. Liq. 3 Acute Tox. 4 * Aquatic Acute 1 … 47 unchanged lines … H411 GHS08 GHS09 Wng H373** H411 030-001-00-1 zinc powder — zinc dust (pyrophoric) 231-175-3 7440-66-6 Water-react. 1 H411 029-015-00-0 copper thiocyanate 214-183-1 1111-67-7 Aquatic Acute 1 Aquatic Chronic 1 H400 H410 GHS09 Wng H410 EUH032 M = 10 029-016-00-6 copper(II) oxide 215-269-1 1317-38-0 Aquatic Acute 1 Aquatic Chronic 1 H400 H410 GHS09 Wng H410 M = 100 029-017-00-1 dicopper chloride trihydroxide 215-572-9 1332-65-6 Acute Tox. 4 Acute Tox. 3 Aquatic Acute 1 Aquatic Chronic 1 H332 H301 H400 H410 GHS06 GHS09 Dgr H332 H301 H410 M = 10 029-018-00-7 tetracopper hexahydroxide sulphate; [1] tetracopper hexahydroxide sulphate hydrate [2] 215-582-3 [1] 215-582-3 [2] 1333-22-8 [1] 12527-76-3 [2] Acute Tox. 4 Aquatic Acute 1 Aquatic Chronic 1 H302 H400 H410 GHS07 GHS09 Wng H302 H410 M = 10 029-019-01-X copper flakes (coated with aliphatic acid) — — Acute Tox. 3 Acute Tox. 4 Eye Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 H331 H302 H319 H400 H410 GHS06 GHS09 Dgr H331 H302 H319 H410 M = 10 029-020-00-8 copper(II) carbonate--copper(II) hydroxide (1:1) 235-113-6 12069-69-1 Acute Tox. 4 Acute Tox. 4 Eye Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 H332 H302 H319 H400 H410 GHS07 GHS09 Wng H332 H302 H319 H410 M = 10 029-021-00-3 copper dihydroxide; copper(II) hydroxide 243-815-9 20427-59-2 Acute Tox. 2 Acute Tox. 4 Eye Dam. 1 Aquatic Acute 1 Aquatic Chronic 1 H330 H302 H318 H400 H410 GHS06 GHS05 GHS09 Dgr H330 H302 H318 H410 M = 10 029-022-00-9 bordeaux mixture; reaction products of copper sulphate with calcium dihydroxide — 8011-63-0 Acute Tox. 4 Eye Dam. 1 Aquatic Acute 1 Aquatic Chronic 1 H332 H318 H400 H410 GHS07 GHS05 GHS09 Dgr H332 H318 H410 M = 10 029-023-00-4 copper sulphate pentahydrate 231-847-6 7758-99-8 Acute Tox. 4 Eye Dam. 1 Aquatic Acute 1 Aquatic Chronic 1 H302 H318 H400 H410 GHS07 GHS05 GHS09 Dgr H302 H318 H410 M = 10 030-001-00-1 zinc powder — zinc dust (pyrophoric) 231-175-3 7440-66-6 Water-react. 1 Pyr. Sol. 1 Aquatic Acute 1 Aquatic Chronic 1 H260 … 1,778 unchanged lines … GHS09 Wng H302 H373** H411 092-001-00-8 uranium 231-170-6 7440-61-1 Acute Tox. 2 * H411 082-013-00-1 lead powder; [particle diameter < 1 mm] 231-100-4 7439-92-1 Repr. 1A Lact. H360FD H362 GHS08 Dgr H360FD H362 Repr. 1A; H360D: C ≥ 0,03 % 082-014-00-7 lead massive: [particle diameter ≥ 1 mm] 231-100-4 7439-92-1 Repr. 1A Lact. H360FD H362 GHS08 Dgr H360FD H362 092-001-00-8 uranium 231-170-6 7440-61-1 Acute Tox. 2 * Acute Tox. 2 * STOT RE 2 * Aquatic Chronic 4 H330 … 1,215 unchanged lines … H315 H336 602-020-00-0 1,2-dichloropropane; propylene dichloride 201-152-2 78-87-5 Flam. Liq. 2 Acute Tox. 4 * Acute Tox. 4 * H225 Carc. 1B Acute Tox. 4* Acute Tox. 4* H225 H350 H332 H302 GHS02 GHS08 GHS07 Dgr H225 H350 H332 H302 602-021-00-6 1,2-dibromo-3-chloropropane 202-479-3 96-12-8 Carc. 1B Muta. 1B … 195 unchanged lines … H314 H317 H411 602-033-00-1 chlorobenzene 203-628-5 108-90-7 Flam. Liq. 3 Acute Tox. 4 * Acute Tox. 4 Skin Irrit. 2 Aquatic Chronic 2 H226 H332 H315 H411 GHS02 GHS07 GHS09 Wng H226 H332 H411 * 602-034-00-7 1,2-dichlorobenzene; H315 H411 602-034-00-7 1,2-dichlorobenzene; o-dichlorobenzene 202-425-9 95-50-1 Acute Tox. 4 * Eye Irrit. 2 STOT SE 3 … 1,522 unchanged lines … H335 H315 H412 STOT SE 3; H335: C ≥ 10 % 603-055-00-4 propylene oxide; 1,2-epoxypropane; methyloxirane 200-879-2 75-56-9 Flam. Liq. 1 1,2-epoxypropane; methyloxirane 200-879-2 75-56-9 Flam. Liq. 1 Carc. 1B Muta. 1B Acute Tox. 4 * Acute Tox. 4 * Acute Tox. 4 * Eye Irrit. 2 Acute Tox. 3 Acute Tox. 3 Acute Tox. 4 STOT SE 3 Skin Irrit. 2 H224 Eye Irrit. 2 H224 H350 H340 H332 H312 H331 H311 H302 H319 H335 H315 GHS02 H319 GHS02 GHS08 GHS07 GHS06 Dgr H224 H350 H340 H332 H312 H331 H311 H302 H319 H335 H315 603-056-00-X [(p-tolyloxy)methyl]oxirane; [1] H319 603-056-00-X [(p-tolyloxy)methyl]oxirane; [1] [(m-tolyloxy)methyl]oxirane; [2] 2,3-epoxypropyl o-tolyl ether; [3] [(tolyloxy)methyl]oxirane; … 1,671 unchanged lines … H335 H315 H318 604-030-00-0 bisphenol A; 4,4’-isopropylidenediphenol 201-245-8 80-05-7 Repr. 2 4,4′-isopropylidenediphenol 201-245-8 80-05-7 Repr. 1B STOT SE 3 Eye Dam. 1 Skin Sens. 1 H361f*** Skin Sens. 1 H360F H335 H318 H317 GHS05 GHS08 GHS07 Dgr H361f*** H317 GHS08 GHS05 GHS07 Dgr H360F H335 H318 H317 604-031-00-6 guaiacol 201-964-7 90-05-1 Acute Tox. 4 * … 395 unchanged lines … H410 GHS09 Wng H362 H410 M = 100 M = 1000 604-092-00-9 phenol, dodecyl-, branched [1]; phenol, 2-dodecyl-, branched; phenol, 3-dodecyl-, branched; phenol, 4-dodecyl-, branched; phenol, (tetrapropenyl) derivatives [2] 310-154-3 [1] 121158-58-5 [1] 74499-35-7 [2] Skin Corr. 1C Aquatic Acute 1 Aquatic Chronic 1 H314 M = 1000 604-092-00-9 phenol, dodecyl-, branched; [1] phenol, 2-dodecyl-, branched; [2] phenol, 3-dodecyl-, branched; [3] phenol, 4-dodecyl-, branched; [4] phenol, (tetrapropenyl) derivatives [5] 310-154-3 [1] [2] [3] [4] [5] 121158-58-5 [1] [2] [3] 210555-94-5 [4] 74499-35-7 [5] Repr. 1B Skin Corr. 1C Eye Dam. 1 Aquatic Acute 1 Aquatic Chronic 1 H360F H314 H318 H400 H410 GHS05 H410 GHS08 GHS05 GHS09 Dgr H314 H410 M = 10 M = 10 605-001-00-5 formaldehyde …% 200-001-8 50-00-0 Carc. 1B Dgr H360F H314 H410 M = 10 M = 10 605-001-00-5 formaldehyde …% 200-001-8 50-00-0 Carc. 1B Muta. 2 Acute Tox. 3* Acute Tox. 3* … 143 unchanged lines … o-chlorobenzaldehyde 201-956-3 89-98-5 Skin Corr. 1B H314 GHS05 Dgr H314 605-012-00-5 benzaldehyde 202-860-4 100-52-7 Acute Tox. 4 * H302 GHS07 Wng H302 605-013-00-0 chloralose (INN); (R)-1,2-O-(2,2,2-trichloroethylidene)-α-D-glucofuranose; glucochloralose; anhydroglucochloral 240-016-7 15879-93-3 Acute Tox. 4 * Acute Tox. 4 * H332 H302 GHS07 Wng H332 H302 605-014-00-6 chloral hydrate; (R)-1,2-O-(2,2,2-trichloroethylidene)-α-D-glucofuranose; glucochloralose; anhydroglucochloral 240-016-7 15879-93-3 Acute Tox. 4* Acute Tox. 3 STOT SE 3 Aquatic Acute 1 Aquatic Chronic 1 H332 H301 H336 H400 H410 GHS06 GHS09 Dgr H332 H301 H336 H410 M = 10 M = 10 C 605-014-00-6 chloral hydrate; 2,2,2-trichloroethane-1,1-diol 206-117-5 302-17-0 Acute Tox. 3 * Eye Irrit. 2 Skin Irrit. 2 H301 … 53 unchanged lines … Dgr H350 H341 H302 605-021-00-4 formaldehyde, reaction products with butylphenol 294-145-9 91673-30-2 Skin Sens. 1 H317 GHS07 Wng H317 605-022-00-X glutaral; glutaraldehyde; 1,5-pentanedial 203-856-5 111-30-8 Acute Tox. 3 * Acute Tox. 3 * Wng H317 605-022-00-X glutaral; glutaraldehyde; 1,5-pentanedial 203-856-5 111-30-8 Acute Tox. 2 Acute Tox. 3 STOT SE 3 Skin Corr. 1B Resp. Sens. 1 Skin Sens. 1 Aquatic Acute 1 H331 Skin Sens. 1A Aquatic Acute 1 Aquatic Chronic 2 H330 H301 H335 H314 H334 H317 H400 GHS06 H400 H411 GHS06 GHS05 GHS08 GHS05 GHS09 Dgr H331 Dgr H330 H301 H335 H314 H334 H317 H400 * Skin Corr. 1B; H314: C ≥ 10 % Skin Irrit. 2; H315: 0,5 % ≤ C < 10 % Eye Dam.; H318: 2 % ≤ C < 10 % Eye Irrit. 2; H319: 0,5 % ≤ C < 2 % STOT SE; H335: C ≥ 0,5 % Skin Sens. 1; H317: C ≥ 0,5 % 605-023-00-5 5-chloro-2-(4-chlorophenoxy)phenol 429-290-0 3380-30-1 Eye Dam. 1 H410 EUH071 STOT SE 3; H335: 0,5 % ≤ C < 5 % M = 1 605-023-00-5 5-chloro-2-(4-chlorophenoxy)phenol 429-290-0 3380-30-1 Eye Dam. 1 Aquatic Acute 1 Aquatic Chronic 1 H318 H400 … 99 unchanged lines … GHS07 Dgr H302 H318 H317 606-001-00-8 acetone; H317 605-040-00-8 hydroxyisohexyl 3-cyclohexene carboxaldehyde (INCI); reaction mass of 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde and 3-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde; [1] 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde; [2] 3-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde [3] - [1] 250-863-4 [2] 257-187-9 [3] 130066-44-3 [1] 31906-04-4 [2] 51414-25-6 [3] Skin Sens. 1A H317 GHS07 Wng H317 606-001-00-8 acetone; propan-2-one; propanone 200-662-2 67-64-1 Flam. Liq. 2 Eye Irrit. 2 … 106 unchanged lines … H335 H315 H400 M=10 606-014-00-9 chlorophacinone (ISO); 2-(2-(4-chlorophenyl)phenylacetyl)indan-1,3-dione 223-003-0 3691-35-8 Acute Tox. 1 Acute Tox. 2 * Acute Tox. 3 * 2-[(4-chlorophenyl)(phenyl)acetyl]-1H-indene-1,3(2H)-dione 223-003-0 3691-35-8 Repr. 1B Acute Tox. 1 Acute Tox. 1 Acute Tox. 1 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1 H310 Aquatic Chronic 1 H360D H330 H310 H300 H331 H372 ** H372 (blood) H400 H410 GHS06 GHS08 H410 GHS08 GHS06 GHS09 Dgr H310 Dgr H360D H330 H310 H300 H331 H372 ** H410 606-016-00-X pindone (ISO); H372 (blood) H410 Repr. 1B; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 0,1 % STOT RE 2; H373 (blood): 0,01 % ≤ C < 0,1 % M = 1 M = 1 606-016-00-X pindone (ISO); 2-pivaloylindan-1,3-dione 201-462-8 83-26-1 Acute Tox. 3 * STOT RE 1 Aquatic Acute 1 … 50 unchanged lines … GHS07 Wng H226 H319 H335 STOT SE 3; H335: C ≥ 10 % 606-021-00-7 N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone 212-828-1 872-50-4 Repr. 1B Eye Irrit. 2 H335 STOT SE 3; H335: C ≥ 10 % 606-021-00-7 N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone 212-828-1 872-50-4 Repr. 1B STOT SE 3 Skin Irrit. 2 H360D*** H319 Skin Irrit. 2 Eye Irrit. 2 H360D*** H335 H315 GHS08 H315 H319 GHS08 GHS07 Dgr H360D*** H319 H335 H315 Repr. 1B; H360D: C ≥ 5 % STOT SE 3; H335: C ≥ 10 % 606-022-00-2 1-phenyl-3-pyrazolidone 202-155-1 92-43-3 Acute Tox. 4 * H315 H319 STOT SE 3; H335: C ≥ 10 % 606-022-00-2 1-phenyl-3-pyrazolidone 202-155-1 92-43-3 Acute Tox. 4 * Aquatic Chronic 2 H302 H411 GHS07 GHS09 … 1,310 unchanged lines … H312 H319 H335 H315 607-056-00-0 warfarin (ISO); [1] H315 607-056-00-0 warfarin (ISO); 4-hydroxy-3-(3-oxo-1-phenylbutyl)-2H-chromen-2-one; [1] (S)-4-hydroxy-3-(3-oxo-1-phenylbutyl)-2-benzopyrone; [2] (R)-4-hydroxy-3-(3-oxo-1-phenylbutyl)-2-benzopyrone [3] 201-377-6 [1] 226-907-3 [2] 226-908-9 [3] 81-81-2 [1] 5543-57-7 [2] 5543-58-8 [3] Repr. 1A (R)-4-hydroxy-3-(3-oxo-1-phenylbutyl)-2-benzopyrone [3] 201-377-6 [1] 226-907-3 [2] 226-908-9 [3] 81-81-2 [1] 5543-57-7 [2] 5543-58-8 [3] Repr. 1A Acute Tox. 1 Acute Tox. 1 Acute Tox. 2 STOT RE 1 Aquatic Chronic 3 H360D *** H372 ** H412 GHS08 Dgr H360D *** H372 ** H412 607-057-00-6 coumachlor (ISO); Aquatic Chronic 2 H360D H330 H310 H300 H372 (blood) H411 GHS08 GHS06 GHS09 Dgr H360D H330 H310 H300 H372 (blood) H411 Repr. 1A; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 0,5 % STOT RE 2; H373 (blood): 0,05 % ≤ C < 0,5 % 607-057-00-6 coumachlor (ISO); 3-[1-(4-chlorophenyl)-3-oxobutyl]-4-hydroxycoumarin 201-378-1 81-82-3 STOT RE 2 * Aquatic Chronic 3 H373 ** H412 GHS08 Wng H373 ** H412 607-058-00-1 coumafuryl (ISO); fumarin; (RS)-3-(1-(2-furyl)-3-oxobutyl)4-hydroxycoumarin; 4-hydroxy-3-[3-oxo-1-(2-furyl) butyl]coumarin 204-195-5 117-52-2 Acute Tox. 3 * STOT RE 1 Aquatic Chronic 3 H301 H372 ** H412 GHS06 GHS08 Dgr H301 H372 ** H412 607-059-00-7 coumatetralyl; 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naphthyl)coumarin 227-424-0 5836-29-3 Acute Tox. 1 Acute Tox. 2 * H412 607-059-00-7 coumatetralyl (ISO); 4-hydroxy-3-(1,2,3,4-tetrahydro-1-naphthyl)coumarin 227-424-0 5836-29-3 Repr. 1B Acute Tox. 2 Acute Tox. 3 Acute Tox. 2 STOT RE 1 Aquatic Chronic 3 H310 Aquatic Chronic 1 H360D H330 H311 H300 H372 ** H412 GHS06 GHS08 Dgr H310 H372 (blood) H410 GHS08 GHS06 GHS09 Dgr H360D H330 H311 H300 H372 ** H412 607-060-00-2 dicoumarol; H372 (blood) H410 Repr. 1B; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 1,0 % STOT RE 2; H373 (blood) 0,1 % ≤ C < 1,0 % M = 10 607-060-00-2 dicoumarol; 4,4'-dihydroxy-3,3'-methylenebis(2H-chromen-2-one) 200-632-9 66-76-2 STOT RE 1 Acute Tox. 4 * Aquatic Chronic 2 H372 ** … 921 unchanged lines … GHS09 Wng H302 H315 H410 607-157-00-X 3-(3-biphenyl-4-yl-1,2,3,4-tetrahydro-1-naphthyl)-4-hydroxycoumarin; difenacoum 259-978-4 56073-07-5 Acute Tox. 2 * H410 607-157-00-X difenacoum (ISO); 3-(3-biphenyl-4-yl-1,2,3,4-tetrahydro-1-naphthyl)-4-hydroxycoumarin 259-978-4 56073-07-5 Repr. 1B Acute Tox. 1 Acute Tox. 1 Acute Tox. 1 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1 H300 H372 ** Aquatic Chronic 1 H360D H330 H310 H300 H372 (blood) H400 H410 GHS06 GHS08 H410 GHS08 GHS06 GHS09 Dgr H300 H372 ** H410 607-158-00-5 sodium salt of chloroacetic acid; Dgr H360D H330 H310 H300 H372 (blood) H410 Repr. 1B; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 0,02 % STOT RE 2; H373 (blood): 0,002 % ≤ C < 0,02 % M = 10 M = 10 607-158-00-5 sodium salt of chloroacetic acid; sodium chloroacetate 223-498-3 3926-62-3 Acute Tox. 3 * Skin Irrit. 2 Aquatic Acute 1 H301 … 84 unchanged lines … GHS09 Wng H312 H302 H410 607-172-00-1 4-hydroxy-3-(3-(4'-bromo-4-biphenylyl)-1,2,3,4-tetrahydro-1-naphthyl)coumarin; brodifacoum 259-980-5 56073-10-0 Acute Tox. 1 Acute Tox. 2 * H410 607-172-00-1 brodifacoum (ISO); 4-hydroxy-3-(3-(4′-bromo-4-biphenylyl)-1,2,3,4-tetrahydro-1-naphthyl)coumarin 259-980-5 56073-10-0 Repr. 1A Acute Tox. 1 Acute Tox. 1 Acute Tox. 1 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1 H310 Aquatic Chronic 1 H360D H330 H310 H300 H372 ** H372 (blood) H400 H410 GHS06 GHS08 H410 GHS08 GHS06 GHS09 Dgr H310 Dgr H360D H330 H310 H300 H372 ** H410 607-173-00-7 dimethyl (3-methyl-4-(5-nitro-3-ethoxycarbonyl-2-thienyl)azo)phenylnitrilodipropionate 400-460-6 — Skin Sens. 1 H372 (blood) H410 Repr. 1A; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 0,02 % STOT RE 2; H373 (blood): 0,002 % ≤ C < 0,02 % M = 10 M = 10 607-173-00-7 dimethyl (3-methyl-4-(5-nitro-3-ethoxycarbonyl-2-thienyl)azo)phenylnitrilodipropionate 400-460-6 — Skin Sens. 1 Aquatic Chronic 3 H317 H412 GHS07 Wng H317 … 1,268 unchanged lines … H411 GHS07 GHS09 Wng H317 H411 607-375-00-5 reaction mass of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin; trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin 421-960-0 90035-08-8 Acute Tox. 2 * H411 607-375-00-5 flocoumafen (ISO); reaction mass of: cis-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin and trans-4-hydroxy-3-(1,2,3,4-tetrahydro-3-(4-(4-trifluoromethylbenzyloxy)phenyl)-1-naphthyl)coumarin 421-960-0 90035-08-8 Repr. 1B Acute Tox. 1 Acute Tox. 2 * Acute Tox. 1 Acute Tox. 1 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1 H330 Aquatic Chronic 1 H360D H330 H310 H300 H372 ** H372 (blood) H400 H410 GHS06 GHS08 H410 GHS08 GHS06 GHS09 Dgr H330 Dgr H360D H330 H310 H300 H372 ** H410 607-376-00-0 benzyl 2,4-dibromobutanoate 420-710-8 23085-60-1 Repr. 2 H372 (blood) H410 Repr. 1B; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 0,05 % STOT RE 2; H373 (blood): 0,005 % ≤ C < 0,05 % M = 10 M = 10 607-376-00-0 benzyl 2,4-dibromobutanoate 420-710-8 23085-60-1 Repr. 2 Skin Irrit. 2 Skin Sens. 1 Aquatic Acute 1 … 1,277 unchanged lines … H302 H410 M=100 607-622-00-7 2-ethylhexyl-2-ethylhexanoate 231-057-1 7425-14-1 Repr. 2 H361d*** GHS08 Wng H361d*** 607-623-00-2 diisobutyl phthalate 201-553-2 84-69-5 Repr. 1B H360Df GHS08 Dgr H360Df Repr. 1B; H360Df: C ≥ 25 % Repr. 2; H361f: 5 % ≤ C < 25 % 607-624-00-8 perfluorooctane sulfonic acid; Dgr H360Df 607-624-00-8 perfluorooctane sulfonic acid; heptadecafluorooctane-1-sulfonic acid; [1] potassium perfluorooctanesulfonate; potassium heptadecafluorooctane-1-sulfonate; [2] … 460 unchanged lines … Wng H373 H317 H410 M = 1 M = 1 608-001-00-3 acetonitrile; M = 1 607-716-00-8 bromadiolone (ISO); 3-[3-(4′-bromobiphenyl-4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy-2H-chromen-2-one 249-205-9 28772-56-7 Repr. 1B Acute Tox. 1 Acute Tox. 1 Acute Tox. 1 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1 H360D H330 H310 H300 H372 (blood) H400 H410 GHS08 GHS06 GHS09 Dgr H360D H330 H310 H300 H372 (blood) H410 Repr. 1B; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 0,005 % STOT RE 2; H373 (blood): 0,0005 % ≤ C < 0,005 % M = 1 M = 1 607-717-00-3 difethialone (ISO); 3-[3-(4′-bromobiphenyl-4-yl)-1,2,3,4-tetrahydronaphthalen-1-yl]-4-hydroxy-2H-1-benzothiopyran-2-one — 104653-34-1 Repr. 1B Acute Tox. 1 Acute Tox. 1 Acute Tox. 1 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1 H360D H330 H310 H300 H372 (blood) H400 H410 GHS08 GHS06 GHS09 Dgr H360D H330 H310 H300 H372 (blood) H410 EUH070 Repr. 1B; H360D: C ≥ 0,003 % STOT RE 1; H372 (blood): C ≥ 0,02 % STOT RE 2; H373 (blood): 0,002 % ≤ C < 0,02 % M = 100 M = 100 607-718-00-9 perfluorononan-1-oic acid [1] and its sodium [2] and ammonium [3] salts 206-801-3 [1] [2] [3] 375-95-1 [1] 21049-39-8 [2] 4149-60-4 [3] Carc. 2 Repr. 1B Lact. Acute Tox. 4 Acute Tox. 4 STOT RE 1 Eye Dam. 1 H351 H360Df H362 H332 H302 H372 (liver, thymus, spleen) H318 GSH08 GSH07 GHS05 Dgr H351 H360Df H362 H332 H302 H372 (liver, thymus, spleen) H318 607-719-00-4 dicyclohexyl phthalate 201-545-9 84-61-7 Repr. 1B Skin Sens. 1 H360D H317 GHS08 GHS07 Dgr H360D H317 608-001-00-3 acetonitrile; cyanomethane 200-835-2 75-05-8 Flam. Liq. 2 Acute Tox. 4 * Acute Tox. 4 * … 564 unchanged lines … H373 ** H319 H410 M = 10 A 609-001-00-6 1-nitropropane 203-544-9 108-03-2 Flam. Liq. 3 608-067-00-3 3,7-dimethylocta-2,6-dienenitrile 225-918-0 5146-66-7 Muta. 1B H340 GHS08 Dgr H340 609-001-00-6 1-nitropropane 203-544-9 108-03-2 Flam. Liq. 3 Acute Tox. 4 * Acute Tox. 4 * Acute Tox. 4 * H226 … 5,419 unchanged lines … H318 H317 H410 M = 10 M = 10 613-001-00-1 ethyleneimine; M = 10 612-288-00-0 bupirimate (ISO); 5-butyl-2-ethylamino-6-methylpyrimidin-4-yl dimethylsulphamate 255-391-2 41483-43-6 Carc. 2 Skin Sens. 1B Aquatic Chronic 1 H351 H317 H410 GHS08 GHS07 GHS09 Wng H351 H317 H410 M = 1 612-289-00-6 triflumizole (ISO); (1E)-N-[4-chloro-2-(trifluoromethyl)phenyl]-1-(1H-imidazol-1-yl)-2-propoxyethanimine — 68694-11-1 Repr. 1B Acute Tox. 4 STOT RE 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 H360D H302 H373 (liver) H317 H400 H410 GHS08 GHS07 GHS09 Dgr H360D H302 H373 (liver) H317 H410 M = 1 M = 1 613-001-00-1 ethyleneimine; aziridine 205-793-9 151-56-4 Flam. Liq. 2 Carc. 1B Muta. 1B … 1,297 unchanged lines … (5-benzyl-3-furyl)methyl (1R)-2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylate 249-014-0 28434-01-7 Aquatic Acute 1 Aquatic Chronic 1 H400 H410 GHS09 Wng H410 M = 1000 613-121-00-4 chlorsulfuron (ISO); 2-chloro-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]benzenesulphonamide 265-268-5 64902-72-3 Aquatic Acute 1 Wng H410 M = 1000 613-121-00-4 chlorsulfuron (ISO); 2-chloro-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2- yl)amino]carbonyl]benzenesulphonamide 265-268-5 64902-72-3 Aquatic Acute 1 Aquatic Chronic 1 H400 H410 GHS09 Wng H410 613-122-00-X diclobutrazole (ISO); Wng H410 M = 1000 M = 100 613-122-00-X diclobutrazole (ISO); (R*, R*)-(±)-β-[(2,4-dichlorophenyl)methyl]-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol; (2RS, 3RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1H—1,2,4-triazol-1yl)pentan-3-ol — 75736-33-3 Eye Irrit. 2 Aquatic Chronic 2 H319 … 264 unchanged lines … Aquatic Chronic 1 H400 H410 GHS09 Wng H410 M=100 613-166-00-X flumioxazin (ISO); N-(7-fluoro-3,4-dihydro-3-oxo-4-prop-2-ynyl-2H-1,4-benzoxazin-6-yl)cyclohex-1-ene-1,2-dicarboxamide — 103361-09-7 Repr. 1B 2-[7-fluoro-3-oxo-4-(prop-2-yn-1-yl)-3,4-dihydro-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione — 103361-09-7 Repr. 1B Aquatic Acute 1 Aquatic Chronic 1 H360D*** Aquatic Chronic 1 H360D H400 H410 GHS08 GHS09 Dgr H360D*** H410 M=1000 613-167-00-5 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] Dgr H360D H410 M = 1000 M = 1000 613-167-00-5 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6] (3:1); reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-4-isothiazolin-3-one [EC no. 220-239-6] (3:1) — 55965-84-9 Acute Tox. 3 * … 1,886 unchanged lines … Dg H302 H314 H334 EUH031 616-011-00-4 N,N-dimethylacetamide 204-826-4 127-19-5 Repr. 1B Acute Tox. 4 * Acute Tox. 4 * H360D *** Acute Tox. 4* Acute Tox. 4* H360D*** H332 H312 GHS08 GHS07 Dgr H360D *** Dgr H360D*** H332 H312 Repr. 1B; H360D: C ≥ 5 % 616-012-00-X N-(dichlorofluoromethylthio)phthalimide; H312 616-012-00-X N-(dichlorofluoromethylthio)phthalimide; N-(fluorodichloromethylthio)phthalimide 211-952-3 719-96-0 Skin Irrit. 2 H315 GHS07 Wng H315 616-013-00-5 butyraldehyde oxime 203-792-8 110-69-0 Acute Tox. 3 * Acute Tox. 4 * … 169 unchanged lines … GHS08 Dgr H361f *** H301 H317 Skin Sens. 1; H317: C ≥ 0,1 % 616-037-00-6 acetochlor (ISO); 2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide 251-899-3 34256-82-1 Acute Tox. 4 * H317 Skin Sens. 1; H317: C ≥ 0,1 % 616-037-00-6 acetochlor (ISO); 2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide 251-899-3 34256-82-1 Carc. 2 Repr. 2 Acute Tox. 4 STOT SE 3 STOT RE 2 Skin Irrit. 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 H332 Aquatic Chronic 1 H351 H361f H332 H335 H373 (kidney) H315 H317 H400 H410 GHS07 H410 GHS08 GHS07 GHS09 Wng H332 Wng H351 H361f H332 H335 H373 (kidney) H315 H317 H410 616-038-00-1 (4-aminophenyl)-N-methylmethylensulfonamide hydrochloride 406-010-5 88918-84-7 Eye Dam. 1 H410 M = 1000 M = 100 616-038-00-1 (4-aminophenyl)-N-methylmethylensulfonamide hydrochloride 406-010-5 88918-84-7 Eye Dam. 1 Skin Sens. 1 Aquatic Chronic 2 H318 H317 … 676 unchanged lines … M = 100 616-206-00-4 flufenoxuron (ISO); 1-(4-(2-cloro-α,α,α-p-trifluorotolyloxy)-2-fluorophenyl)-3-(2,6-difluorobenzolyl)urea 417-680-3 101463-69-8 Lact. H362 GHS09 H362 M = 10000 M = 10000 Aquatic Acute 1 H400 Wng Aquatic Chronic 1 H410 H410 616-207-00-X polyhexamethylene biguanide hydrochloride 27083-27-8 or 32289-58-0 Carc. 2 H351 GHS05 H351 M = 10 M = 10 Acute Tox. 4 H302 GHS07 H302 STOT RE 1 H372 (respiratory tract) (inhalation) GHS08 H372 (respiratory tract) (inhalation) Eye Dam. 1 H318 GHS09 H318 Skin Sens. 1B H317 Dgr H317 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 H410 616-208-00-5 N-ethyl-2-pyrrolidone; 616-207-00-X polyhexamethylene biguanide hydrochloride; PHMB — 32289-58-0 27083-27-8 Carc. 2 Acute Tox. 2 Acute Tox. 4 STOT RE 1 Eye Dam. 1 Skin Sens. 1B Aquatic Acute 1 Aquatic Chronic 1 H351 H330 H302 H372 (respiratory tract) (inhalation) H318 H317 H400 H410 GHS08 GHS06 GHS05 GHS09 Dgr H351 H330 H302 H372 (respiratory tract) (inhalation) H318 H317 H410 M = 10 M = 10 616-208-00-5 N-ethyl-2-pyrrolidone; 1-ethylpyrrolidin-2-one 220-250-6 2687-91-4 Repr. 1B H360D GHS08 Dgr H360D 616-209-00-0 amidosulfuron (ISO); 3-(4,6-dimethoxypyrimidin-2-yl)-1-((N-methyl-N-methylsulfonylamino)sulfonyl)urea 407-380-0 120923-37-7 Aquatic Acute 1 H400 GHS09 M = 100 … 64 unchanged lines … GHS09 Wng H302 H410 M = 1 M = 1 617-001-00-2 di-tert-butyl peroxide 203-733-6 110-05-4 Org. Perox. E M = 1 616-218-00-X benzovindiflupyr (ISO); N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide — 1072957-71-1 Acute Tox. 3 Acute Tox. 3 Aquatic Acute 1 Aquatic Chronic 1 H331 H301 H400 H410 GHS06 GHS09 Dgr H331 H301 H410 M = 100 M = 100 616-219-00-5 fluopyram (ISO); N-{2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]ethyl}-2-(trifluoromethyl)benzamide — 658066-35-4 Aquatic Chronic 2 H411 GHS09 H411 616-220-00-0 pencycuron (ISO); 1-[(4-chlorophenyl)methyl]-1-cyclopentyl-3-phenylurea 266-096-3 66063-05-6 Aquatic Acute 1 Aquatic Chronic 1 H400 H410 GHS09 Wng H410 M = 1 M = 1 617-001-00-2 di-tert-butyl peroxide 203-733-6 110-05-4 Org. Perox. E Flam. Liq. 2 Muta. 2 H242 H225 … 227 unchanged lines … H302 H314 H317 H411 647-001-00-8 glucosidase, β- 232-589-7 9001-22-3 Resp. Sens. 1 H334 GHS08 H411 617-023-00-2 tert-butyl hydroperoxide 200-915-7 75-91-2 Muta. 2 H341 GHS08 Wng H341 647-001-00-8 glucosidase, β- 232-589-7 9001-22-3 Resp. Sens. 1 H334 GHS08 Dgr H334 647-002-00-3 cellulase 232-734-4 9012-54-8 Resp. Sens. 1 H334 GHS08 Dgr H334 647-003-00-9 cellobiohydrolase, exo- 253-465-9 37329-65-0 Resp. Sens. 1 H334 GHS08 Dgr H334 647-004-00-4 cellulases with the exception of those specified elsewhere in this Annex — — Resp. Sens. 1 H334 GHS08 … 20,340 unchanged lines … C; R34 R42 C R: 22-31-34-42 S: (1/2-)7-22-26-36/37/39-45 616-011-00-4 N,N-dimethylacetamide 204-826-4 127-19-5 Repr. Cat. 2; R61 Xn; R20/21 T R: 61-20/21 S: 53-45 Repr. Cat. 2; R61: C ≥ 5 % E 616-012-00-X N-(dichlorofluoromethylthio)phthalimide; S: (1/2-)7-22-26-36/37/39-45 616-012-00-X N-(dichlorofluoromethylthio)phthalimide; N-(fluorodichloromethylthio)phthalimide 211-952-3 719-96-0 Xi; R38 Xi R: 38 S: (2-)28 616-013-00-5 butyraldehyde oxime 203-792-8 110-69-0 T; R24 … 4,996 unchanged lines … S: 61 650-055-00-5 silver sodium zirconium hydrogenphosphate 422-570-3 155925-27-2 N; R50-53 N R: 50/53 S: 60-61

MODIFIED +101 −153 Annex VII Translation table from classification under Directive 67/548/EEC to classification under this Regulation

applies from: unchanged

Note 2 no longer recommends classifying in Category 1B while noting that 1C could apply in certain cases; instead it states that where the exposure period distinction cannot be made, Category 1 shall be assigned, and that further sub-categorisation into Category 1B or Category 1C shall be considered when sequential-approach data are available.

The entry for C; R34 changes its corresponding classification from Skin Corr. 1B to Skin Corr. 1, while keeping the same hazard statement and note reference.

Cited: Annex VII, v2 · Annex VII, v1

text before / after

02008R1272-2017060102008R1272-20180301

ANNEX VII Translation table from classification under Directive 67/548/EEC to classification under this Regulation This Annex includes a table to assist translation of a classification made for a substance or a mixture under Directive 67/548/EEC or Directive 1999/45/EC, respectively, into the corresponding classification under this Regulation. Whenever data for the substance or mixture are available, an evaluation and classification shall be done in accordance with Articles 9 to13 of this Regulation. 1. Translation table The codes used are introduced in Table 1.1 and section 1.1.2.2 of Annex VI. Table 1.1 Translation between classification in accordance with Directive 67/548/EEC and this Regulation Note 1 For these classes it is possible to use the recommended minimum classification as defined in section 1.2.1.1 in Annex VI. Data or other information may be available to indicate that re-classification in a more severe category is appropriate. Note 2 It is recommended to classify in Category 1B even if it also could be possible that 1C could be applicable for certain cases. Going back to original data, data may not result in a possibility to distinguish between Category 1B or 1C, since the exposure period has normally been up to 4 hours according to Regulation (EC) No 440/2008. In these cases, Category 1 shall be assigned. However, for the future, when data are derived from tests following a sequential approach as foreseen in the Regulation (EC) No 440/2008, further sub-categorisation into Category 1B or Category 1C should shall be considered. Note 3 The route of exposure could be added to the hazard statement if it is conclusively proven that no other routes of exposure cause the hazard. Note 4 Hazard statements H360 and H361 indicate a general concern for effects on fertility … 349 unchanged words … gas Acute Tox. 2 H330 (1) T+; R26 vapour Acute Tox. 1 H330 T+; R26 dust/mist Acute Tox. 2 H330 (1) T+; R27 Acute Tox. 1 H310 T+; R28 Acute Tox. 2 H300 (1) R33 STOT RE 2 H373 (3) C; R34 Skin Corr. 1B 1 H314 (2) C; R35 Skin Corr. 1A H314 Xi; R36 Eye Irrit. 2 H319 Xi; R37 STOT SE 3 H335 Xi; R38 Skin Irrit. 2 H315 T; R39/23 STOT SE 1 H370 (3) T; R39/24 STOT SE 1 H370 (3) T; R39/25 STOT SE 1 H370 (3) T+; R39/26 STOT SE 1 H370 (3) T+; R39/27 STOT SE 1 H370 (3) T+; R39/28 STOT SE 1 H370 (3) Xi; R41 Eye Dam. 1 H318 R42 Resp. Sens. 1 H334 R43 Skin Sens. 1 H317 Xn; R48/20 STOT RE 2 H373 (3) Xn; R48/21 STOT RE 2 H373 (3) Xn; R48/22 STOT RE 2 H373 (3) T; R48/23 STOT RE 1 H372 (3) T; R48/24 STOT RE 1 H372 (3) T; R48/25 STOT RE 1 H372 (3) R64 Lact. H362 Xn; R65 Asp. Tox. 1 H304 R67 STOT SE 3 H336 Xn; R68/20 STOT SE 2 H371 (3) Xn; R68/21 STOT SE 2 H371 (3) Xn; R68/22 STOT SE 2 H371 (3) Carc. Cat. 1; R45 Carc. 1A H350 Carc. Cat. 2; R45 Carc. 1B H350 Carc. Cat. 1; R49 Carc. 1A H350i Carc. Cat. 2; R49 Carc. 1B H350i Carc. Cat. 3; R40 Carc. 2 H351 Muta. Cat. 2; R46 Muta. 1B H340 Muta. Cat. 3; R68 Muta. 2 H341 Repr. Cat. 1; R60 Repr. 1A H360F (4) Repr. Cat. 2; R60 Repr. 1B H360F (4) Repr. Cat. 1; R61 Repr. 1A H360D (4) Repr. Cat. 2; R61 Repr. 1B H360D (4) Repr. Cat. 3; R62 Repr. 2 H361f (4) Repr. Cat. 3; R63 Repr. 2 H361d (4) Repr. Cat. 1; R60-61 Repr. 1A H360FD Repr. Cat. 1; R60 Repr. Cat. 2; R61 Repr. 1A H360FD Repr. Cat. 2; R60 Repr. Cat. 1; R61 Repr. 1A H360FD Repr. Cat. 2; R60-61 Repr. 1B H360FD Repr. Cat. 3; R62-63 Repr. 2 H361fd Repr. Cat. 1; R60 Repr. Cat. 3; R63 Repr. 1A H360Fd Repr. Cat. 2; R60 Repr. Cat. 3; R63 Repr. 1B H360Fd Repr. Cat. 1; R61 Repr. Cat. 3; R62 Repr. 1A H360Df Repr. Cat. 2; R61 Repr. Cat. 3; R62 Repr. 1B H360Df N; R50 Aquatic Acute 1 H400 N; R50-53 Aquatic Acute 1 Aquatic Chronic 1 H400 H410 N; R51-53 Aquatic Chronic 2 H411 R52-53 Aquatic Chronic 3 H412 R53 Aquatic Chronic 4 H413 N; R59 Ozone H420 Table 1.2 Translation between risk phrases assigned under Directive 67/548/EEC and supplementary labelling requirements under this Regulation Directive 67/548/EEC This Regulation R1 EUH001 R6 EUH006 R14 EUH014 R18 EUH018 R19 EUH019 R44 EUH044 R29 EUH029 R31 EUH031 R32 EUH032 R66 EUH066 R39-41 EUH070

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